Abstract
The pressure elevation related to the variances in temperature for cylinder Li-ion cells including LiCoO2, LiMnO2, LiFePO4, and LiNi1/3Mn1/3Co1/3O2 cathodes was compared with their explosive behaviors. 50 and 100% state of charges Li-ion cells were examined the pressure rising rates in an open-circuit voltage condition using adiabatic calorimetry. A charged cell underwent an extremely runaway reaction at elevated temperatures and caused a thermal explosion due to high potential energy of the battery system and interaction with the components. This study presented the relationships between temperature and pressure in a Li-ion cell proceeding on a thermal explosion in the adiabatic confinement testing. The layer-structure LiCoO2 cell has the significant deflagration potential for condensed phase explosion. Moreover, the considerable quantities of gas eruption from a charged cell can be resulted in battery rupture and flames from a confined energy storage system. The critical temperature to thermal explosion model for a cylinder Li-ion cell was evaluated to classify their runaway reaction and deflagration potential.
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Abbreviations
- a :
-
Constant
- b :
-
Constant
- c v :
-
Total heat capacity, J g−1 K−1
- d :
-
Constant
- (dT/dt)ad :
-
Self-heating rate under an adiabatic condition, °C min−1
- dp/dt :
-
Pressure rising rate, bar min−1
- E 0 :
-
Li chemical potential, V
- E a :
-
Apparent activation energy, eV
- E dyn :
-
Thermal explosion expression, kJ
- E iso :
-
Isothermal expansion, kJ
- F :
-
Faraday constant, 96,487 C mol−1
- ∆G :
-
Change in Gibbs free energy, J
- ∆H :
-
Enthalpy, J
- i :
-
Constant
- j :
-
Constant
- m :
-
Constant
- k 0 :
-
Frequency factor, min−1
- k B :
-
Boltzmann’s constant, 8.62e−5 eV K−1
- m LIB :
-
Mass of the LIB, g
- n :
-
The charged number carried by the exchanged Li ion
- n i :
-
Moles of reactants, mole
- n f :
-
Moles of products, mole
- p :
-
Pressure, barg
- p 0 :
-
Ambient pressure, 1.01 barg
- p 1 :
-
Absolute pressure, barg
- p cr :
-
Critical pressure in a turning from thermal runaway to explosion, barg
- p peak :
-
Peak pressure, barg
- p max :
-
Maximum pressure, barg
- Q :
-
Heat generation, W
- R :
-
Ideal gas constant, 8.314 J K−1 mol−1
- r :
-
Constant
- ∆S :
-
Entropy, J K−1
- SoC:
-
State of charge, %
- t :
-
Time
- T :
-
Temperature, °C or K
- T 0 :
-
Apparent exothermic onset temperature, °C or K
- T cr :
-
Critical temperature from runaway to explosion, °C or K
- U OCV :
-
Open-circuit voltage, V
- v :
-
Volume of a Li-ion cell
- W e :
-
Electric work, J
- x :
-
Degree of conversion
- α :
-
Ionic composition
References
Jhu CY, Wang YW, Shu CM, Chang JC, Wu HC. Thermal explosion hazards on 18650 lithium ion batteries with a VSP2 adiabatic calorimeter. J Hazard Mater. 2011;192:99–107.
Julien C, Stoynov Z. Design considerations for lithium batteries. In: Julien C, Stoynov Z, editors. Materials for lithium-ion batteries. Dordrecht: Springer; 2000. p. 1–20.
Patel P. Improving the lithium-ion battery. ACS Central Sci. 2015;1:161–2.
Wang Z, Ouyang D, Chen M, Wang X, Zhang Z, Wang J. Fire behavior of lithium-ion battery with different states of charge induced by high incident heat fluxes. J Therm Anal Calorim. 2019;136(6):2239–47.
Chen M, Dongxu O, Cao S, Liu J, Wang Z, Wang J. Effects of heat treatment and SoC on fire behaviors of lithium-ion batteries pack. J Therm Anal Calorim. 2019;136(6):2429–37.
Ouyang D, He Y, Chen M, Liu J, Wang J. Experimental study on the thermal behaviors of lithium-ion batteries under discharge and overcharge conditions. J Therm Anal Calorim. 2018;132(1):65–75.
Zhang Z, Ramadass P, Fang W. Safety of lithium-ion batteries. In: Pistoia G, editor. Lithium-ion batteries: advances and applications. New York: Elsevier; 2014. p. 409–35.
Broussely M, Biensan P, Bonhomme F, Blanchard P, Herreyre S, Nechev K, et al. Main aging mechanisms in Li ion batteries. J Power Sources. 2005;146:90–6.
Federal Aviation Administration (FAA). Office of Security and Hazardous Materials Safety. Events with smoke, fire, extreme heat or explosion involving lithium batteries. USA FAA. 2018. https://www.faa.gov/hazmat/resources/lithium_batteries/media/Battery_incident_chart.pdf. Accessed 01 May 2018.
Ishikawa H, Mendoza Q, Sone Y, Umeda M. Study of thermal deterioration of lithium-ion secondary cell using an accelerated rate calorimeter (ARC) and AC impedance method. J Power Sources. 2012;198:236–42.
Vazquez-Arenas J, Gimenez LE, Fowler M, Han T, Chen SK. A rapid estimation and sensitivity analysis of parameters describing the behavior of commercial Li-ion batteries including thermal analysis. Energy Convers Manag. 2014;87:472–82.
Jhu CY, Wang YW, Wen CY, Chiang CC, Shu CM. Self-reactive rating of thermal runaway hazards on 18650 lithium-ion batteries. J Therm Anal Calorim. 2011;106:159–63.
Doughty D, Roth EP. A general discussion of li-ion battery safety. Electrochem Soc Interface. 2012;21:37–44.
Duh YS, Lee CY, Chen YL, Kao CS. Characterization on the exothermic behaviors of cathode materials reacted with ethylene carbonate in lithium-ion battery studied by differential scanning calorimeter (DSC). Thermochim Acta. 2016;642:88–94.
Chung YH, Jhang WC, Chen WC, Wang YW, Shu CM. Thermal hazard assessment for three C rates for a Li-polymer battery by using vent sizing package 2. J Therm Anal Calorim. 2017;127(1):809–17.
Duh YS, Tsai MT, Kao CS. Characterization on the thermal runaway of commercial 18650 lithium-ion batteries used in electric vehicle. J Therm Anal Calorim. 2017;127(1):983–93.
Lu TY, Chiang CC, Wu SH, Chen KC, Lin SJ, Wen CY, Shu CM. Thermal hazard evaluations of 18650 lithium-ion batteries by an adiabatic calorimeter. J Therm Anal Calorim. 2013;114(3):1083–8.
Wang YW, Shu CM. Hazard characterizations of Li-ion batteries: thermal runaway evaluation by calorimetry methodology. In: Zhang Z, Zhang SS, editors. Rechargeable batteries: materials, technology and new trends. Cham: Springer; 2015. p. 419–54.
Ozawa K. Lithium ion rechargeable batteries: materials, technology, and new applications. New York: Wiley; 2012. p. 1–9.
Wang Q, ** P, Zhao X, Chu G, Sun J, Chen C. Thermal runaway caused fire and explosion of lithium ion battery. J Power Sources. 2012;208:210–4.
Yazami R. Thermodynamics of electrode materials for lithium-ion batteries. In: Ozawa K, editor. Lithium ion rechargeable batteries: materials, technology, and new applications. New York: Wiley; 2012. p. 67–102.
Al-Hallaj S, Maleki H, Hong JS, Selman JR. Thermal modeling and design considerations of lithium-ion batteries. J Power Sources. 1999;83:1–8.
Chen WC, Wang YW, Shu CM. Adiabatic calorimetry test of the reaction kinetics and self-heating model for 18650 Li-ion cells in various states of charge. J Power Sources. 2016;318:200–9.
Argue S, Davidson I, Ammundsen B, Paulsen J. A comparative study of the thermal stability of Li1−xCoO2 and Li3−xCrMnO5 in the presence of 1 M LiPF6 in 3: 7 EC/DEC electrolyte using accelerating rate calorimetry. J Power Sources. 2003;119:664–8.
Crowl DA. Fundamentals of fires and explosions. In: Crowl DA, editor. Understanding explosions. New York: American Institute of Chemical Engineers; 2003. p. 54–112.
Gachot G, Grugeon S, Jimenez-Gordon I, Eshetu GG, Boyanov S, Lecocq A, Marlair G, Pilard S, Laruelle S. Gas chromatography/Fourier transform infrared/mass spectrometry coupling: a tool for Li-ion battery safety field investigation. Anal Methods. 2014;6:6120–4.
Smith JM, Ness HC. Introduction to chemical engineering thermodynamics. 7th ed. New York: McGraw Hill; 2005. p. 159–88.
Hu L, Zhang SS, Zhang Z. Electrolytes for lithium and lithium-ion batteries. In: Zhang SS, Zhang Z, editors. Rechargeable batteries: materials, technology and new trends. Cham: Springer; 2015. p. 231–61.
Golubkov AW, Fuchs D, Wanger J, Wiltsche H, Stangl C, Fauler G, Voitic G, Thaler A, Hacker V. Thermal-runaway experiments on consumer Li ion batteries with metal-oxide and olivin-type cathodes. RSC Adv. 2014;4:3633–42.
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The author is indebted to the Ministry of Science and Technology of Taiwan (MOST 104-2221-E-039-005-MY2) for providing financial support of this study.
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Wang, YW. Evaluate the deflagration potential for commercial cylinder Li-ion cells under adiabatic confinement testing. J Therm Anal Calorim 143, 661–670 (2021). https://doi.org/10.1007/s10973-020-09282-x
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DOI: https://doi.org/10.1007/s10973-020-09282-x