SpringerLink
Log in

Thermodynamic analysis of liquid In–Sn alloys using Oelsen calorimetry

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

The results of calorimetric investigations of liquid In–Sn alloys using Oelsen calorimetry are presented in this article. Based on obtained enthalpy space diagram and enthalpy isotherm diagram, thermodynamic parameters for the liquid In–Sn alloys, including mixing and excess integral and partial molar quantities at temperature of 600 K, have been determined and compared with available literature data.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. http://www.univie.ac.at/cost531.

  2. Speckbrock G, Kamitz S, Alt M, Schmitt H. Low melting gallium, indium, and tin eutectic alloys, United States Patent 6019509; 2000.

  3. White CET, Okamoto H, editors. Phase diagrams of indium alloys and their engineering applications. Utica, NY: Indium Corporation of America, Ohio: Materials Information Soc., Materials Park; 1992.

  4. http://www.crct.polymtl.ca/fact/Documentation/BINARY/In-Sn.jpg.

  5. Vicentini M, Paoletti A. Self diffusion in liquid In-Sn alloys. Phys Astron. 1959;14:1373–80.

    Google Scholar 

  6. Swarnalata N, Padmini ARKL. Ultrasonic velocities and elastic constants in tin–indium alloys. Patrmana. 1984;23:155–63.

    Article  CAS  Google Scholar 

  7. Maciejewski S. Band structure and fermi surface on In3Sn alloys in the β-phase. Phys Status Solidi B. 2006;66:633–38.

    Google Scholar 

  8. Degtyareva VF. The fcc-bcc bain path in In-Sn and related alloys at ambient and high pressure. J Phys. 2009;21:95702–6.

    Google Scholar 

  9. Terpilowski J, Przedziecka-Mycielska E. EMF measurements of In-Sn alloys. Arch Hutn. 1960;5:281–9.

    CAS  Google Scholar 

  10. Cakir O, Alpaut O. Thermodynamic properties of solid In-Sn alloys. J Less-Common Met. 1988;141:11–27.

    Article  CAS  Google Scholar 

  11. Kleppa OJ. Calorimetric investigation of the In-Sn system. J Phys Chem. 1956;60:842–50.

    Article  CAS  Google Scholar 

  12. Wittig FE, Scheidt P. Direct reaction calorimetry of In-Sn alloys. Z Phys Chem. 1961;28:120–6.

    CAS  Google Scholar 

  13. Yazawa A, Kawashima T, Itagaki K. Thermodynamics of the In-Sn system. J Jpn Inst Met Sendai. 1968;32:1281–7.

    CAS  Google Scholar 

  14. Brunetti B, Gozzi D, Iervolino M, Piacente V, Zanicchi G, Parodi N, Borzone G. Bismuth activity in lead-free solder Bi-In-Sn-alloys. Calphad. 2006;30:431–42.

    Article  CAS  Google Scholar 

  15. Hultgren R, Desai PD, Hawkins DT, Gleiser M, Kelley KK. Selected values of thermodynamic properties of binary alloys. Metals Park, OH: American Society of Metals; 1973.

    Google Scholar 

  16. Dinsdale AT, Watson A, Kroupa A, Zemanova A, Vrestal J, Vizdal J. COST531 thermodynamic database, Ver. 2.2; 2006.

  17. Oelsen W, Zuhlke P. Zur thermodynamischen Analyse VIII. Arch Eisenhuttenwes. 1956;27:743–52.

    CAS  Google Scholar 

  18. Oelsen W, Johannsen F, Podgornik A. Kalorimetrie und Thermodynamik der Blei-Antimon-legierungen. Zeitsch Erzbergbau Metallhüttenwes. 1956;9:1–11.

    Google Scholar 

  19. Oelsen W, Schürmann E, Weigt HJ, Oelsen O. Zur thermodynamischen Analyse IV. Arch Eisenhuttenwes. 1956;27:487–511.

    CAS  Google Scholar 

  20. Pool MJ, Predel B, Schulheiss E. Application of the Setaram high temperature calorimeter for determination of mixing enthalpies of liquid alloys. Thermochim Acta. 1979;28:349–58.

    Article  CAS  Google Scholar 

  21. Zivkovic D, Manasijevic D, Zivković Z. Thermodynamic and phase diagram investigation of Pb-BiIn section in Pb-Bi-In ternary system. Thermochim Acta. 2004;417:119–25.

    Article  CAS  Google Scholar 

  22. Sorai M, editors. Comprehensive handbook of calorimetry and thermal analysis. Chichester: Wiley; 2004. p 297.

  23. Zivkovic D, Katayama I, Gomidzelovic L, Manasijevic D, Novakovic R. Comparative thermodynamic study and phase equilibria of the Bi-Ga-Sn ternary system. Int J Mater Res. 2007;98:1025–30.

    CAS  Google Scholar 

  24. Gomidzelovic L, Zivkovic D. Thermodynamic analysis of AuIn-Sb system using Oelsen calorimetry and predicting methods. J Therm Anal Calorim. 2009;98:743–8.

    Article  CAS  Google Scholar 

  25. Saunders N, Miodownik AP. CALPHAD calculation of phase diagrams—a comprehensive guide. Amsterdam: Elsevier; 1998.

Download references

Acknowledgements

The authors are grateful to support of the Ministry of Science and Technological Development of the Republic of Serbia under project No 142043. Presented investigations were done also in the frame of COST project MP0602.

Author information

Authors and Affiliations

  1. University of Belgrade, Technical Faculty in Bor, VJ 12, 19210, Bor, Serbia

    Dragana Živković, Aleksandra Mitovski, Ljubiša Balanović, Dragan Manasijević & Živan Živković

Authors
  1. Dragana Živković
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Aleksandra Mitovski
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ljubiša Balanović
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Dragan Manasijević
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Živan Živković
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Dragana Živković.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Živković, D., Mitovski, A., Balanović, L. et al. Thermodynamic analysis of liquid In–Sn alloys using Oelsen calorimetry. J Therm Anal Calorim 102, 827–830 (2010). https://doi.org/10.1007/s10973-010-0785-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10973-010-0785-x

Keywords

Search

Navigation