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Thermal analysis of copper(Ii) complexes of general formula [Et4N]2[CuBrnCl4-n]

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Abstract

Thermal decomposition of compounds consisting of tetrahalogenocuprate(II), [CuBrnCl4−n]2− (n=0–4) anions and a tetraethylammonium cation has been studied using TG-FTIR, TG-MS, DTA and DTG techniques. The measurements were carried out in an argon and air atmospheres over the temperature range 293-1073 K. The products of the thermal decomposition were identified by IR and Far Infrared (FIR) spectroscopy as well as X-ray powder diffractometry.

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Authors and Affiliations

  1. Faculty of Chemistry, University of Gdańsk, Sobieskiego 18, 80-952, Gdańsk, Poland

    E. Styczeń, D. Wyrzykowski & Z. Warnke

  2. Institute of General and Ecological Chemistry, Technical University of Łódź, Żwirki 36, 90-924, Łódź, Poland

    W. K. Jóźwiak

  3. Faculty of Physics and Mathematics, Technical University of Gdańsk, Narutowicza 11/12, 80-952, Gdańsk, Poland

    M. Gazda

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  1. E. Styczeń
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  2. W. K. Jóźwiak
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  3. M. Gazda
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  4. D. Wyrzykowski
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  5. Z. Warnke
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Correspondence to E. Styczeń.

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Styczeń, E., Jóźwiak, W.K., Gazda, M. et al. Thermal analysis of copper(Ii) complexes of general formula [Et4N]2[CuBrnCl4-n]. J Therm Anal Calorim 91, 979–984 (2008). https://doi.org/10.1007/s10973-007-8689-0

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  • DOI: https://doi.org/10.1007/s10973-007-8689-0

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