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Adsorption kinetic, isotherm and thermodynamic studies of Sr2+ onto hexagonal tungsten oxide

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Abstract

Hexagonal tungsten oxide (hex-WO3) with exchangeable sodium and ammonium cations located in hexagonal channel was synthesized by a facile hydrothermal treatment of sodium tungstate dihydrate in concentrated HCl solution in the presence of ammonium sulfate. An attempt was made to assess the potential of hex-WO3 for the adsorption of Sr2+ ions from acidic radioactive waste solutions. Adsorption of Sr2+ reached equilibrium very quickly in 2 h in acidic aqueous solution. Maximum removal of Sr2+ ions occurred at pH 4. Equilibrium studies showed that the extent of Sr2+ ions uptake by hex-WO3 was better described by the Freundlich isotherm in comparison with the Langmuir model. The thermodynamic parameters showed that the adsorption of Sr2+ ions onto hex-WO3 was spontaneous and exothermic under the studied conditions.

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Acknowledgments

The financial support from the National Natural Science Foundation of China (Grant 41103077) and China Academy of Engineering Physics is gratefully acknowledged.

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Author notes

  1. Shoujian Li

    Present address: College of Chemistry, Sichuan University, 29# Wangjiang Road, Chengdu, 610064, Sichuan, China

  2. **ngliang Li

    Present address: Institute of Nuclear Chemistry and Physics, China Academy of Engineering Physics, 64# Mianshan Road, Mianyang, 621900, Sichuan, China

Authors and Affiliations

  1. College of Chemistry, Sichuan University, 29# Wangjiang Road, Chengdu, 610064, Sichuan, China

    **ngliang Li

  2. Institute of Nuclear Chemistry and Physics, China Academy of Engineering Physics, 64# Mianshan Road, Mianyang, 621900, Sichuan, China

    Wanjun Mu, Bijun Liu, Wenbin Zhong, Hongyuan Wei, Yuan Jian, Zhengkun Zhong & Shunzhong Luo

  3. Institute of Nuclear Science and Technology, Sichuan University, Chengdu, 610064, China

    **ngliang Li, Yuan Jian, Shunzhong Luo & Shoujian Li

Authors
  1. **ngliang Li
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  2. Wanjun Mu
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Correspondence to **ngliang Li or Shoujian Li.

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Li, X., Mu, W., Liu, B. et al. Adsorption kinetic, isotherm and thermodynamic studies of Sr2+ onto hexagonal tungsten oxide. J Radioanal Nucl Chem 298, 47–53 (2013). https://doi.org/10.1007/s10967-013-2617-5

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  • DOI: https://doi.org/10.1007/s10967-013-2617-5

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