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[(EtO)3Si(CH2)3N+H3][CH3COO−] as Basic Ionic Liquid Catalyst Promoted Green Synthesis of Benzo[a]pyrano[2,3-c]phenazine Derivatives in Homogenous Solution

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Abstract

An efficient, one-pot quantitative procedure for the preparation of benzo[a]pyrano[2,3-c]phenazine derivatives from four-component condensation reaction of 2-hydroxynaphthalene-1,4-dione, benzene-1,2-diamine, aromatic aldehydes, and malononitrile in the presence of [(EtO)3Si(CH2)3N+H3][CH3COO−] as basic ionic liquid as catalyst in homogenous solution under solvent-free conditions at 90 °C is described. Simple procedure, high yields, short reaction times, and an environmentally benign method are advantages of this protocol. The [(EtO)3Si(CH2)3N+H3][CH3COO−] can be recovered and reused several times without loss of its activity.

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The data that support the findings of this study are available in the supplementary material of this article.

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Funding

We are thankful to the University of Sistan and Baluchestan Research Council for the partial support of this research.

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  1. Department of Chemistry, Faculty of Science, University of Sistan and Baluchestan, PO Box: 987-98155, Zahedan, 98197-45845, Iran

    Farhad Shirzaei & Hamid Reza Shaterian

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  1. Farhad Shirzaei
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All authors contributed to the study conception and design. Material preparation, data collection and analysis were performed by FS, and HRS.

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Correspondence to Hamid Reza Shaterian.

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Shirzaei, F., Shaterian, H.R. [(EtO)3Si(CH2)3N+H3][CH3COO−] as Basic Ionic Liquid Catalyst Promoted Green Synthesis of Benzo[a]pyrano[2,3-c]phenazine Derivatives in Homogenous Solution. J Solution Chem 53, 328–340 (2024). https://doi.org/10.1007/s10953-023-01332-w

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