Abstract
This paper discusses the relationship between the medium effect as defined by Owen’s and Pitzer’s equations. Using this relationship and values of Pitzer’s parameters (which account for various types of short-range interactions between neutral molecules and ions, for indirect forces arising from the solvent, and for triple particle interactions), we analyzed published experimental data for {HCl + organic solvent + water} systems.
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Yang, JZ., Xu, WG. Medium Effect of an Organic Solvent on the Activity Coefficients of HCl Consistent with Pitzer’s Electrolyte Solution Theory. J Solution Chem 34, 71–76 (2005). https://doi.org/10.1007/s10953-005-2073-0
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DOI: https://doi.org/10.1007/s10953-005-2073-0