Abstract
The crystal structures of type 1234 and 2234 are not found in compositions Bi1-xBxSr2Ca3Cu4Oy and Bi2-xBxSr2Ca3Cu4Oy after synthesis under conditions of ambient pressure P = 1 bar and T = 835 °C for τ = 240 h. This conclusion is obtained as a result of the fact that the series of bismuth superconductors Bi1-xBxSr2Ca3Cu4Oy, Bi2-xBxSr2Ca3Cu4Oy, Bi2-xBxSr2Ca2Cu3Oy, Bi1.7-xBxPb0.3Sr2Ca2Cu3Oy with different boron content x = 0-2 were synthesized followed by slow (rate < 10 °C/sec) cooling or quenching (< 100 °C/sec). Samples of Bi1.7-xBxPb0.3Sr2Ca2Cu3Oy with a boron content of x = 0.5 have a significant (> 35%) proportion of the superconducting phase 2223, regardless of the accuracy of observing the temperature modes of synthesis (in temperature ranges < ±10 °C) and cooling after it. A model of the effect of boron on phase equilibrium in Bi-Pb-Sr-Ca-Cu-O system is proposed using the process of boron-bismuth glass formation. Therefore, the boron addition during the synthesis of bismuth superconductors will increase the production process reproducibility of phase 2223. Also, this technology can be used at the synthesis of superconductors from the boron-bismuth not very enriched ores in conditions of limited available resources.
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References
Lee, Ho Keun: Effects of Ga do** on the superconducting properties of (B1-xGax)(Ba1.25Sr0.75)(Ca0.5Er0.5)Cu2Oz. Prog. Supercond. Cryog. 25(4), 14–18 (2023). https://doi.org/10.9714/psac.2023.25.4.014
Flores-Livas, J.A., Boeri, L., Sanna, A., Profeta, G., Arita, R., Eremets, M.: A perspective on conventional high-temperature superconductors at high pressure: Methods and materials. Phys. Rep. 856, 1–78 (2020). https://doi.org/10.1016/j.physrep.2020.02.0
Kim, M.S., Lee, S.I., Iyo, A., Tokiwa, K., Tokumoto, M., Ihara, H.: Interlayer coupling and superconducting properties of the triple-layer compound B0.6C0.4(Sr0.25Ba0.75)2Ca2Cu3O9. Phys. Rev. B 57(14), 8667 (1998). https://doi.org/10.1103/PhysRevB.57.8667
Wang, Y., Wang, K., Sun, Y., Ma, L., Wang, Y., Zou, B., ... & Wang, H.: Synthesis and superconductivity in yttrium superhydrides under high pressure. Chin. Phys. B 31(10), 106201 (2022). https://doi.org/10.1088/1674-1056/ac872e
Gladyshevskii, R., Galez, P.: Crystal structures of high-Tc superconducting cuprates. In: Handbook of Superconductivity, pp. 267–431. Academic Press (2000). https://doi.org/10.1016/B978-012561460-3/50009-6
Takayama-Muromachi, E., Matsui, Y., Kosuda, K.: New oxyborate superconductor, BSr2Ca3Cu4O11 (Tc=110 K) prepared at high pressure. Physica C 241(1–2), 137–141 (1995). https://doi.org/10.1016/0921-4534(94)02363-8
Katsura, H., Suemune, T.H.: Boron ion do** effects on superconductivity of YBa2Cu3-xBxO7-y ceramics. Jpn. J. Appl. Phys. 30(2R), 274 (1991). https://doi.org/10.1143/JJAP.30.274
Li, J.Q., Li, F.H., Zhao, Z.X.: Transmission-electron-microscopy study of incommensurate structural modulation in Y(Ba,Sr)2Cu2.5B0.5Oy. Phys. Rev. B 48(2), 1333 (1993). https://doi.org/10.1103/PhysRevB.48.1333
Zhu, W.J., Yue, J.J., Huang, Y.Z., Zhao, Z.X.: (B, Cu)Sr2YCu2O7, a new layered copper-oxide based on the boron-oxygen group. Physica C 205(1–2), 118–122 (1993). https://doi.org/10.1016/0921-4534(93)90176-Q
Iyo, A., Tokiwa, K., Tereda, N., Tokumoto, M., Ihara, H.: Preparation of (B1−xCx)(Sr1−yBay)2Ca2Cu3O9 with Tc=119 K. Czech J. Phys. 46(Suppl 3), 1481–1482 (1996). https://doi.org/10.1007/BF02562855
Takayama-Muromachi, E., Kawashima, T., Matveev, A.T., Isobe, M., Ramirez-Castellanos, J., Matsui, Y.: Superconductivity of M-12(n-1)n series of compounds prepared under high pressure. Czech J. Phys. 46, 1461–1462 (1996). https://doi.org/10.1007/BF02562845
Kawashima, T., Matsui, Y., Takayama-Muromachi, E.: New series of oxide superconductors, BSr2Can−1CunO2n+3 (n=3∼5), prepared at high pressure. Physica C 254(1–2), 131–136 (1995). https://doi.org/10.1016/0921-4534(95)00566-8
Yu, S., Okuda, Y., Kawashima, T., Takayama-Muromachi, E.: Critical current densities and irreversibility fields of high Tc superconductors, GaSr2Ca2Cu3O9 and BSr2Can-1CunO2n+3 (n= 3, 4). Jpn. J. Appl. Phys. 35(6R), 3378 (1996). https://doi.org/10.1143/JJAP.35.3378
Grumbach, M.P., Sankey, O.F., McMillan, P.F.: Properties of B2O: An unsymmetrical analog of carbon. Phys. Rev. B 52(22), 15807 (1995). https://doi.org/10.1103/PhysRevB.52.15807
Swenson, J., Börjesson, L., Howells, W.S.: Structure of borate glasses from neutron-diffraction experiments. Phys. Rev. B 52(13), 9310 (1995). https://doi.org/10.1103/PhysRevB.52.9310
Barrio, R.A., Castillo-Alvarado, F.L., Galeener, F.L.: Structural and vibrational model for vitreous boron oxide. Phys. Rev. B 44(14), 7313 (1991). https://doi.org/10.1103/PhysRevB.44.7313
Barrio, R.A., de Landa Castillo-Alvarado, F.: Model for the vibrational spectra of B2O3−xLi2O. Phys. Rev. B 46(21), 13779 (1992). https://doi.org/10.1103/PhysRevB.46.13779
Kieffer, J.: Mechanical degradation and viscous dissipation in B2O3. Phys. Rev. B 50(1), 17 (1994). https://doi.org/10.1103/PhysRevB.50.17
Vast, N., Bernard, S., Zerah, G.: Structural and electronic properties of liquid boron from a molecular-dynamics simulation. Phys. Rev. B 52(6), 4123 (1995). https://doi.org/10.1103/PhysRevB.52.4123
Saligan, P.P., Oikawa, Y., Koizumi, K., Mori, N., Ozaki, H.: Tc, onset, fluctuation and intergrain connection in the Bi2−xGexSr2CaCu2O8+δ. Czech J. Phys. 46, 1281–1282 (1996). https://doi.org/10.1007/BF02562755
Isobe, M., Kawashima, T., Kosuda, K., Matsui, Y., Takayama-Muromachi, E.: A new series of high-Tc superconductors AlSr2Can-1CunO2n+3 (n=4, Tc=110 K; n=5, Tc=83 K) prepared at high pressure. Physica C 234(1–2), 120–126 (1994). https://doi.org/10.1016/0921-4534(94)90063-9
Slater, P.R., Greaves, C., Slaski, M.: Synthesis and superconducting properties of the fluorite block system [Y/Ce]2Sr2−xBaxCu3O9−z substituted by oxy-anions (BO33−, SO42−, PO43−). Physica C 235, 741–742 (1994). https://doi.org/10.1016/0921-4534(94)91595-4
Ozturk, H., et al.: Effects of carbon-encapsulated nano boron addition on superconducting parameters of BSCCO. J. Alloys Compd. (2018). https://www.sciencedirect.com/science/article/pii/S0925838817335296
Aytekin, M.E., Özkurt, B.: The influence of nano-sized SnO2 do** on physical and magnetic properties of the Bi2Sr2-x(SnO2)xCa1Cu1.75Na0.25Oy superconductors. J. Supercond. Nov. Magn. 33, 965 (2020). https://doi.org/10.1007/s10948-019-05336-w
Zhang, S., Ma, X., Shao, B., Cui, L., Liu, G., Zheng, H., Liu, X., Feng, J., Li, C., Zhang, P.: Fabrication of multifilamentary powder in tube superconducting tapes of Bi-2223 with Sr deficient starting composition. Cryogenics 114, 103245 (2021). https://doi.org/10.1016/j.cryogenics.2020.103245
Habanjar, K., El Haj Hassan, F., Awad, R.: Physical and dielectric properties of (Bi, Pb)-2223 superconducting samples added with BaFe12O19 nanoparticles. Chem. Phys. Lett. 757, 137880 (2020). https://doi.org/10.1016/j.cplett.2020.137880
Masnita, M.J., Abd-Shukor, R.: Iron sulfide effects on AC susceptibility and electrical properties of Bi1.6Pb0.4Sr2CaCu2O8 superconductor. Results Phys. 17, 103177 (2020). https://doi.org/10.1016/j.rinp.2020.103177
Lojka, M., Antončík, F., Sedmidubský, D., Hlásek, T., Wild, J., Pavlů, J., Jankovský, O., Bartůnĕk, V.: Phase-stable segmentation of BSCCO high-temperature superconductor into micro-, meso-, and nano-size fractions. J. Mater. Res. Technol. 9, 12071 (2020). https://doi.org/10.1016/j.jmrt.2020.08.107
Anas, M.: The effect of PbF2 do** on the structural, electrical and mechanical properties of (Bi, Pb)–2223 superconductor. Chem. Phys. Lett. 742, 137033 (2020). https://www.sciencedirect.com/science/article/pii/S0009261419310140
Anas, M., El Makdah, M.H., El Dakdouki, M.H., et al.: Investigation of Physical Properties of (Nano-SmIG)/(Bi, Pb)-2212 Phase. J. Low Temp. Phys. 213, 191 (2023). https://doi.org/10.1007/s10909-023-02994-y
Dogruer, M., Yildirim, G., Terzioglu C.: Effect of Nd/Sr partial replacement on characteristic Bi-2223 phase and related fundamental superconducting parameters. Article 19 July 2022. https://springer.longhoe.net/10.1007/s10948-022-06330-5?fromPaywallRec=true
Guner, S.B., Zalaoglu, Y., Turgay, T., Ozyurt, O., Ulgen, A.T., Dogruer, M., Yildirim, G.: A detailed research for determination of Bi/Ga partial substitution effect in Bi-2212 superconducting matrix on crucial characteristic features. J. Alloys Compd. 772, 388 (2019). https://doi.org/10.1016/j.jallcom.2018.09.071
Akkurt, B., Erdem, U., Zalaoglu, Y., et al.: Evaluation of crystallographic and electrical-superconducting features of Bi-2223 advanced ceramics with vanadium addition. J. Mater. Sci. 32, 5035 (2021). https://doi.org/10.1007/s10854-021-05238-5
Erdem, U.: Homovalent Ho/Bi substitution effect on characteristic properties of Bi-2212 superconducting ceramics. J. Mater. Sci. Mater. Electron. 32, 28587 (2021). https://doi.org/10.1007/s10854-021-07236-z
Li, Z.B., Liu, G.Q., Jiao, G.F., Xu, X.Y., Hao, Q.B., Bai, L.F., Yao, K., Li, C.S.: Influence of the precursor powder composition on the microstructure and the critical current density of Bi2212 wires. J. Mater. Sci: Mater. Electron. 33(26), 21111 (2022). https://springer.longhoe.net/doi/10.1007/s10854-022-08914-2
Oloye, T.A., Matras, M., Jiang, J., Hossain, S.I., Su, Y., Trociewitz, U.P., Hellstrom, E.E., Larbalestier, D.C., Kametani, F.: Correlation of critical current density to quasi-biaxial texture and grain boundary cleanliness in fully dense Bi-2212 wires. Supercond. Sci. Technol. 34(3), 035018 (2021). https://doi.org/10.1088/1361-6668/abd575
Liu, G.Q., **, L.H., Xu, X.Y., Jiao, G.F., Zheng, H.L., Hao, Q.B., Cui, L.J., Yu, Z.M., Li, C.S.: Comparison of intermediate phase evolution in Bi-2212 powders prepared by spray pyrolysis and co-precipitation methods for high performance wires. Rare. Metal. Mat. Eng. 1, 92 (2022)
Hao, Q.B., Li, C.S., Xu, X.Y., Liu, G.Q., Jiao, G.F., Zheng, H.L., Zhang, S.N., Li, G.S., Zhang, C.P., Yu, Z.M., Bai, L.F., Feng, J.Q., Zhang, P.X.: Effect of pre-annealing on microstructure, mechanical properties and current-carrying properties of Bi-2212 wires. Fusion Eng. Des. 156, 111606 (2020). https://doi.org/10.1016/j.fusengdes.2020.111606
Angrisani Armenio, A., Leveratto, A., de Marzi, G., Traverso, A., Bernini, C., Celentano, G., Malagoli, A.: Investigation of transport mechanisms induced by filament-coupling bridges-network in Bi-2212 wires. Supercond. Sci. Technol. 35(3), 035002 (2022). https://doi.org/10.1088/1361-6668/ac45a0
Pothugantia, P.K., Bhogia, A., Kalimib, M.R., Reniguntla, P.: Physical and Optical Properties of Borobismuthate Glasses Containing Vanadium Oxide. Glass Phys. Chem. 46(2), 146 (2020)
Sasakura, H., Akagi, Y., Tsukui, S., et al.: Effect of Boron Substitution for Bi on Superconductivity of the Bi-2212 Phase in the Bi-Sr-Ca-Cu-O System. J. Supercond. Nov. Magn. 23, 437–441 (2010). https://doi.org/10.1007/s10948-009-0594-2
Fallah-Arani, H., Baghshahi, S., Sedghi, A., Stornaiuolo, D., Tafuri, F., Riahi-Noori, N.: Enhancement in superconducting properties of Bi2Sr2Ca1Cu2O8+θ (Bi-2212) by means of boron oxide additive. Physica C: Superconductivity and its Applications 548, 31–39 (2018). https://doi.org/10.1016/j.physc.2018.01.012
Chandra Sekhar, M., Gopalakrishna, B., Kumar, M.M., Suryanarayana, S.V.: Effect of Boron Do** in Bi-based 2223 Superconductors. Cryst. Res. Technol. 30(3), 345–352 (1995). https://doi.org/10.1002/crat.2170300312
Chen, H., Li, Y., Wang, M., Han, G., Shi, M., Zhao, X.: Smart metastructure method for increasing Tc of Bi(Pb)SrCaCuO high-temperature superconductors. J. Supercond. Novel Magn. 33, 3015–3025 (2020). https://doi.org/10.1007/s10948-020-05591-2
Margiani, N.G., Nikoghosyan, S.K., Adamia, Z.A., Dzanashvili, D.I., Kuzanyan, V.S., Papunashvili, N.A., Kvartskhava, I.G., Sarkisyan, A.G., Zhghamadze, V.V.: Enhancement of phase formation and critical current density in (Bi,Pb)-2223 superconductor by boron addition and ball milling. Int. J. Adv. Appl. Phys. Res. 1(1), 1–5 (2016). https://doi.org/10.15379/2408-977X.2016.01
Eremina, E.A., Kravchenko, A.V., Kazin, P.E., Tretyakov, Y.D., Jansen, M.: Influence of boron-containing dopants on the formation of superconducting phase in the system Bi(Pb)–Sr–Ca–Cu–O. Supercond. Sci. Technol. 11, 223 (1998)
Popov, A.G., Dovgopol, V.P., Olevsky, F.M., Melnikov, V.S., Pan, V.M.: The superconductivity of the Sb-doped Bi-Pb-Sr-Ca-Cu-O compounds. Supercond. Sci. Technol. 5, 654 (1992)
Cao, H., Zhang, S., Cui, Y., Zhi, L., Zhang, Y., Zhang, W., ... & Zhang, P.: Development of a novel fabrication technique for high-quality Bi-2223 bulks with high superconducting performance. Ceram. Int. (2024). https://doi.org/10.1016/j.ceramint.2024.01.125
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The author is grateful to Drs. V. S. Melnikov, A. G. Popov, A. L. Kasatkin, V. M. Pan, O. M. Fesenko, A. A. Kordyuk for all kinds of assistance and useful recommendations.
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Starrynets, S.M. The Effect of Boron on Equilibrium of Superconducting Phases in Bi-Pb-Sr-Ca-Cu-O System. J Supercond Nov Magn 37, 1079–1088 (2024). https://doi.org/10.1007/s10948-024-06767-w
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DOI: https://doi.org/10.1007/s10948-024-06767-w