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Having it both ways: delicate hierarchical structure and robust mechanical stability on micro/nanomaterials with mesoporous silica coating

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Abstract

Mesoporous silica (meso-SiO2) was coated on the micro/nanomaterials with hierarchical structure such as flowerlike Fe2O3, flowerlike MgO, SnO2 nanospheres, Co3O4 nanosheets and nanowires from a simple solution method. The structure of the nanomaterials and the silica coating before and after stirring in solution were characterizated by SEM and TEM. The results show that meso-SiO2 coating was an ideal method to enhance the structural stability of fragile nanomaterials. The catalysis stability of flowerlike MgO was also enhanced by the meso-SiO2 coating.

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References

  1. B.Z. Fang, J.H. Kim, M. Kim, J.S. Yu, Ordered hierarchical nanostructured carbon as a highly efficient cathode catalyst support in proton exchange membrane fuel cell. Chem. Mater. 21(5), 789–796 (2009)

    Article  CAS  Google Scholar 

  2. J.H. Lee, Gas sensors using hierarchical and hollow oxide nanostructures: overview. Sens. Actuator B Chem. 140(1), 319–336 (2009)

    Article  CAS  Google Scholar 

  3. Y.F. Zhao, M. Wei, J. Lu, Z.L. Wang, X. Duan, Biotemplated hierarchical nanostructure of layered double hydroxides with improved photocatalysis performance. ACS Nano 3(12), 4009–4016 (2009)

    Article  CAS  Google Scholar 

  4. L.Y. Jiang, X.L. Wu, Y.G. Guo, L.J. Wan, SnO2-based hierarchical nanomicrostructures: facile synthesis and their applications in gas sensors and lithium-ion batteries. J. Phys. Chem. C 113(32), 14213–14219 (2009)

    Article  CAS  Google Scholar 

  5. L.S. Zhong, J.S. Hu, H.P. Liang, A.M. Cao, W.G. Song, L.J. Wan, Self-assembled 3D flowerlike iron oxide nanostructures and their application in water treatment. Adv. Mater. 18(18), 2426–2431 (2006)

    Article  CAS  Google Scholar 

  6. S.W. Bian, Z. Ma, Z.M. Cui, L.S. Zhang, F. Niu, W.G. Song, Synthesis of micrometer-sized nanostructured magnesium oxide and its high catalytic activity in the Claisen-Schmidt condensation reaction. J. Phys. Chem. C 112(30), 11340–11344 (2008)

    Article  Google Scholar 

  7. L.S. Zhong, J.S. Hu, A.M. Cao, Q. Liu, W.G. Song, L.J. Wan, 3D flowerlike ceria micro/nanocomposite structure and its application for water treatment and CO removal. Chem. Mater. 19(7), 1648–1655 (2007)

    Article  CAS  Google Scholar 

  8. M.V. Walter, N. Cheval, O. Liszka, M. Malkoch, A. Fahmi, Hybrid one-dimensional nanostructures: one-pot preparation of nanoparticle chains via directed self-assembly of in situ synthesized discrete Au nanoparticles. Langmuir 28(14), 5947–5955 (2012). doi:10.1021/la3000526

    Article  CAS  Google Scholar 

  9. Z. Chen, J. Moore, G. Radtke, H. Sirringhaus, S. O’Brien, Binary nanoparticle superlattices in the semiconductor–semiconductor system: CdTe and CdSe. J. Am. Chem. Soc. 129(50), 15702–15709 (2007). doi:10.1021/ja076698z

    Article  CAS  Google Scholar 

  10. F.L. Yap, P. Thoniyot, S. Krishnan, S. Krishnamoorthy, Nanoparticle cluster arrays for high-performance SERS through directed self-assembly on flat substrates and on optical fibers. ACS Nano 6(3), 2056–2070 (2012). doi:10.1021/nn203661n

    Article  CAS  Google Scholar 

  11. L. Shi, C.J. Plumley, C. Berkland, Biodegradable nanoparticle flocculates for dry powder aerosol formulation. Langmuir 23(22), 10897–10901 (2007). doi:10.1021/la7020098

    Article  CAS  Google Scholar 

  12. W.M. Zhang, X.L. Wu, J.S. Hu, Y.G. Guo, L.J. Wan, Carbon coated Fe3O4 nanospindles as a superior anode material for lithium-ion batteries. Adv. Funct. Mater. 18(24), 3941–3946 (2008). doi:10.1002/adfm.200801386

    Article  CAS  Google Scholar 

  13. W.M. Zhang, J.S. Hu, Y.G. Guo, S.F. Zheng, L.S. Zhong, W.G. Song, L.J. Wan, Tin-nanoparticles encapsulated in elastic hollow carbon spheres for high-performance anode material in lithium-ion batteries. Adv. Mater. 20(6), 1160–1164 (2008). doi:10.1002/adma.200701364

    Article  CAS  Google Scholar 

  14. Z.M. Cui, Z. Chen, C.Y. Cao, W.G. Song, L. Jiang, Coating with mesoporous silica remarkably enhances the stability of the highly active yet fragile flower-like MgO catalyst for dimethyl carbonate synthesis. Chem. Commun. 49(54), 6093–6095 (2013). doi:10.1039/c3cc42504e

    Article  CAS  Google Scholar 

  15. C.Q. Chen, J. Qu, C.Y. Cao, F. Niu, W.G. Song, CuO nanoclusters coated with mesoporous SiO2 as highly active and stable catalysts for olefin epoxidation. J. Mater. Chem. 21(15), 5774–5779 (2011). doi:10.1039/c0jm04568c

    Article  CAS  Google Scholar 

  16. L.H. Hu, Q. Peng, Y.D. Li, Selective synthesis of Co3O4 nanocrystal with different shape and crystal plane effect on catalytic property for methane combustion. J. Am. Chem. Soc. 130(48), 16136–16137 (2008)

    Article  CAS  Google Scholar 

  17. A.J. Paula, D. Stefani, A.G. Souza, Y.A. Kim, M. Endo, O.L. Alves, Surface chemistry in the process of coating mesoporous SiO2 onto carbon nanotubes driven by the formation of Si–O–C bonds. Chem. Eur. J. 17(11), 3228–3237 (2011). doi:10.1002/chem.201002455

    Article  CAS  Google Scholar 

  18. P.J.E. Harlick, A. Sayari, Applications of pore-expanded mesoporous silica. 5. Triamine grafted material with exceptional CO(2) dynamic and equilibrium adsorption performance. Ind. Eng. Chem. Res. 46(2), 446–458 (2007). doi:10.1021/ie060774+

    Article  CAS  Google Scholar 

  19. C.S. Gill, B.A. Price, C.W. Jones, Sulfonic acid-functionalized silica-coated magnetic nanoparticle catalysts. J. Catal. 251(1), 145–152 (2007). doi:10.1016/j.jcat.2007.07.007

    Article  CAS  Google Scholar 

  20. Z. Chen, Z.-M. Cui, F. Niu, L. Jiang, W.-G. Song, Pd nanoparticles in silica hollow spheres with mesoporous walls: a nanoreactor with extremely high activity. Chem. Commun. 46(35), 6524–6526 (2010). doi:10.1039/c0cc01786h

    Article  CAS  Google Scholar 

  21. J. Lee, J.C. Park, H. Song, A nanoreactor framework of a Au@SiO2 yolk/shell structure for catalytic reduction of p-nitrophenol. Adv. Mater. 20(8), 1523 (2008). doi:10.1002/adma.200702338

    Article  CAS  Google Scholar 

  22. Z.F. Dou, C.Y. Cao, Y. Chen, W.G. Song, Fabrication of porous Co3O4 nanowires with high CO sensing performance at a low operating temperature. Chem. Commun. 50(94), 14889–14891 (2014). doi:10.1039/c4cc05498a

    Article  CAS  Google Scholar 

  23. X.L. **ao, X.F. Liu, H. Zhao, D.F. Chen, F.Z. Liu, J.H. **ang, Z.B. Hu, Y.D. Li, Facile shape control of Co3O4 and the effect of the crystal plane on electrochemical performance. Adv. Mater. 24(42), 5762–5766 (2012). doi:10.1002/adma.201202271

    Article  CAS  Google Scholar 

  24. G. Stoica, S. Abello, J. Perez-Ramirez, Synthesis of dimethyl carbonate by transesterification of ethylene carbonate over activated dawsonites. ChemSusChem 2(4), 301–304 (2009)

    Article  CAS  Google Scholar 

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Acknowledgments

We thank the financial supports from the National Basic Research Program of China (MOST 2013CB933000, 2014CB931802), National Natural Science Foundation of China (NSFC 51302008, 51502089), the Fundamental Research Funds for the Central Universities (2016MS03) and the Chinese Academy of Sciences.

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Correspondence to Zhi-Min Cui or Weiguo Song.

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Cui, ZM., Hao, J., Cao, CY. et al. Having it both ways: delicate hierarchical structure and robust mechanical stability on micro/nanomaterials with mesoporous silica coating. J Porous Mater 24, 103–108 (2017). https://doi.org/10.1007/s10934-016-0242-8

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