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Environmentally Benign Nanofiller-Aided Enhancement of the Electrochemical Performance of Flexible Lithium Polymer Composite

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Abstract

Flexible polymer electrolytes with efficient electrochemical characteristics were necessary to meet the requirements of smart electronics technology and foldable electronics. It is both important and difficult to design and construct a flexible lithium polymer electrolyte with higher ionic conductivity and better dielectric properties for use in electrochemical storage devices because of the need to increase storage capacity and electrochemical stability. This research describes the inclusion of Nickel oxide nanoparticles (n-NiO), which are environmentally benign, doped lithium flexible polymer electrolytes (n-FLPEs), via the solution-cast method with polymer matrices of poly (vinylidene fluoride-hexafluoropropylene) (PVdF-HFP), poly (ethylene oxide) (PEO), which is a biodegradable polymer, as well as Lithium trifluoromethanesulfonate (LiCF3SO3). When n-NiO is incorporated into FLPEs, the ionic conductivity increases by a factor of nearly four and a half. The εʹmax value increased four times, and ε″max value increased seventeen times owing to n-NiO inclusion. We used cyclic voltammetry (CV) and chronoamperometry (CA) to study the charge carrier buildup, ionic strength, and transference number in the optimal n-FLPE membrane. n-FLPEs have been shown to be electrochemically stable and capable of transporting ions due to chemical shifts in functional groups illustrated by X-ray photoelectron spectroscopy (XPS) investigations. The significance of the [υs(SO3)] mode in ionic conductivity has been extensively addressed. We analysed the FESD's discharging behaviour at a 0.04 C assessment, or an average current during discharge of 5.128 mA over 25 h.

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Acknowledgements

We would like to extend gratitude to The Chairman, the Board of Studies, and the Head of the Department at the Department of Physics, Osmania University. Special thanks to Dr. K. Uday Kumar, Assistant Professor, Department of Physics, NIT, Warangal for providing Chronoamperometry and Cyclic Voltammetry investigations. The Principal of Government Polytechnic in Gadwal, Sri T. Ram Mohan, has provided Mr. P. Ajay Kumar solely with encouragement and support throughout his time at this work.

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  1. Department of Physics, Osmania University, Hyderabad, Telangana, India

    P. Ajay Kumar & J. Siva Kumar

  2. Department of Technical Education, Government Polytechnic, Gadwal, Telangana, India

    P. Ajay Kumar

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PAK: conceptualization, methodology, investigation, validation, writing—original draft preparation, software, data curation, and editing. JSK: reviewing, editing, and supervision.

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Kumar, P.A., Kumar, J.S. Environmentally Benign Nanofiller-Aided Enhancement of the Electrochemical Performance of Flexible Lithium Polymer Composite. J Polym Environ 32, 1631–1649 (2024). https://doi.org/10.1007/s10924-023-03064-w

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