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Novel Layered Double Hydroxides@carboxymethyl Cellulose Composite Aerogel Towards Co(II) Absorption

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Abstract

Cobalt (Co) ion is a common heavy metal ion and the main metal ion in nuclear wastewater. However, the study on the absorption for Co(II) is not sufficient. Herein, a novel ES-layered double hydroxide (LDH) is prepared by intercalated ethylenediaminetetraacetic acid disodium salt (EDTA) and sodium dodecylbenzene sulfonate (SDBS) in a magnesium, iron pristine LDH, which is subsequently used for ES-LDH@carboxymethyl cellulose (CMC) composite aerogel. The results of Fourier transform infrared spectroscopy, X-ray diffraction spectra and thermogravimetric analysis shows successfully preparation of intercalated LDH. The pore morphology, specific surface area and pore size distribution of the composite aerogels are characterized by scanning electron microscope and Nitrogen-BET curves. The significantly improved adsorption capacity, adsorption kinetics and isotherms the absorbents on Co(II) are systematically revealed. This study thus provides an important understanding and path for dealing with the threat of Co(II).

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References

  1. Awual MR et al (2014) pH dependent Cu(II) and Pd(II) ions detection and removal from aqueous media by an efficient mesoporous adsorbent. Chem Eng J 236:100–109

    Article  CAS  Google Scholar 

  2. Juberg DR, Kleiman CF, Kwon SC (1997) Position paper of the American Council on Science and Health: lead and human health. Ecotoxicol Environ Saf 38(3):162–180

    Article  CAS  PubMed  Google Scholar 

  3. Wang J et al (2019) Selective removal of heavy metal ions in aqueous solutions by sulfide-selector intercalated layered double hydroxide adsorbent. J Mater Sci Technol 35(9):1809–1816

    Article  CAS  Google Scholar 

  4. **ao Y et al (2021) Functional covalent organic framework for exceptional Fe2+, Co(2+)and Ni2 + removal: An upcycling strategy to achieve water decontamination and reutilization as smoke suppressant and flame retardant simultaneously. Chemical Engineering Journal, 421

  5. Jiang C et al (2019) Adsorption performance of a polysaccharide composite hydrogel based on crosslinked glucan/chitosan for heavy metal ions. Compos Part B-Engineering 169:45–54

    Article  CAS  Google Scholar 

  6. Li S et al (2019) Graphene oxide based dopamine mussel-like cross-linked polyethylene imine nanocomposite coating with enhanced hexavalent uranium adsorption. J Mater Chem A 7(28):16902–16911

    Article  CAS  Google Scholar 

  7. Chen H et al (2020) Polydopamine modified cyclodextrin polymer as efficient adsorbent for removing cationic dyes and Cu2+. Journal of Hazardous Materials, 389

  8. Huang XQ et al (2017) Metal Sulfide Nanomaterials Based Adsorbents. Progress In Chemistry 29(1):83–92

    CAS  Google Scholar 

  9. Liang QW et al (2017) Fast and selective removal of Cr(VI) from aqueous solutions by a novel magnetic Cr(VI) ion-imprinted polymer. J Mol Liq 248:767–774

    Article  CAS  Google Scholar 

  10. Huang G et al (2016) Intercalation of thiacalix[4]arene anion via calcined/restored reaction into LDH and efficient heavy metal capture. J Mol Liq 220:346–353

    Article  CAS  Google Scholar 

  11. Santos RMM et al (2017) Thermal decomposition and recovery properties of ZnAl-CO3 layered double hydroxide for anionic dye adsorption: insight into the aggregative nucleation and growth mechanism of the LDH memory effect. J Mater Chem A 5(20):9998–10009

    Article  CAS  Google Scholar 

  12. Palza H, Delgado K, Govan J (2019) Novel magnetic CoFe2O4/layered double hydroxide nanocomposites for recoverable anionic adsorbents for water treatment. Applied Clay Science, 183

  13. Samuei S, Rezvani Z, Amani-Ghadim AR (2017) Comparative study of removal of reactive dye by LDHs: The effect of cation variety. Environ Prog Sustain Energy 36(2):372–381

    Article  CAS  Google Scholar 

  14. Razani S, Dadkhah A, Tehrani (2019) Development of new organic-inorganic, hybrid bionanocomposite from cellulose nanowhisker and Mg/Al-CO3-LDHfor enhanced dye removal. Int J Biol Macromol 133:892–901

    Article  CAS  PubMed  Google Scholar 

  15. Mallakpour S, Hatami M (2017) Biosafe organic diacid intercalated LDH/PVC nanocomposites versus pure LDH and organic diacid intercalated LDH: Synthesis, characterization and removal behaviour of Cd 2 + from aqueous test solution. Appl Clay Sci 149:28–40

    Article  CAS  Google Scholar 

  16. Shi M et al (2020) A novel heat-treated humic acid/MgAl-layered double hydroxide composite for efficient removal of cadmium: Fabrication, performance and mechanisms. Applied Clay Science, 187

  17. Sheng G et al (2016) Enhanced sequestration of Cr(VI) by nanoscale zero-valent iron supported on layered double hydroxide by batch and XAFS study. Chemosphere 148:227–232

    Article  CAS  PubMed  Google Scholar 

  18. Wang F, Guo Z (2019) Insitu growth of ZIF-8 on Co Al layered double hydroxide/carbon fiber composites for highly efficient absorptive removal of hexavalent chromium from aqueous solutions. Appl Clay Sci 175:115–123

    Article  CAS  Google Scholar 

  19. Chen H et al (2018) Preparation of MgAl-EDTA-LDH based electrospun nanofiber membrane and its adsorption properties of copper(II) from wastewater. J Hazard Mater 345:1–9

    Article  CAS  PubMed  Google Scholar 

  20. Hu B et al (2017) Macroscopic and spectroscopic insights into the mutual interaction of graphene oxide, Cu(II), and Mg/Al layered double hydroxides. Chem Eng J 313:527–534

    Article  CAS  Google Scholar 

  21. Yang XY, Al-Duri B (2005) Kinetic modeling of liquid-phase adsorption of reactive dyes on activated carbon. J Colloid Interface Sci 287(1):25–34

    Article  CAS  PubMed  Google Scholar 

  22. Ho YS (2006) Second-order kinetic model for the sorption of cadmium onto tree fern: A comparison of linear and non-linear methods. Water Res 40(1):119–125

    Article  CAS  PubMed  Google Scholar 

  23. Weber WJ, Morris JC (1963) Kinetics of Adsorption on Carbon from Solution. Journal of the Sanitary Engineering Division, 1963, Vol. 89, Issue 2, Pg. 31–60, 89(2): p. 31–60

  24. Ho YS, Chiu WT, Wang CC (2005) Regression analysis for the sorption isotherms of basic dyes on sugarcane dust. Bioresour Technol 96(11):1285–1291

    Article  CAS  PubMed  Google Scholar 

  25. Altın O, Ozbelge HO, Dogu T (1998) Use of general purpose adsorption isotherms for heavy metal-clay mineral interactions. J Colloid Interface Sci 198:130–140

    Article  Google Scholar 

  26. Memon JR et al (2009) Banana peel: A green and economical sorbent for the selective removal of Cr(VI) from industrial wastewater. Colloids and Surfaces B-Biointerfaces 70(2):232–237

    Article  CAS  PubMed  Google Scholar 

  27. Kumar PA, Ray M, Chakraborty S (2009) Adsorption behaviour of trivalent chromium on amine-based polymer aniline formaldehyde condensate. Chem Eng J 149(1–3):340–347

    Article  CAS  Google Scholar 

  28. Deng L et al (2017) Fabrication of a novel NiFe2O4/Zn-Al layered double hydroxide intercalated with EDTA composite and its adsorption behavior for Cr(VI) from aqueous solution. J Phys Chem Solids 104:79–90

    Article  CAS  Google Scholar 

  29. Zaghloul A et al (2021) Removal and Comparative Adsorption of Anionic Dye on Various MgAl synthetic Clay. Biointerface Res Appl Chem 11(6):14986–14997

    Article  CAS  Google Scholar 

  30. Zhang D et al (2017) Effective removal of brilliant green from aqueous solution with magnetic Fe3O4@SDBS@LDHs composites. Trans Nonferrous Met Soc China 27(12):2673–2681

    Article  CAS  Google Scholar 

  31. Huang D et al (2019) Cr(VI) removal from aqueous solution using biochar modified with Mg/Al-layered double hydroxide intercalated with ethylenediaminetetraacetic acid. Bioresour Technol 276:127–132

    Article  CAS  PubMed  Google Scholar 

  32. Qiu X, Wang W (2017) Removal of borate by layered double hydroxides prepared through microwave-hydrothermal method. J Water Process Eng 17:271–276

    Article  Google Scholar 

  33. Rahman S et al (2021) High capacity aqueous phosphate reclamation using Fe/Mg-layered double hydroxide (LDH) dispersed on biochar. J Colloid Interface Sci 597:182–195

    Article  CAS  PubMed  Google Scholar 

  34. Fu D et al (2021) Recovering heavy metals from electroplating wastewater and their conversion into Zn2Cr-layered double hydroxide (LDH) for pyrophosphate removal from industrial wastewater. Chemosphere, 271

  35. Pavel OD et al (2021) Catalytic behavior of Li-Al-LDH prepared via mechanochemical and co-precipitation routes for cyanoethylation reaction. Catal Today 366:227–234

    Article  CAS  Google Scholar 

  36. Huang Z et al (2021) Phosphotungstic acid intercalated Zn,Al-layered double hydroxides/ nanocellulose based 3D lightweight foam thermal insulation materials. Materials Research Express, 8(2)

  37. Huang C et al (2021) Preparation of iron-based metal-organic framework @cellulose aerogel by in situ growth method and its application to dye adsorption. Journal of Solid State Chemistry, 297

  38. Xu J et al The aminosilane functionalization of cellulose nanocrystal aerogel via vapor-phase reaction and its CO2 adsorption characteristics. Journal of Applied Polymer Science: p.12

  39. Shahzadi K et al (2021) Fire retardant cellulose aerogel with improved strength and hydrophobic surface by one-pot method. Journal of Applied Polymer Science, 138(16)

  40. Liao W et al (2019) On controlling aerogel microstructure by freeze casting. Compos Part B: Eng 173:107036

    Article  CAS  Google Scholar 

  41. Scotti KL, Dunand DC (2018) Freeze casting - A review of processing, microstructure and properties via the open data repository, FreezeCasting.net. Prog Mater Sci 94:243–305

    Article  CAS  Google Scholar 

  42. Albadarin AB et al (2017) Activated lignin-chitosan extruded blends for efficient adsorption of methylene blue. Chem Eng J 307:264–272

    Article  CAS  Google Scholar 

  43. Naushad M et al (2017) Nickel ferrite bearing nitrogen-doped mesoporous carbon as efficient adsorbent for the removal of highly toxic metal ion from aqueous medium. Chem Eng J 330:1351–1360

    Article  CAS  Google Scholar 

  44. Alqadami AA et al (2017) Novel Metal-Organic Framework (MOF) Based Composite Material for the Sequestration of U(VI) and Th(IV) Metal Ions from Aqueous Environment. ACS Appl Mater Interfaces 9(41):36026–36037

    Article  CAS  PubMed  Google Scholar 

  45. **g Q-x et al (2017) Behavior of ammonium adsorption by clay mineral halloysite. Trans Nonferrous Met Soc China 27(7):1627–1635

    Article  CAS  Google Scholar 

  46. Li J-J et al (2018) Synthesis and Phosphorus Adsorption of Coal-Fly-Ash Magnetic Adsorbents. Chin J Inorg Chem 34(8):1455–1462

    CAS  Google Scholar 

  47. El-Kamash AM, Zaki AA, El MA, Geleel (2005) Modeling batch kinetics and thermodynamics of zinc and cadmium ions removal from waste solutions using synthetic zeolite A. J Hazard Mater 127(1–3):211–220

    Article  CAS  PubMed  Google Scholar 

  48. Chien SH, Clayton WR (1980) Application of Elovich equation to the kinetics of phosphate release and sorption on soils. Soil Sci Soc Am J 44:265–268

    Article  CAS  Google Scholar 

  49. Altun T, Kar Y (2016) Removal of Cr (VI) from aqueous solution by pyrolytic charcoals. New Carbon Mater 31(5):501–509

    Article  CAS  Google Scholar 

  50. Ruan C-P, Ai K-L, Lu L-H (2016) An Acid-resistant Magnetic Co/C Nanocomposite for Adsorption and Separation of Organic Contaminants from Water. Chin J Anal Chem 44(2):224–230

    Article  CAS  Google Scholar 

  51. Akkaya G, Özer A (2005) Biosorption of Acid Red 274 (AR 274) on Dicranella varia: Determination of equilibrium and kinetic model parameters. Process Biochem 40(11):3559–3568

    Article  CAS  Google Scholar 

  52. Li J et al (2011) Effect of surfactants on Pb(II) adsorption from aqueous solutions using oxidized multiwall carbon nanotubes. Chem Eng J 166(2):551–558

    Article  CAS  Google Scholar 

  53. Ma J et al (2018) Fast adsorption of heavy metal ions by waste cotton fabrics based double network hydrogel and influencing factors insight. J Hazard Mater 344:1034–1042

    Article  CAS  PubMed  Google Scholar 

  54. Godiya CB et al (2019) Carboxymethyl cellulose/polyacrylamide composite hydrogel for cascaded treatment/reuse of heavy metal ions in wastewater. J Hazard Mater 364:28–38

    Article  CAS  PubMed  Google Scholar 

  55. Nasir MH et al (2007) Efficacy of modified distillation sludge of rose (Rosa centifolia) petals for lead(II) and zinc(II) removal from aqueous solutions. J Hazard Mater 147(3):1006–1014

    Article  CAS  PubMed  Google Scholar 

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Acknowledgements

The author appreciate the financial support from the National Natural Science Foundation of China (Grants 51603130), the International Clean Energy Talent of China Scholarship Council and ‘Young Scholars’ support plan of ** Wei & Yao **ao

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  1. Wang Liao
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  2. **nlei Long
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  3. Yao **ao
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Correspondence to Wang Liao.

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Liao, W., Long, X., Wei, Y. et al. Novel Layered Double Hydroxides@carboxymethyl Cellulose Composite Aerogel Towards Co(II) Absorption. J Polym Environ 30, 3779–3790 (2022). https://doi.org/10.1007/s10924-022-02431-3

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