Abstract
The objectives of this research were to evolve a gellan gum based double network (DN) hydrogel with high mechanical properties, and investigate its potential as an adsorbent to remove Al(III) ion. The double network hydrogel was synthesized for the first time in the literature, and Fourier Transform Infrared Spectroscopy and Scanning Electron Microscopy were utilized for structural and morphological characterization. Gellan gum hydrogel was characterized in terms of mechanical strength. The Al(III) removal behaviour studies were performed in 100 ppm aqueous Al(III) solution, and the kinetic data were correlated with the models of pseudo-first order and second-order. In addition, the equilibrium adsorption data were applied to Langmuir, Freundlich and Dubinin–Radushkevich (D–R) isotherm models. Moreover, the DN hydrogel adsorption capacities were calculated for the regeneration and reuse studies. The DN hydrogel could be used at least five times without significant decreasing in its adsorption capacity. In this work, the possibility of the mechanically developed strong DN hydrogel was observed for Al(III) ion removal behaviour.
Similar content being viewed by others
References
Saleh T-A, Tuzen M, Sarı A (2017) J Environ Chem Eng. 5(3):2853
Yüce M, Bilgin E, Köse K, Erol K, Köse D-A (2017) J Macromol Sci Part A 54(3):145
Özkahraman B (2018) J Polym Environ 26(3):1113
Wang Z, Wei X, Yang J, Suo J, Chen JLX, Zhao X (2016) Neurosci Lett 610:200
Yavuz H, Say R, Andaç M, Bayraktar N, Denizli A (2004) Biomagn Res Technol 2(5):1
Septhum C, Rattanaphani S, Bremner J-B, Rattanaphani V (2007) J Hazard Mater 148:185
Ahmed E-M (2015) J Adv Res 6(2):105
Bal A, Özkahraman B, Özbaş Z (2016) J Appl Polym Sci 133:43226
Negrini C-N, Tarsini P, Tanzi M-C, Fare S (2018) J Appl Polym Sci 136(8):47104
Pakdel P-M, Peighambardoust S-J (2018) J Environ Manag 217:123
Guilherme MR, Aouada FA, Fajardo AR, Martins AF, Paulino AT, Davi MFT, Rubira AF, Muniz EC (2015) Eur Polym J 72:365
Mun S, Kim Y-R, McClements D-J (2015) Food Chem 175:454
Peppas N-A, Blarcon S-V (2016) J Controll Release 240:142
Zhuang Y, Yu F, Chen H, Zheng J, Ma J, Chen J-J (2016) Mater Chem A 4:10885
Haque M-A, Kurokawa T, Gong J-P (2012) Polymer 53:1805
Zhuang Y, Yu F, Chen J, Ma J (2016) J Environ Chem Eng 4:147
Gong J-P (2010) Soft Matter 6:2583
Gong J-P, Katsuyama Y, Kurokawa T, Osada Y (2003) Adv Mater 15(14):1155
Yasuda K, Gong J-P, Katsuyama Y, Nakayama A, Tanabe Y, Kondo E, Ueno M, Osada Y (2005) Biomaterials 26:4468
Xu R, Zhou G, Tang Y, Chu L, Liu C, Zeng Z, Luo S (2015) Chem Eng J 275:179
Ma J, Zhou G, Chu L, Lin Y, Liu C, Luo S, Wei Y (2017) ACS Sustain Chem. Eng 5:843
Chu L, Liu C, Zhou G, Xu R, Tang Y, Zeng Z, Luo S (2015) J Hazard of Mater 300:153
Zhou G, Luo J, Liu C, Chu L, Crittenden J (2018) Water Res 131:246
Abdel-Halim E-S, Al-Deyab S-S (2014) React Funct Polym 75:1
Zeng G, Liu Y, Tang L, Yang G, Pang Y, Zhang Y, Zhou Y, Li Z, Li M, Lai M, He X, He Y (2015) Chem Eng J 259:153
Shin H, Olsen B-D, Khademhosseini A (2012) Biomaterials 33:3143
Shin H, Olsen B-D, Khademhosseini A (2014) J Mater Chem B 2:2508
Coutinho D-F, Sant S, Shakiba M, Wang B, Gomes M-E, Neves N-M, Reis R-L, Khademhosseini A (2012) J Mater Chem 22:17262
Jampen S, Britt I-J, Tung M-A (2000) Food Res Int 33:579
Silva GM, Rocha RFP, Costa MPM, Mello Ferreira IL, Delpech MC (2018) J Mol Liq 268:201
Weng L, Gouldstone A, Wu Y, Chen W (2008) Biomaterials 29:2153
Emik S (2014) React Funct Polym 75:63
Hamcerencu M, Desbrieres J, Khoukh A, Popa M, Riess G (2008) Carbohydr Polym 71:92
Karthika J-S, Vishalakshi B (2015) Int J Biol Macromol 81:648
Settimio P, Patrizia P, Inge D, Shuichiro K, Annabella V, Maria Antonietta C (2015) Int J Biol Macromol 72:1335
Lim S-L, Ishak A, Azwan M-L, Sains M (2015) Sains Malays 44(6):779
Fahmy A, Mix R, Schönhals A, Friedrich JF (2011) Plasma Process Polym 8:147
Milosavljevic N-B, Ristic M-D, Peric-Grujic A-A, Filipovic J-M, Strbac S-B, Rakocevic Z-L, Kalagasidis Krusic M-T (2011) Colloids Surf A 388:59
Pacelli S, Paolicelli P, Pepi F, Garzoli S, Polini A, Tita B, Vitalone A, Casadei M-A (2014) J Polym Res 21:409
Kasgoz H, Ozbas Z, Esen E, Sahin C-P, Gurdag G (2013) J Appl Polym Sci 130:4440
Lim SF, Lee AYW (2015) Environ Sci Pollut Res 22:10144
Özkahraman B, Özbaş Z, Öztürk-Bal A (2018) J Polym Environ 26:4303
Lagergren S (1898) Handlingar 24(4):1
Ho Y-S, McKay G (1999) Process Biochem 34(5):451
Langmuir I (1918) J Am Chem Soc 40:1361
Freundlich H-M-F (1906) J Phys Chem 57:385
Dubinin M-M, Radushkevich L-V (1947) Phys Chem Sect 55:331
Nakayama A, Kakugo A, Gong JP, Osada Y, Takai M, Erata T, Kawano S (2004) Adv Funct Mater 14:1124
Myung D, Koh W, Ko J, Hu Y, Carrasco M, Noolandi J, Ta CN, Frank CW (2007) Polymer 48:5376
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Özkahraman, B., Özbaş, Z. Removal of Al(III) Ions Using Gellan Gum-Acrylic Acid Double Network Hydrogel. J Polym Environ 28, 689–698 (2020). https://doi.org/10.1007/s10924-019-01636-3
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10924-019-01636-3