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Effect of Y2O3 Content on the Structural, Optical, and Shielding Properties of the Ca/Na Lead Borovanadate Multi-Component Oxide Glass

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Abstract

In this study, the melt-quenching method has been used to obtain a set of Ca/Na lead borovanadate multi-component glasses doped with different contents of Y2O3. The effect of Y2O3 content on the structural properties of the amorphous glass system was investigated by the XRD (X-ray diffraction patterns), FTIR (Fourier transform infrared spectra), and DSC (Differential scanning calorimetric analysis), where the morphology analysis of the samples was performed by TEM. The physical and shielding properties of the investigated glass system were also determined. Using UV–VIS data the optical parameters including optical absorption coefficients, optical band gap for direct and indirect electronic transitions, Urbach's energy, refraction (n) and absorption (K) indices, optical dielectric constant's real (ε1) and imaginary (ε2) parts surface energy loss (SELF) and volume energy loss (VELF), optical and electrical conductivity and nonlinear properties were evaluated. In relation to the thickness used, the HVL values of the studied glasses were found to be better than those of concrete. The analysis of obtained results indicates the mixed alkali lead borovanadate multi-component oxide glass doped with high Y2O3 content is suitable as a protective coating material for various electrical and optoelectronic devices, including solar cell units, sheets, smartphones, computers, and TV screens. Also, the Y2O3 samples may be useful for shielding applications.

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The original measurements and data analysis of this work will be available when required.

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Acknowledgements

The authors extend their appreciation to the Deputyship for Research & Innovation, Ministry of Education, in Saudi Arabia for funding this research work through the project number: (IFP-KKU-2020/9)”.

Author information

Authors and Affiliations

  1. Pharaohs-Higher Institute for Computer, Information Systems and Management, Giza, Egypt

    Hosam M. Gomaa

  2. Department of Physics, Faculty of Science, Al-Azhar University, Nasr City, Cairo, 11884, Egypt

    H. A. Saudi

  3. Laboratory of Nano-Smart Materials for Science and Technology (LNSMST), Department of Physics, Faculty of Science, King Khalid University, P.O. Box 9004, Abha, Saudi Arabia

    I. S. Yahia & H. Y. Zahran

  4. Research Center for Advanced Materials Science (RCAMS), King Khalid University, P.O. Box 9004, Abha, 61413, Saudi Arabia

    I. S. Yahia & H. Y. Zahran

  5. Nanoscience Laboratory for Environmental and Biomedical Applications (NLEBA), Semiconductor Lab., Metallurgical Lab.1., Department of Physics, Faculty of Education, Ain Shams University, Roxy, 11757, Cairo, Egypt

    I. S. Yahia & H. Y. Zahran

  6. Department of Physics, College of Arts and Sciences, Wadi Aldawaser, Prince Sattam Bin Abdulaziz University, AlKharj, Saudi Arabia

    B. M. A. Makram

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Contributions

HMG & HAS suggested the research idea, performed all calculations, measurements, data analysis, and wrote the section of results and discussion, BMAM wrote the introduction and experimental sections. HYZ & ISY performed and funded the experimental measurements and preparation process.

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Correspondence to Hosam M. Gomaa.

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Gomaa, H.M., Saudi, H.A., Yahia, I.S. et al. Effect of Y2O3 Content on the Structural, Optical, and Shielding Properties of the Ca/Na Lead Borovanadate Multi-Component Oxide Glass. J Inorg Organomet Polym 33, 981–994 (2023). https://doi.org/10.1007/s10904-023-02549-4

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