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A Three-Dimensional Cd(II)-Coordination Polymer: Crystal Structure, Electrochemiluminescent Property and Novel Topology

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Abstract

By employing 5-(pyridin-3-yl)-1H-pyrazole-3-carboxylic acid ligand, a new coordination polymer [Cd(HPPC−)2(H2O)2]n (1) has been prepared via the one-pot solvothermal reation with CdI2 and structurally characterized via elemental analysis, FT-IR spectroscopy, single-crystal X-ray diffraction analysis and X-ray powder diffraction. The results represented that 1 is a three-dimensional (3D) framework based on the 2D corrugated layers and Cd–O pillars, which can be considered as a (3,6)-connected trl topology with Schläfli symbol of {4·62}2{42·610·83}. In this work, the photoluminescence and electrogenerated chemiluminescence (ECL) behavior of complex 1 were investigated and thermal stability was confirmed by TGA analysis. Meanwhile, the Brunauer–Emmett–Teller measurement of 1 was also conducted to address the porosity of this 3D structure. Complex 1 exhibited high intense ECL in dimethyl sulfoxide and after eight circulations the ECL efficiency still remained stable, thus providing the possibility for construction of potential polymers ECL materials. In addition, Hirshfeld surface analysis for 1 mapped with various functions and 2D fingerprint plots revealed that the H···H and O···H contacts outnumbered the other contacts in 1 (25.3% and 23.0% of the total interactions, respectively).

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Acknowledgements

We acknowledge the financial support from Jiangsu Ainaji Neoenergy Science & Technology Co., Ltd. (8507040091), the Fundamental Research Funds for the Central Universities (3207045420), the National Natural Science Foundation of China (81703366) and the National Science Foundation for Cultivation of Bengbu University (2018GJPY03).

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Southeast University, Nan**g, 211189, People’s Republic of China

    Ling-Mei Zhang, Feng-Zhen Hua, Ke Zou, Yu-Meng Yang & Hong Zhao

  2. School of Materials and Chemical Engineering, Bengbu University, Bengbu, 233030, People’s Republic of China

    Chao Feng

  3. Institute of Medicinal Biotechnology, Chinese Academy of Medical Science and Peking Union Medical College, Bei**g, 100050, People’s Republic of China

    Guo-Ning Zhang & Yu-Cheng Wang

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  1. Ling-Mei Zhang
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Appendix A. Supplementary data

Appendix A. Supplementary data

CCDC 2,084,680 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/retrieving.html, or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: (+ 44) 1223–336-033; or e-mail: deposit@ccdc.cam.ac.uk.

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Zhang, LM., Hua, FZ., Feng, C. et al. A Three-Dimensional Cd(II)-Coordination Polymer: Crystal Structure, Electrochemiluminescent Property and Novel Topology. J Inorg Organomet Polym 32, 423–430 (2022). https://doi.org/10.1007/s10904-021-02121-y

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