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Condensation Product of 1-Naphthaldehyde and 3-Aminophenol: Fluorescent “on” Probe for Ce3+and “off” Probe for Dichromate (Cr2O72−)

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Abstract

A new probe (Z)-3-((naphthalen-1-ylmethylene)amino)phenol has been synthesized by condensation reaction between 1-naphthaldehyde and 3-aminophenol for the fluorescent sensing of Ce3+ by “on” mode and dichromate (Cr2O72−) by “off” mode. Metal ions—Ag+, Al3+, As3+, Ba2+, Ca2+, Cd2+, Ce4+, Co2+, Cr3+, Cr6+, Cu2+, Fe2+, Fe3+, Hg2+, K+, La+, Li+, Mg2+, Mn2+, Na+, Ni2+, Pb2+, Zn2+and anions Br−, C2O42−, CH3COO−, Cl−, CO32−, F−, H2PO4−, HCO3−, HF2−, HPO42−, I−, MnO4−, NO3−, OH−, S2−, S2O32−, SCN−, SO42− do not interfere. The limit of detection (LOD) for sensing Ce3+ and Cr2O72− ions are 1.286 × 10–7 M and 6.425 × 10–6 M, respectively.

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Acknowledgements

The authors thank DST, New Delhi for the MRP under SERB No. EMR/2016/001745 and ASTEC, Guwahati for financial support. DST is also thanked for financial support to the department through FIST program.

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Funding received from DST, New Delhi (EMR/2016/001745).

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Authors and Affiliations

  1. Department of Chemistry, Gauhati University, Guwahati, 781014, India

    Priyakshi Bordoloi & Diganta Kumar Das

  2. Department of Chemistry, Cotton University, Guwahati, 781001, India

    Ankur Kanti Guha

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PB has done all the experimental work; DKD has done analysis of the results and written the paper; AKG has done the computational part.

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Correspondence to Diganta Kumar Das.

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Bordoloi, P., Guha, A.K. & Das, D.K. Condensation Product of 1-Naphthaldehyde and 3-Aminophenol: Fluorescent “on” Probe for Ce3+and “off” Probe for Dichromate (Cr2O72−). J Fluoresc 32, 1189–1198 (2022). https://doi.org/10.1007/s10895-022-02927-0

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