Abstract
The present work describes the synthesis process of radar-absorbing material (RAM) composed of graphene nanoplatelets (GNP)-reinforced glass fabric-epoxy (EP/GF) hybrid composite laminates effective for both load bearing and microwave absorption in X-band (8.2–12.4 GHz). The fine and uniform dispersion of GNP was achieved by sonication, and RAM with GNP content 0.5, 1, and 3 wt% was fabricated by conventional hand-layup technique followed by compression molding. The coefficient of thermal expansion (CTE), tensile strength, and electrical conductivity of the hybrid composites were evaluated. The radar absorption properties of EP/GF/GNP RAM were investigated in the X-band. The RAM containing 0.5 wt% GNP showed lowest CTE which is about 83% lower than the CTE of neat epoxy resin. The addition of GNP in the EP/GF composite enhanced the tensile strength except for the composite with 0.5 wt% GNP. With increasing GNP loading, the electrical conductivity of EP/GF/GNP composites found to be increased. At 3 wt% GNP, the electrical conductivity of the composite enhanced by 4 orders of magnitude as compared to composite without GNP. The incorporation of GNP facilitated better microwave absorption for the EP/GF/GNP composite laminates. The excellent microwave absorption properties were seen in the composite reinforced with 0.5 wt% GNP, i.e., the measured RLmin is -18.31 dB at 9.98 GHz frequency with 90% EM waves absorption bandwidth of 1.45 GHz (9.25 to 10.7 GHz). Moreover, hybrid containing 3 wt% GNP exhibited a shielding effectiveness of more than 22 dB in the X-band.
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References
A. Kumar, S. Singh, I.O.P. Conf, Ser. Mater. Sci. Eng. 330, 012006 (2018)
J.-H. Oh, K.-S. Oh, C.-G. Kim, C.-S. Hong, Compos. B Eng. 35, 49 (2004)
B.D. Che, L.-T.T. Nguyen, B.Q. Nguyen, H.T. Nguyen, T.V. Le, N.H. Nguyen, Macromol. Res. 22, 1221 (2014)
I. Choi, J.G. Kim, I.S. Seo, D.G. Lee, Compos. Struct. 94, 3002 (2012)
S.K. Singh, M.J. Akhtar, K.K. Kar, Compos. B Eng. 167, 135 (2019)
F. Ghanbari, S. Mora Didehaghi, H. Mahdavi, Coat. Technol. Res. 17, 815 (2020)
A.V. Trukhanov, V.O. Turchenko, I.A. Bobrikov, S.V. Trukhanov, I.S. Kazakevich, A.M. Balagurov, J. Magn. Magn. Mater. 393, 253 (2015)
M.V. Zdorovets, A.L. Kozlovskiy, D.I. Shlimas, D.B. Borgekov, J. Mater. Sci. Mater. Electron. 32, 16694 (2021)
R.E. El-Shater, H. El Shimy, S.A. Saafan, M.A. Darwish, D. Zhou, K.C.B. Naidu, M.U. Khandaker, Z. Mahmoud, A.V. Trukhanov, S.V. Trukhanov, F. Fakhry, Mater. Adv. 4, 2794 (2023)
V.A. Silva, L.D.C. Folgueras, G.M. Cândido, A.L.D. Paula, M.C. Rezende, M.L. Costa, Mat. Res. 16, 1299 (2013)
Y.-J. Wan, L.-C. Tang, L.-X. Gong, D. Yan, Y.-B. Li, L.-B. Wu, J.-X. Jiang, G.-Q. Lai, Carbon 69, 467 (2014)
C. Zeng, S. Lu, X. **ao, J. Gao, L. Pan, Z. He, J. Yu, Polym. Bull. 72, 453 (2015)
F. Wang, L.T. Drzal, Y. Qin, Z. Huang, J. Mater. Sci. 51, 3337 (2016)
L. Vasconcelos Da Silva, S.H. Pezzin, M. Cerqueira Rezende, S. Campos Amico, Polym. Compos. 37, 2277 (2016)
M. Wu, H. He, Z. Zhao, X. Yao, J. Phys. D Appl. Phys. 33, 2398 (2000)
A.V. Trukhanov, M.A. Almessiere, A. Baykal, Y. Slimani, E.L. Trukhanova, A.V. Timofeev, V.G. Kostishin, S.V. Trukhanov, M. Sertkol, A. Ul-Hamid, Nano-Struct. Nano-Objects 33, 100941 (2023)
V. Pratap, A.K. Soni, A.M. Siddiqui, S.M. Abbas, R. Katiyar, N.E. Prasad, J. of Electron. Mater. 49, 3972 (2020)
B. Ribeiro, J.A.R. Corredor, L.F.D.P. Santos, N.A.S. Gomes, M.C. Rezende, J. Mater. Sci. Mater. Electron. 32, 1962 (2021)
F. Marra, J. Lecini, A. Tamburrano, L. Pisu, M.S. Sarto, IEEE Trans. Microwave Theory Techn. 68, 590 (2020)
K. Kunrath, E.F. Kerche, M.C. Rezende, S.C. Amico, Polym. Polym. Compos. 27, 262 (2019)
K. Rubrice, X. Castel, M. Himdi, P. Parneix, Materials 9, 825 (2016)
F. Nanni, P. Travaglia, M. Valentini, Compos. Sci. Technol. 69, 485 (2009)
B. Ribeiro, N.A.S. Gomes, M.C. Rezende, J. Mater. Sci. Mater. Electron. 32, 14494 (2021)
W. Zheng, Z. Yao, X. Zhang, J. Zhou, J. Mater. Sci. Mater. Electron. 33, 5127 (2022)
D.C. Silveira, N.A.S. Gomes, M.C. Rezende, E.C. Botelho, J. Mater. Sci. Mater. Electron. 31, 13095 (2020)
P. Panda, G. Mishra, S. Mantry, S.K. Singh, S.P. Sinha, J. Compos. Mater. 48, 3073 (2013)
X. Yao, I.A. Kinloch, M.A. Bissett, Front. Mater. 8, 773343 (2021)
N.C. Adak, S. Chhetri, N.H. Kim, N.C. Murmu, P. Samanta, T. Kuila, J. of Materi Eng and Perform 27, 1138 (2018)
U. Zaheer, A.A. Khurram, T. Subhani, Adv. Compos. Hybrid Mater. 1, 705 (2018)
W. Wang, Y. Wang, Y. Gao, Y. Zhao, J. Supercrit. Fluids 85, 95 (2014)
X. Wang, L. Zhang, RSC Adv. 9, 3693 (2019)
E. Rezaii, L. Nazmi, M. Mahkam, M. Ghaleh Assadi, MGC 20, 89 (2021)
A. Tezvergil, L.V.J. Lassila, P.K. Vallittu, Dent. Mater. 19, 471 (2003)
M. Suchitra, N.M. Renukappa, Macromol. Symp. 361, 117 (2016)
F. Tariq, M. Shifa, R.A. Baloch, Arab. J. Sci. Eng. 43, 5937 (2018)
G.V. Vigneshwaran, B.P. Shanmugavel, R. Paskaramoorthy, S. Harish, Arch. Civ. Mech. Eng. 20, 94 (2020)
Z. Wang, J. Luo, G. Zhao, AIP Adv. 4, 017139 (2014)
J. Liang, Y. Wang, Y. Huang, Y. Ma, Z. Liu, J. Cai, C. Zhang, H. Gao, Y. Chen, Carbon 47, 922 (2009)
Y. Wang, J. Yu, W. Dai, Y. Song, D. Wang, L. Zeng, N. Jiang, Polym. Compos. 36, 556 (2015)
A.S. Wajid, H.S.T. Ahmed, S. Das, F. Irin, A.F. Jankowski, M.J. Green, Macromol. Mater. Eng. 298, 339 (2013)
W. Zheng, W.G. Chen, Q. Zhao, S.X. Ren, Y.Q. Fu, Polymer 163, 171 (2019)
K. Li, R. Zhao, J. **a, G.-L. Zhao, Adv. Eng. Mater. 22, 1900780 (2020)
Q. Yuchang, W. Jie, W. Hongyu, L. Fa, Z. Wancheng, RSC Adv. 6, 80424 (2016)
J.A. Rojas, B. Ribeiro, M.C. Rezende, Carbon 160, 317 (2020)
B. Santhosi, K. Ramji, N.M. Rao, Polym. Polym. Compos. 29, 444 (2021)
W. Chen, X. Zheng, X. He, Y. Su, J. Wang, J. Yang, S. Chen, Z. Zheng, Polym. Test. 86, 106448 (2020)
A. Sotiropoulos, S. Koulouridis, A. Masouras, V. Kostopoulos, H.T. Anastassiu, Compos. B Eng. 217, 108896 (2021)
N. R. Abdelal, Def. Technol. S2214914723002325 (2023)
X. Gao, W. Yang, L. Cheng, Y. Ding, J. Zhan, J. Tan, J. Mater. Res. Technol. 13, 1759 (2021)
T. Khan, M.Y. Khalid, J.J. Andrew, M.A. Ali, L. Zheng, R. Umer, Compos. Commun. 44, 101767 (2023)
N. Abdelal, N. Dib, D. Young, A. Slanker, J. Mater. Sci. 57, 13928 (2022)
J. Shin, H. Jang, W. Choi, T. Song, C. Kim, W. Lee, J. Appl. Polym. Sci. 132, 42019 (2015)
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VSD acknowledge the Ministry of Education (MoE), Government of India for providing the research scholarship.
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R. K. Goyal conceived the idea of the study and edited the manuscript. V. S. Darekar prepared the composites, performed material characterization, and prepared a first draft of the manuscript.
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Darekar, V.S., Goyal, R.K. Development of single-layered radar-absorbing material composed of graphene nanoplatelets-reinforced glass fabric/epoxy hybrid composites for X-band. J Mater Sci: Mater Electron 35, 1167 (2024). https://doi.org/10.1007/s10854-024-12928-3
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DOI: https://doi.org/10.1007/s10854-024-12928-3