Abstract
The microstructural evolution and failure mode of Sn–3.0Ag–0.5Cu (SAC305)/Sn–37Pb hybrid ball grid array solder joints with various mixed percentages undergoing electromigration (EM) at 130 °C with a current density of 5 × 103 A/cm2 were investigated. The EM reliability of Ni/SAC305/Sn–37Pb/Ni hybrid solder joints increased with increasing mixed percentage. The hybrid solder joints with 25% mixed percentage had the worst EM reliability, showing cracks and occurrence of final failure at the cathode, since higher Pb content at the cathode decreased the melting point of solder while increased the local resistivity of solder and subsequently more Joule heat was generated to melt the local solder, and finally the hybrid solder joints failed in the liquid–solid EM failure mode. While for the hybrid solder joints with higher mixed percentages (50 and 100%), only a few voids occurred at the cathode. The growth rate of interfacial IMCs at the anode was the fastest for the hybrid solder joints with 100% mixed percentage, due to the lower diffusion activation energy of atoms; while at the cathode, the thickness of interfacial IMCs increased first and then decreased, due to the combined effect of chemical potential gradient-induced flux and EM-induced flux.
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References
M.L. Huang, F. Yang, Size effect model on kinetics of interfacial reaction between Sn–xAg–yCu solders and Cu substrate. Sci. Rep. 4, 7117 (2014). https://doi.org/10.1038/srep07117
M.S. Kim, M.S. Kang, J.H. Bang, C.W. Lee, S. Yoo, Interfacial reactions of fine-pitch Cu/Sn–3.5Ag pillar joints on Cu/Zn and Cu/Ni under bump metallurgies. J. Alloys Compd. 616, 394–400 (2014). https://doi.org/10.1016/j.jallcom.2014.07.124
B. Nandagopal, Z.Q. Mei, S. Teng, Microstructure and thermal fatigue life of BGAs with eutectic Sn–Ag–Cu Balls assembled at 210 °C with eutectic Sn–Pb solder paste. IEEE Electron. Compon. Technol. Conf. (2006). https://doi.org/10.1109/ECTC.2006.1645759
L.Y. Gao, X.W. Cui, F.F. Tian, Z.Q. Liu, Failure mechanism of the SnAgCu/SnPb mixed soldering process in a ball grid array structure. J. Electron. Mater. 49(10), 6223–6231 (2020). https://doi.org/10.1007/s11664-020-08372-8
M.L. Huang, Q. Zhou, N. Zhao, X.Y. Liu, Z.J. Zhang, Reverse polarity effect and cross-solder interaction in Cu/Sn–9Zn/Ni interconnect during liquid-solid electromigration. J. Mater. Sci. 49(4), 1755–1763 (2014). https://doi.org/10.1007/s10853-013-7862-z
J.W. Nah, K.W. Paik, J.O. Suh, K.N. Tu, Mechanism of electromigration-induced failure in the 97Pb–3Sn and 37Pb–63Sn composite solder joints. J. Appl. Phys. 94(12), 7560–7566 (2003). https://doi.org/10.1063/1.1628388
K.N. Tu, C.C. Yeh, C.Y. Liu, C. Chen, Effect of current crowding on vacancy diffusion and void formation in electromigration. Appl. Phys. Lett. 76, 988–990 (2000). https://doi.org/10.1063/1.125915
M.S. Park, S.L. Gibbons, R. Arróyave, Phase-field simulations of intermetallic compound evolution in Cu/Sn solder joints under electromigration. Acta Mater. 61, 7142–7154 (2013). https://doi.org/10.1016/j.actamat.2013.08.016
A. Choubey, M. Osterman, M. Pecht, Microstructure and intermetallic formation in SnAgCu BGA components attached with SnPb solder under isothermal aging. IEEE Trans. Device Mater. Reliab. 8(1), 160–167 (2008). https://doi.org/10.1109/TDMR.2007.915049
X.Z. Zeng, Thermodynamic analysis of influence of Pb contamination on Pb-free solder joint reliability. J. Alloy. Compd. 348, 184–188 (2005). https://doi.org/10.1016/S0925-8388(02)00855-1
V. Vasudevan, R. Coyle, R. Aspandiar, S. Tisdale, R. Kinyanjui, G. Long, Thermal cycling reliability, microstructural characterization and assembly challenges with backward compatible soldering of a large high density ball grid array. Electron. Compon. Technol. Conf. (2011). https://doi.org/10.1109/ECTC.2011.5898625
F.J. Wang, D.Y. Li, S. Tian, Z.J. Zhang, J.H. Wang, C. Yan, Interfacial behaviors of Sn–Pb, Sn–Ag–Cu Pb-free and mixed Sn–Ag–Cu/Sn–Pb solder joints during electromigration. Microelectron. Reliab. 73, 106–115 (2017). https://doi.org/10.1016/j.microrel.2017.04.031
C.E. Ho, R.Y. Tsai, Y.L. Lin, C.R. Kao, Effect of Cu concentration on the reaction between Sn–Ag–Cu solders and Ni. J. Electron. Mater. 31(6), 584–590 (2002). https://doi.org/10.1007/s11664-002-0129-0
J.W. Yoon, B.I. Noh, J.H. Yoon, H.B. Kang, S.B. Jung, Sequential interfacial intermetallic compound formation of Cu6Sn5 and Ni3Sn4 between Sn–Ag–Cu solder and ENEPIG substrate during a reflow process. J. Alloy. Compd. 509(9), L153–L156 (2011). https://doi.org/10.1016/j.jallcom.2011.01.015
K.N. Tu, Electromigration in stressed thin films. Phys. Rev. B 45(3), 1409–1413 (1992). https://doi.org/10.1103/PhysRevB.45.1409
K.C. Huang, F.S. Shieu, Y.H. Hsiao, C.Y. Liu, Ni interdiffusion coefficient and activation energy in Cu6Sn5. J. Electron. Mater. 43(17), 172–175 (2012). https://doi.org/10.1007/s11664-011-1821-8
S.K. Seo, S.K. Kang, M.G. Cho, D.Y. Shih, H.M. Lee, The crystal orientation of β-Sn grains in Sn–Ag and Sn–Cu solders affected by their interfacial reactions with Cu and Ni(P) under bump metallurgy. J. Electron. Mater. 38(12), 2461–2469 (2009). https://doi.org/10.1007/s11664-009-0902-4
Acknowledgements
This work was supported by the Science and Technology Plan of Liaoning Province [2022JH2/101300260] and the National Natural Science Foundation of China (Grant Nos. 52350321 and U1837208).
Funding
This work was supported by the Science and Technology Plan of Liaoning Province [2022JH2/101300260] and the National Natural Science Foundation of China (Grant Nos. 52350321 and U1837208).
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Yin, S.Q., Ren, J. & Huang, M.L. Electromigration behavior of Sn–3.0Ag–0.5Cu/Sn–37Pb hybrid solder joints with various mixed percentages for aerospace electronics. J Mater Sci: Mater Electron 35, 838 (2024). https://doi.org/10.1007/s10854-024-12609-1
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DOI: https://doi.org/10.1007/s10854-024-12609-1