Abstract
The current work focussed on the synthesis and characterization of Ni-doped ZnO/rGO heterostructures and evaluation of its photoactivity under UV light irradiation. The nanocomposite photocatalysts were prepared via green synthesis using P.dodecandra L’Herit (P.d) leaves extract. The X-ray diffraction analysis revealed that Ni and rGO were successfully incorporated into the wurtzite structure of ZnO nanocomposites. FESEM images showed a uniformed particle with the average size of about 10–20 nm for all samples. Later, the photocatalytic degradation of Rhodamine B (RhB) and methylene blue (MB) using the produced materials under visible light irradiation was examined. These results revealed that Ni-doped ZnO/rGO nanocomposites exhibited better photocatalytic performance than ZnO. However, Ni-doped ZnO/rGO composite achieved the highest degradation efficiency for RhB dye approximately 98% under UV light. Moreover, the composite exhibited higher rate constant (0.0156 min−1) and long-term stability. Altogether, the unique properties such as electron accepting and transporting properties of rGO in the nanocomposite enhanced photocatalytic activity by minimizing the charge carrier’s recombination rate. Overall, Ni-doped ZnO/rGO showed better results in antioxidant as well as photocatalytic activity against the pure ZnO NPs. Facile and low-temperature synthesis process with excellent degradation performance demonstrated that the Ni-doped ZnO/rGO nanocomposites have a great potential for wastewater treatment applications.
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References
G. Yan, L. Zhan, J. Peng, K. Jiang, Z. Jiang, S. Jiang, Preparation of a flower-like BiOCl/K-C3N4 p-n heterojunction and photodegradation formaldehyde and dyes. J. Electron. Mater. 51, 6228–6237 (2022)
G. Yan, K. Wang, Z. Jiang, K. Jiang, J. Peng, Xu. Jian, Flower-like ZnO/BiOI p–n heterojunction composites for enhanced photodegradation of formaldehyde and dyes. J. Mater. Sci. Mater. Electron. 33, 23064–23074 (2022)
G. Yan, Gu. Yefan, P. Qin, W. Deng, M. Lin, C. Huang, Y. Ning, Hu. Hongliang, L. **ao, Z-scheme K-C3N4/Ag/Ag3PMo12O40 heterojunction with improved visible light photodegradation of formaldehyde. Appl. Surf. Sci. 574, 151693 (2022)
M. Kheirabadi, M. Samadi, E. Asadian, Y. Zhou, C. Dong, J. Zhang, A. Moshfegh, Well-designed Ag/ZnO/3D graphene structure for dye removal: adsorption, photocatalysis and physical separation capabilities. J. Coll. Interface Sci. 537, 66–78 (2019)
M. Jothibas, C. Manoharan, S.J. Jeyakumar, P. Praveen, I.K. Punithavathy, J.P. Richard, Synthesis and enhanced photocatalytic property of Ni doped ZnS nanoparticles. Sol. Energy 159, 434–443 (2018)
M. Coto, S.C. Troughton, J. Duan, R.V. Kumar, T.W. Clyne, Development and assessment of photo-catalytic membranes for water purification using solar radiation. Appl. Surf. Sci. 433, 101–107 (2018)
O. Baytar, O. Sahin, H. Kilicvuran, S. Horoz, Synthesis, structural, optical and photocatalytic properties of Fe-alloyed CdZnS nanoparticles. J. Mater. Sci. Mater. Electron. 29, 4564–4568 (2018)
C. Hang, L. Yang, R. **, F. Wang, G. Li, Xu. Yanbin, Porous CeB 6 nanostructure: a step towards rapid adsorption of methylene blue. J. Aust. Ceram. Soc. 54, 423–428 (2018)
S. Ahmed, M. Ahmad, B.L. Swami, S. Ikram, A review on plants extract mediated synthesis of silver nanoparticles for antimicrobial applications: a green expertise. J. Adv. Res. 7, 17–28 (2016)
S.A. El-Hakam, F.T.A.L. Shorifi, R.S. Salama, S. Gamal, W.A. El-Yazeed, A.A. Ibrahim, A.I. Ahmed, Application of nanostructured mesoporous silica/ bismuth vanadate composite catalysts for the degradation of methylene blue and brilliant green. J. Mat. Res. Technol. 18, 1963–1976 (2022)
Y.K. Su, S.M. Peng, L.W. Ji, C.Z. Wu, W.B. Cheng, C.H. Liu, Ultraviolet ZnO nanorod photosensors. Langmuir 26, 603–606 (2010)
K. Mukae, K. Tsuda, I. Nagasawa, Capacitance-vs-voltage characteristics of ZnO varistors. J. Appl. Phys. 50, 4475–4476 (1979)
W. Zhong Lin, Zinc oxide nanostructures: growth, properties and applications. J. Phys. Condens. Matter 16, R829 (2004)
L. Yi, Y. Hou, H. Zhao, D. He, Z. Xu, Y. Wang, X. Xu, The photo- and electro-luminescence properties of ZnO: Zn thin film. Displays 21, 147–149 (2000)
E. Forgacs, T. Cserháti, G. Oros, Removal of synthetic dyes from wastewaters: a review. Environ. Int. 30, 953–971 (2004)
Ü. Özgür, Y.I. Alivov, C. Liu, A. Teke, M.A. Reshchikov, S. Doğan, V. Avrutin, S.J. Cho, H. Morkoç, A comprehensive review of ZnO materials and devices. J. Appl. Phys. 98, 041301 (2005)
P. Sutradhar, M. Saha, D. Maiti, Microwave synthesis of copper oxide nanoparticles using tea leaf and coffee powder extracts and its antibacterial activity. J. Nanostruct. Chem. 4, 86–91 (2014)
P. Mohanpuria, N.K. Rana, S.K. Yadav, Biosynthesis of nanoparticles: technological concepts and future applications. J. Nanopart. Res. 10, 507–517 (2008)
M. Pattanayak, P.L. Nayak, Ecofriendly green synthesis of iron nanoparticles from various plants and spices extract. Int. J. Plant Anim. Environ. Sci. 3, 68–78 (2013)
G. Hoag, J. Collins, J. Holcomb, J. Hoag, M. Nadagoudab, R. Varma, Degradation of bromothymol blue by ‘greener’ nano-scale zero-valent iron synthesized using tea polyphenols. J. Mater. Chem. 19, 8671–8677 (2009)
Q. Sun, X. Cia, J. Li, M. Zheng, Z. Chen, C.P. Yu, Green synthesis of silver nanoparticles using tea leaf extract and evaluation of their stability and antibacterial activity. Coll. Surf. A 444, 226–231 (2014)
N.A. Begum, S. Mondal, S. Basu, R.A. Laskar, D. Mandal, Biogenic synthesis of Au and Ag nanoparticles using aqueous solutions of Black Tea leaf extracts. Coll. Surf. B 80, 113–118 (2009)
M.N. Nadagouda, R.S. Varma, Green synthesis of silver and palladium nanoparticles at room temperature using coffee and tea extract. Green Chem. 10, 589–862 (2008)
S.H. Amirnordin, H.A. Rahman, H.Z. Abdullah, H. Taib, Effect of zeta potential of stanum oxide (SnO2) on electrophoretic deposition (EPD) on porous alumina. Adv. Mater. Res. Trans. Tech. Publ. 795, 334–337 (2013)
K. Huszla, K. Wysokowski, A. Zgoła-Grześkowiak, M. Staszak, M. Janczarek, T. Jesionowski, B. Wyrwas, UV-light photocatalytic degradation of non-ionic surfactants using ZnO nanoparticles. Int. J. Environ. Sci. Technol. 19, 173–188 (2022)
S. Thakur et al., Structural and optical study of nickel doped ZnO nanoparticles and thin films for dye sensitized solar cell applications. J. Optoelectron. Adv. Mater. 15(7–8), 989–994 (2013)
S. Gayathri, O.S.N. Ghosh, S. Sathiskumar, S. Sudhakara, J. Jayarmudu, S.S. Ray, A.K. Viswanath, Investigation of physicochemical properties of Ag doped ZnO nanoparticles prepared by chemical route. Res. Sci. 1, 8–13 (2015)
D.I. Son, B.W. Kwon, D.H. Park, W. Seo, Y. Yi, B. Angadi, C. Lee, W.K. Choi, Emissive ZnO–graphene quantum dots for white-light-emitting diodes. Nat. Nanotechnol. 7, 465–471 (2012)
S. Siamak, P. Haghshenas, A. Nemati, R. Simchi, C.-U. Kim, Photocatalytic and photoluminescence properties of ZnO/graphene quasi core-shell nanoparticles. Ceram. Int. 45, 8945–8961 (2019)
R. BoopathiRaja, M. Parthibavarman, Hetero-structure arrays of MnCo2O4 nanoflakes@nanowires grown on Ni foam: design, fabrication and applications in electrochemical energy storage. J. Alloy. Compd. 811, 152084 (2019)
R. BoopathiRaja, M. Parthibavarman, A. Nishara Begum, Hydrothermal induced novel CuCo2O4 electrode for high performance supercapacitor applications. Vacuum 165, 96–104 (2019)
R. BoopathiRaja, M. Parthibavarman, Desert rose like heterostructure of NiCo2O4/NF@PPy composite has high stability and excellent electrochemical performance for asymmetric super capacitor application. Electrochim. Acta 346, 136270 (2020)
R. BoopathiRaja, M. Parthibavarman, Reagent induced formation of NiCo2O4 with different morphologies with large surface area for high performance asymmetric supercapacitors. Chem. Phys. Lett. 755, 137809 (2020)
G. Park, L. Bartolome, K.G. Lee, S.J. Lee, D.H. Kim, T.J. Park, One-step sonochemical synthesis of a graphene oxide-manganese oxide nanocomposite for catalytic glycolysis of poly (ethylene terephthalate). Nanoscale 4, 3879–3885 (2012)
K.S.W. Sing, D.H. Everett, R.A.W. Haul, L. Moscou, R.A. Pierotti, J. Rouquerol et al., Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (recommendations 1984). Pure Appl. Chem. 57, 603–619 (1985)
Yi. Lin, R. Hong, H. Chen, D. Zhang, X. **jia, Green synthesis of ZnO-GO composites for the photocatalytic degradation of methylene blue. J. Nanomater. 2020, 4147357 (2020)
P. Molaei, M. Cheraghizade, R. Yousefi, Impact of rGO on photocatalytic performance of Cd-doped ZnO nanostructures synthesized via a simple aqueous co-precipitation route. Mater. Res. Express. 6, 025051 (2019)
H.A. Rafaie, N.S. Ismail, S.H.N.I.D. Dasiano, M.F. Kasim, N.I.T. Ramli, Z.A.M. Hir, M.H. Mamat, Constructing Ni doped ZnO/GO heterostrutures for enhanced sunlight-triggered degradation of methylene blue dye, Malaysian. J. Anal. Sci. 26, 520–531 (2022)
Z. Sun, H. Zhang, YuSu. Xuehua Shen, H. Liu, Yu. Hailin, Preparation of highly efficient Ni-doped layered perovskite grafted graphene oxide NixSr1-xTiO3-RGO heterojunction photocatalyst with enhanced visible-light photocatalytic activity for MB degradation. Mater. Chem. Phys. 273, 125119 (2021)
A.R. Malik, S. Nasir, F. Shaheen, M. Khalid, Y. Iqbal, A. Faisal et al., Green synthesis of RGO-ZnO mediated Ocimum basilicum leaves extract nanocomposite for antioxidant, antibacterial, antidiabetic and photocatalytic activity. J. Saudi Chem. Soc. 28, 101438 (2022)
S.J. Lee, T. Begildayeva, H.J. Jung, R. Koutavarapu, Y. Yiseul, M. Choi, M.Y. Choi, Plasmonic ZnO/Au/g-C3N4 nanocomposites as solar light active photocatalysts for degradation of organic contaminants in wastewater. Chemosphere 263, 128262 (2021)
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Bavaji, S.R., Ahamed, A.J. Green synthesis of rGO nanosheets wrapped on Ni-doped ZnO nanocomposite using P. dodecandra L’Herit (P.d) leaves extract and their photocatalytic and antioxidant performance. J Mater Sci: Mater Electron 35, 147 (2024). https://doi.org/10.1007/s10854-024-11956-3
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DOI: https://doi.org/10.1007/s10854-024-11956-3