Abstract
A bimetallic Zn–Co-ZIF derived from metal organic framework was successfully synthesized via simple co-precipitation method. The as-synthesized bimetallic MOF powder was then pyrolyzed at 600 °C, 700 °C, 800 °C, and 900 °C in N2 atmosphere, which changed the morphology and structure of the final product evidenced from field emission scanning electron microscopy and X-ray diffraction. The electrochemical results revealed that the change in elemental composition affected the specific capacity, cycling stability, and rate capability for each sample. The galvanostatic charge–discharge results showed that C600 achieved the highest specific capacity and rate capability compared to other samples heated at higher temperatures. On the other hand, C900, the sample heated at the highest temperature exhibited the best capacity retention after 50 cycles at 78% after the initial discharge whilst providing the lowest reversible discharge capacity at 45 mAh g−1.
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All data generated or analysed during this study are included in this article (and its supplementary information files) and available from the corresponding author on reasonable request.
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This work was supported by the Ministry of Higher Education Malaysia and Universiti Malaya, FRGS/1/2018/STG07/UM/02/8 and SATU Joint Research Grant, ST033-2020.
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Conception and design of study: SRM and ISI, acquisition of data: NSK, ISI, and NFMY, data curation and writing and preparation of the original draft: NSK and ISI, supervision: SRM and NHI, validation and writing, reviewing, and editing of the manuscript: SRM and NHI.
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Imaduddin, I.S., Majid, S.R., Kamaruddin, N.S. et al. Capacity determination of ZnCo0.26O1.63–N0.18C0.82 derived from bimetallic zeolitic imidazolate framework as anode in sodium-ion battery. J Mater Sci: Mater Electron 33, 25263–25273 (2022). https://doi.org/10.1007/s10854-022-09233-2
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DOI: https://doi.org/10.1007/s10854-022-09233-2