Abstract
This study sought to analyze the semi-solid behavior of commercial 332 aluminum alloy during thixoforming in a mechanical eccentric press (thixoforging). The solid–liquid transition, i.e., the working temperatures corresponding to 77%, 67% and 54% fraction solid, was characterized using differential scanning calorimetry and simulation with Thermo-Calc® software. The alloy was then heated to the working temperature, held at that temperature for 0, 30, 90 and 210 s and thixoforged. The microstructure was characterized in three distinct regions of the thixoforged product: the end, the curved region and the central region. Different microstructures were observed along the product: in the central region, a completely deformed coarse dendrite microstructure was observed while in the region at the end of the product the microstructure was partially globular because the material flows into the die cavity without suffering significant deformation. The thixoforged alloy with the lowest fraction solid (52%), which was achieved at 572 ± 2 °C, had the most refined structure and smallest dendrite arm spacing (approximately 90 µm), leading to a yield strength of 151 MPa, ultimate tensile strength of 233 MPa and elongation of 0.6. These mechanical characteristics can be considered excellent as no prior preparation or modification of the raw material was carried out. The material thus has excellent potential for use in both thixoforming and rheocasting.
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References
Spencer DB, Mehrabian R, Flemings MC (1972) Rheological behavior of Sn-15 pct Pb in the crystallization range. Metall Trans B 3:1925–1932. https://doi.org/10.1007/BF02642580
Flemings MC, Riek RG, Young KP (1976) Rheocasting. Mater Sci Eng 25:103–117. https://doi.org/10.1016/0025-5416(76)90057-4
Flemings MC (1991) Behavior of metal alloys in the semisolid state. Metall Trans A 22A:957–981. https://doi.org/10.1007/BF02661090
Atkinson HV (2005) Modelling the semisolid processing of metallic alloys. Prog Mater Sci 50:341–412. https://doi.org/10.1016/j.pmatsci.2004.04.003
Kapranos P, Ward PJ, Atkinson HV, Kirkwood DH (2000) Near net sha** by semi-solid metal processing. Mater Des 21:387–394. https://doi.org/10.1016/S0261-3069(99)00077-1
Zoqui EJ, Lourençato LA, Benati DM (2008) Thixoforming of aluminium-silicon alloys in a mechanical eccentric press. Sol State Phenom 141–143:517–522. https://doi.org/10.4028/www.scientific.net/SSP.141-143.517
Chiarmetta G (1996) Thixoforming of automobile components In: Kirkwood DH, Kapranos P (eds) Proceedings of the 4th international conference on semi-solid processing of alloys and composites, Sheffield, England, pp.204–207
Chiarmetta G (2000) Why thixo? In: Chiarmetta G, Rosso M (eds) Proceedings of the 6th international conference on the semi-solid processing of alloys and composites. Edimet, Turin, pp.15–21
Zoqui EJ (2014) Alloys for semisolid processing. In: Hashmi S (ed) Comprehensive materials processing. Elsevier, Amsterdam, pp 163–190
Zoqui EJ, Naldi MA (2011) Evaluation of the thixoformability of the A332 alloy (Al–9.5 wt %Si–2.5 wt %Cu). J Mater Sci 46(23):7558–7566. https://doi.org/10.1007/s10853-011-5730-2
Davies JR (1993), ASM specialty handbook: aluminum and aluminum alloys, ASM International, Materials Park, USA. ISBN: 978-0-87170-496-2
Torres LV, Zoqui EJ (2019) Microstructural characterization of the AA7004 and AA7075 thixoforging alloys in an eccentric press. Matéria (Rio J.) 24:e-12452. https://doi.org/10.1590/s1517-707620190003.0768
ASTM International (2018) B179–18 Standard specification for aluminum alloys in ingot and molten forms for castings from all casting processes. ASTM Int West Conshohocken. https://doi.org/10.1520/B0179-18
Hanim MAA, Chung SC, Chuan OK (2011) Effect of a two-step solution heat treatment on the microstructure and mechanical properties of 332 aluminium silicon cast alloy. Mater Des 32:2334–2338. https://doi.org/10.1016/j.matdes.2010.12.040
Tzimas E, Zavaliangos A (2000) Evaluation of volume fraction of solid in alloys formed by semisolid processing. J Mater Sci 35:5319–5330. https://doi.org/10.1023/A:1004890711322
Liu D, Atkinson HV, Jones H (2005) Thermodynamic prediction of thixoformability in alloys based on the Al–Si–Cu and Al–Si–Cu–Mg systems. Acta Mater 53:3807–3819. https://doi.org/10.1016/j.actamat.2005.04.028
ASTM International (2002) B557–02a Standard test methods of tension testing wrought and cast aluminum- and magnesium-alloy products. ASTM Int West Conshohocken. https://doi.org/10.1520/B0557-02A
ASTM International (2013) E112–13 Standard test methods for determining average grain size. ASTM Int West Conshohocken. https://doi.org/10.1520/E0112-13
Zhao Z, Chen Q, Hu C, Huang S, Wang Y (2009) Near-liquidus forging, partial remelting and thixoforging of an AZ91D + Y magnesium alloy. J Alloy Compd 485:627–636. https://doi.org/10.1016/j.jallcom.2009.06.053
Ammar H (2010) Influence of metallurgical parameters on the mechanical properties and quality indices of Al–Si–Cu–Mg and Al–Si–Mg casting alloys. PhD Dissertation, University of Quebec At Chicoutimi
Ferreira JPG, Lourençato LA, Roca AS, Fals HDC (2020) The influence of strontium on microstructural and rheological behavior of the semi-solid A380 aluminum alloy. Metall Mater Trans A 1:1–13. https://doi.org/10.1007/s11661-020-05996-7
Kearns MA, Thistlethwaite SR, Cooper PS (1996) Recent advances in understanding the mechanism of aluminum grain refinement by TiBAl master alloys In: Hale, W (ed) Annual meeting and exhibition of the Minerals, Metals and Materials Society (TMS). North Wales (United Kingdom), Anaheim
Legoretta EC, Atkinson HV, Jones H (2008) Cooling slope casting to obtain thixotropic feedstock I: observations with a transparent analogue. J Mater Sci 43:5448–5455. https://doi.org/10.1007/s10853-008-2828-2
Legoretta EC, Atkinson HV, Jones H (2008) Cooling slope casting to obtain thixotropic feedstock II: observations with A356 alloy. J Mater Sci 43:5456–5469. https://doi.org/10.1007/s10853-008-2829-1
Bolouri A, Shahmiri M, Kang CG (2012) Coarsening of equiaxed microstructure in the semisolid state of aluminum 7075 alloy through SIMA processing. J Mater Sci 47:3544–3553. https://doi.org/10.1007/s10853-011-6200-6
Eskin GI (1998) Ultrasonic treatment of light alloy melts. Gordon and Breach Science Publishers, Amsterdam
Taghavi F, Saghafian H, Kharrazi YHK (2009) Study on the effect of prolonged mechanical vibration on the grain refinement and density of A356 aluminum alloy. Mater Des 30:1604–1611. https://doi.org/10.1016/j.matdes.2008.07.032
Acknowledgements
The authors would like to thank the Brazilian research funding agencies FAPESP (São Paulo Research Foundation—Projects 2015/22143-3 and 2018/11802-4), CNPq (National Council for Scientific and Technological Development—Project CNPq PQ 304921-2017-3) and CAPES (Federal Agency for the Support and Improvement of Higher Education) for providing financial support for this study. The authors are also indebted to the Faculty of Mechanical Engineering at the University of Campinas and to the Federal Institute of Education, Science and Technology of São Paulo—Bragança Paulista campus (IFSP) for the practical support very kindly provided.
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Torres, L.V., Naldi, M.A. & Zoqui, E.J. Thixoforging of 332 aluminum alloy in a mechanical eccentric press. J Mater Sci 56, 11541–11556 (2021). https://doi.org/10.1007/s10853-021-06024-8
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DOI: https://doi.org/10.1007/s10853-021-06024-8