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One-step fabrication of HNBR/MIL-100 composites via selective hydrogenation of acrylonitrile-butadiene rubber with a catalyst derived from MIL-100(Fe)

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Abstract

Heterogeneous catalyst has been widely used in hydrogenation process. However, the heterogeneous catalytic hydrogenation of acrylonitrile-butadiene rubber (NBR) usually requires high temperature and thus remains a significant challenge. Herein, an efficient MIL-100(Fe)-supported palladium (Pd) catalyst was successfully synthesized via a solution impregnation method without stabilizing and reducing agents and applied in selective hydrogenation of NBR with an in situ reduction process. Specifically, Pd2+ could be directly reduced to Pd0 during hydrogenation process, which would further get involved in the hydrogenation of NBR rapidly. As-obtained Pd(II)/MIL-100(Fe) composite exhibited highly catalytic activity toward NBR at room temperature due to the well-dispersed and small-sized Pd nanoparticles and the high external surface area of MIL-100(Fe). Furthermore, the hydrogenation degree of hydrogenated acrylonitrile-butadiene rubber (HNBR) could reach to 93% even at 10 °C. More importantly, the MIL-100/HNBR composites with improved mechanical properties could be also prepared by the one-step method through using the remained catalysts in HNBR substrate.

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Acknowledgements

This work was funded by State Key Laboratory of Organic–Inorganic Composites, Bei**g University of Chemical Technology.

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Authors and Affiliations

  1. State Key Laboratory of Organic-Inorganic Composites, Bei**g University of Chemical Technology, Bei**g, 100029, China

    Naiqun Yao, Yingdong Zhang, Ruichen Zhang, Liqun Zhang & Dongmei Yue

  2. Key Laboratory of Bei**g City On Preparation and Processing of Novel Polymer Materials, Bei**g, 100029, China

    Liqun Zhang & Dongmei Yue

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  1. Naiqun Yao
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Correspondence to Dongmei Yue.

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Yao, N., Zhang, Y., Zhang, R. et al. One-step fabrication of HNBR/MIL-100 composites via selective hydrogenation of acrylonitrile-butadiene rubber with a catalyst derived from MIL-100(Fe). J Mater Sci 56, 326–336 (2021). https://doi.org/10.1007/s10853-020-05227-9

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