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Pulsed electrodeposition of Ni-W coatings predicts microhardness via gene expression programming

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Abstract

In the present work, a robust prediction model is presented for predicting Ni-W coating microhardness using powerful soft computing techniques, i.e., Gene expression programming (GEP). We considered the W content in coating (wt.%), pH, time (min) of coating bath, frequency (kHz) and current density (mA cm−2) of pulse current electrodeposition as input variables and the microhardness of Ni-W coatings as output variables. To achieve this, we had three main steps: (i) 63 experiments were collected to construct models; (ii) Creating training and testing phases based on 50 and 13 data and (iii) A new model is built and compared using correlation coefficients (R2), root relative square errors (RRSE), and relative standard errors (RSE). Using the results, GEP-6 was found to be the appropriate model for predicting the microhardness of Ni-W coatings with R2 = 0.9926, RSE = 0.0077, and RRSE = 0.0880. Additionally, sensitivity analysis results indicated that pulse electrodeposition's frequency, current density, and time of coating bath were the most effective parameters in determining microhardness.

Graphical abstract

Comparison of actual (experimented) versus predicted microhardness for Ni-W coatings using GEP-2, GEP-4, and GEP-6 models in (a) training, and (b) testing.

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Abbreviations

GEP:

Gene expression programming

RSE:

Relative standard error

MEMS:

Microelectromechanical systems

KMO:

Kaiser mayer olkin

PVD:

Physical vapor deposition

GA:

Genetic algorithm

CVD:

Chemical vapor deposition

GP:

Genetic programming

R2 :

Correlation coefficient

ET:

Expression tree

RRSE:

Root relative square error

SA:

Sensitivity analysis

References

  1. Wasekar NP, Hebalkar N, Jyothirmayi A, Lavakumar B, Ramakrishna M, Sundararajan G (2020) Influence of pulse parameters on the mechanical properties and electrochemical corrosion behavior of electrodeposited Ni-W alloy coatings with high tungsten content. Corros Sci 165:108409

    CAS  Google Scholar 

  2. Bathini L, Prasad M, Wasekar NP (2022) Development of continuous compositional gradient Ni-W coatings utilizing electrodeposition for superior wear resistance under sliding contact. Surf Coat Technol 445:128728

    CAS  Google Scholar 

  3. Kumar KA, Kalaignan GP, Muralidharan V (2012) Pulse electrodeposition and characterization of nano Ni–W alloy deposits. Appl Surf Sci 259:231–237

    Google Scholar 

  4. Krishnan R, Kennedy CJ, Jayakrishnan S, Sriveeraraghavan S, Natarajan S, Venkatakrishnan P (1995) Electrodeposition of nickel-tungsten alloys. Met Finish 93:33–39

    CAS  Google Scholar 

  5. Donten M, Cesiulis H, Stojek Z (2000) Electrodeposition and properties of Ni-W, Fe-W and Fe-Ni-W amorphous alloys. A comparative study. Electrochim Acta 45:3389–3396

    CAS  Google Scholar 

  6. Uppada S, Koona R, Chintada VB, Koutavarapu R (2022) Influence of heat treatment on crystal structure, microhardness and corrosion resistance of bilayer electroless Ni-P-SiC/Ni-P-Al2O3 coatings. SILICON 2022:1–11

    Google Scholar 

  7. Chintada VB, Gurugubelli TR, Koutavarapu R (2022) An investigation over the effect of the reducing agent on the properties of the ZnO-reinforced Ni–P coatings. J Mater Sci: Mater Electron 33:950–958

    CAS  Google Scholar 

  8. Yari S, Dehghanian C (2013) Deposition and characterization of nanocrystalline and amorphous Ni-W coatings with embedded alumina nanoparticles. Ceram Int 39:7759–7766

    CAS  Google Scholar 

  9. Wasekar NP, Latha SM, Ramakrishna M, Rao D, Sundararajan G (2016) Pulsed electrodeposition and mechanical properties of Ni-W/SiC nano-composite coatings. Mater Des 112:140–150

    CAS  Google Scholar 

  10. Allahyarzadeh M, Aliofkhazraei M, Rezvanian A, Torabinejad V, Rouhaghdam AS (2016) Ni-W electrodeposited coatings: characterization, properties and applications. Surf Coat Technol 307:978–1010

    CAS  Google Scholar 

  11. Argañaraz MQ, Ribotta S, Folquer M, Zelaya E, Llorente C, Ramallo-López J, Benítez G, Rubert A, Gassa L, Vela M (2012) The chemistry and structure of nickel–tungsten coatings obtained by pulse galvanostatic electrodeposition. Electrochim Acta 72:87–93

    Google Scholar 

  12. Slavcheva E, Mokwa W, Schnakenberg U (2005) Electrodeposition and properties of NiW films for MEMS application. Electrochim Acta 50:5573–5580

    CAS  Google Scholar 

  13. Farzaneh M, Zamanzad-Ghavidel M, Raeissi K, Golozar M, Saatchi A, Kabi S (2011) Effects of Co and W alloying elements on the electrodeposition aspects and properties of nanocrystalline Ni alloy coatings. Appl Surf Sci 257:5919–5926

    CAS  Google Scholar 

  14. Borgia C, Scharowsky T, Furrer A, Solenthaler C, Spolenak R (2011) A combinatorial study on the influence of elemental composition and heat treatment on the phase composition, microstructure and mechanical properties of Ni-W alloy thin films. Acta Mater 59:386–399

    CAS  Google Scholar 

  15. Bicelli LP, Bozzini B, Mele C, D’Urzo L (2008) Corrosion behavior of titanium and nickelbased alloys in HCl and HCl+ H2S environments. Int J Electrochem Sci 3:356–408

    CAS  Google Scholar 

  16. Shojaei Z, Khayati GR, Darezereshki E (2022) Review of electrodeposition methods for the preparation of high-entropy alloys. Int J Miner Metall Mater 29:1683–1696

    CAS  Google Scholar 

  17. Muralidhara H, Naik YA (2008) Electrochemical deposition of nanocrystalline zinc on steel substrate from acid zincate bath. Surf Coat Technol 202:3403–3412

    CAS  Google Scholar 

  18. Królikowski A, Płońska E, Ostrowski A, Donten M, Stojek Z (2009) Effects of compositional and structural features on corrosion behavior of nickel–tungsten alloys. J Solid State Electrochem 13:263–275

    Google Scholar 

  19. Elias L, Hegde AC (2015) Electrodeposition of laminar coatings of Ni-W alloy and their corrosion behaviour. Surf Coat Technol 283:61–69

    CAS  Google Scholar 

  20. Landolt D, Marlot A (2003) Microstructure and composition of pulse-plated metals and alloys. Surf Coat Technol 169:8–13

    Google Scholar 

  21. Younes-Metzler O, Zhu L, Gileadi E (2003) The anomalous codeposition of tungsten in the presence of nickel. Electrochim Acta 48:2551–2562

    CAS  Google Scholar 

  22. Mizushima I, Tang PT, Hansen HN, Somers MA (2006) Residual stress in Ni-W electrodeposits. Electrochim Acta 51:6128–6134

    CAS  Google Scholar 

  23. Chandrasekar M, Pushpavanam M (2008) Pulse and pulse reverse plating—conceptual, advantages and applications. Electrochim Acta 53:3313–3322

    CAS  Google Scholar 

  24. Sarangi CK, Sahu BP, Mishra BK, Mitra R (2020) Pulse electrodeposition and characterization of graphene oxide particle-reinforced Ni-W alloy matrix nanocomposite coatings. J Appl Electrochem 50:265–279

    CAS  Google Scholar 

  25. He T, He Y, Li H, Fan Y, Yang Q, He Z (2018) A comparative study of effect of mechanical and ultrasound agitation on the properties of pulse electrodeposited Ni-W/MWCNTs composite coatings. J Alloy Compd 743:63–72

    CAS  Google Scholar 

  26. Nazari A (2012) Experimental study and computer-aided prediction of percentage of water absorption of geopolymers produced by waste fly ash and rice husk bark ash. Int J Miner Process 110:74–81

    Google Scholar 

  27. Ferreira C (2002) Gene expression programming in problem solving. Soft computing and industry. Springer, pp 635–653

    Google Scholar 

  28. Ghaferi Z, Raeissi K, Golozar M, Edris H (2011) Characterization of nanocrystalline Co–W coatings on Cu substrate, electrodeposited from a citrate-ammonia bath. Surf Coat Technol 206:497–505

    CAS  Google Scholar 

  29. de Lima-Neto P, Correia AN, Santana RA, Colares RP, Barros EB, Casciano PN, Vaz GL (2010) Morphological, structural, microhardness and electrochemical characterisations of electrodeposited Cr and Ni-W coatings. Electrochim Acta 55:2078–2086

    Google Scholar 

  30. Panagopoulos C, Plainakis G, Lagaris D (2011) Nanocrystalline Ni-W coatings on copper. Mater Sci Eng, B 176:477–479

    CAS  Google Scholar 

  31. Hou KH, Sheu HH, Ger MD (2014) Preparation and wear resistance of electrodeposited Ni-W/diamond composite coatings. Appl Surf Sci 308:372–379

    CAS  Google Scholar 

  32. Vamsi M, Wasekar NP, Sundararajan G (2017) Influence of heat treatment on microstructure and mechanical properties of pulse electrodeposited Ni-W alloy coatings. Surf Coat Technol 319:403–414

    CAS  Google Scholar 

  33. Shreeram DD, Li S, Bedekar V, Cong H, Doll G (2017) Effect of reverse pulse time on electrodeposited Ni-W coatings. Surf Coat Technol 325:386–396

    CAS  Google Scholar 

  34. Wasekar NP, Bathini L, Sundararajan G (2018) Tribological behavior of pulsed electrodeposited Ni-W/SiC nanocomposites. J Mater Eng Perform 27:5236–5245

    CAS  Google Scholar 

  35. Liu B, Yan S, He Y, He T, Li H, He Y, Song R, Zhang Z, Liu D, Shangguan J (2022) Research for electrodeposited superhydrophobic Ni-W-WS2 coating and its anticorrosion and wear resistance. Colloids Surf A Physicochem Eng Aspect 655:130236

    CAS  Google Scholar 

  36. Shi X, Zhang Z, Dai L, Lv Y, Xu Z, Yin Y, Liao Z, Wei G (2022) Effect of Al2O3 nanoparticles and heat treatment on the wear resistance of electrodeposited Ni-W/Al2O3 composite coatings. J Mater Eng Perform 31:3094–3106

    CAS  Google Scholar 

  37. Hair J, Black W, Babin B, Anderson R, Tatham R (1998) Multivariate data analysis. Prentice hall, Upper Saddle River, pp 207–219

    Google Scholar 

  38. Faradonbeh RS, Monjezi M (2017) Prediction and minimization of blast-induced ground vibration using two robust meta-heuristic algorithms. Eng Comput 33:835–851

    Google Scholar 

  39. Ross SM (2020) Introduction to probability and statistics for engineers and scientists. Academic press

    Google Scholar 

  40. Kaiser HF (1974) An index of factorial simplicity. Psychometrika 39:31–36

    Google Scholar 

  41. Sofroniou N, Hutcheson GD (1999) The multivariate social scientist. Multivar Soc Sci 1999:1–288

    Google Scholar 

  42. Mahdavi Jafari M, Khayati GR (2018) Prediction of hydroxyapatite crystallite size prepared by sol–gel route: gene expression programming approach. J Sol-Gel Sci Technol 86:112–125

    CAS  Google Scholar 

  43. Koza JR (1994) Genetic programming II: automatic discovery of reusable programs. MIT press

    Google Scholar 

  44. Ferreira C (2006) Gene expression programming: mathematical modeling by an artificial intelligence. Springer

    Google Scholar 

  45. Ferreira C (2001) Gene expression programming: a new adaptive algorithm for solving problems. Cornell University

    Google Scholar 

  46. Kolle MK, Shajahan S, Basu A (2020) Effect of electrodeposition current and pulse parameter on surface mechanical and electrochemical behavior of Ni-W alloy coatings. Metall Mater Trans A 51:3721–3731

    CAS  Google Scholar 

Download references

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This research was performed by Mrs. Shojaei. Furthermore, Mrs. Shojaei was responsible for writing the manuscript. Also, Dr.Khayati acted as a supervisor in this research.

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Correspondence to Z. Shojaei.

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Shojaei, Z., Khayati, G.R. Pulsed electrodeposition of Ni-W coatings predicts microhardness via gene expression programming. J Appl Electrochem 53, 1433–1447 (2023). https://doi.org/10.1007/s10800-023-01844-9

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