Abstract
We performed dynamic mechanical analysis (DMA) on nitrocellulose (NC) plasticized by an insensitive plasticizer N-butyl-N-(2-nitroxy-ethyl)nitramine (Bu-NENA). NC/Bu-NENA blend shows two mechanical relaxation processes in the temperature ranges of − 50 to − 40 °C and 30 ~ 40 °C, and their variations with deformation frequencies were studied. To explore further the effect of temperature on relaxation, the binary mixture model of NC/Bu-NENA was constructed, and molecular dynamic simulations were conducted. The simulated mean square displacements (MSD) show abrupt increase in the temperature range of − 50 to − 40 °C and 30 ~ 40 °C, which are consistent with those of the two relaxation processes observed in the DMA curves. Moreover, the free volume (Vfree) and torsion energy obtained from molecular dynamic simulations exhibit distinct increase at the temperature above 30 °C and − 50 °C respectively, reflecting the sudden enhancements on the mobility of polymer chain elements and the rotation of molecular bonds. Furthermore, the radial distribution function (RDF) associated with the intermolecular interactions reveals that the intensities of both hydrogen bond and van der Waals forces decrease with the increase of temperature, which is responsible for the decrease of storage modulus at high temperature. These computational and experimental studies reveal guidance to strengthening the NC base propellants in broad temperature range.
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This work is financially supported by the National Science Foundation of China (21703167), and National defense basic science foundation of China (61407200204)
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Qi, X., Yan, N., Li, H. et al. New insight into dynamic mechanical relaxation in N-butyl-N-(2-nitroxy-ethyl) nitramine plasticized nitrocellulose through molecular dynamic simulations. Cellulose 29, 1307–1314 (2022). https://doi.org/10.1007/s10570-021-04374-9
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DOI: https://doi.org/10.1007/s10570-021-04374-9