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Growth Features of Gas Hydrate Films at Interface of Liquid Carbon Dioxide with Water and Sodium Dodecyl Sulfate Solution in Teflon and Steel Cuvettes

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Chemistry and Technology of Fuels and Oils Aims and scope

The growth features of a hydrate film at the interface between liquid carbon dioxide and pure water and sodium dodecyl sulfate solution were studied. It was found in all cases that in a Teflon cell a hydrate film is formed on the contact surface of the liquid phases, after which no visible changes are observed for an indefinitely long time. In experiments with pure water in a steel cell after the water-CO2 surface is covered with hydrate the hydrate film is slowly deformed as a result of growth along the line of contact between the hydrate and the cell wall. In experiments with a solution of sodium dodecyl sulfate the deformation of the hydrate film is much more pronounced, and the degree of conversion of the water into hydrate is increased significantly.

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Acknowledgments

The investigation was supported by the Russian Science Foundation, grant No. 23-29-00830, https://rscf.ru/project/23-29-00830/.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, Siberian Branch, Novosibirsk, Russia

    A. K. Sagidullin & A. Yu. Manakov

  2. Kazan Federal University, Kazan, Russia

    A. K. Sagidullin & A. Yu. Manakov

Authors
  1. A. K. Sagidullin
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  2. A. Yu. Manakov
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Correspondence to A. K. Sagidullin.

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Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 4, pp. 50–56, July – August, 2023.

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Sagidullin, A.K., Manakov, A.Y. Growth Features of Gas Hydrate Films at Interface of Liquid Carbon Dioxide with Water and Sodium Dodecyl Sulfate Solution in Teflon and Steel Cuvettes. Chem Technol Fuels Oils 59, 718–725 (2023). https://doi.org/10.1007/s10553-023-01575-9

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