Abstract
Nitrogen isotopic composition and abundances of eleven ordinary chondrites (OCs), Mahadevpur (H4/5), Didwana-Rajod (H5), Monahans (1998) (H5), Portales Valley (H6), Itawa Bhopji (L3/5), Jodiya (L5), Jalangi (L5/6), Kaprada (L5/6), Devri-Khera (L6), Katol (L6) and Bruderheim (L6) have been determined. Ranges of nitrogen isotopic composition, \(\delta ^{15}\)N for individual subgroups of OCs in bulk samples are, H: −41.0 ± 5.8\(\permil \) to +75.1 ± 10.9\(\permil \), L: −168.7 ± 23.9\(\permil \) to +64.2 ± 3.4\(\permil \), LL: −74.0 ± 24.0\(\permil \) to +30.9 ± 5.4\(\permil \), respectively. Trapped N shows 15N enriched isotopic signatures in the bulk ordinary chondrites (H, L, and LL) compared to the solar wind and are also distinct from that of phase-Q. The ranges of nitrogen concentration in bulk samples of OCs are, H: 0.37 ppm to 39.2 ppm, L: 0.25 ppm to 39.4 ppm and LL: 0.35 ppm to 12.7 ppm, respectively. No significant correlation between N isotopic composition and N concentration in OCs is observed with their petrologic type.
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References
Aleon, J.: Multiple origins of nitrogen isotopic anomalies in meteorites and comets. Astrophys. J. 722, 1342–1351 (2010)
Alexander, C.M.O’D., Russell, S.S., Arden, J.W., Ash, R.D., Grady, M.M., Pillinger, C.T.: The origin of chondritic macromolecular organic matter: a carbon and nitrogen isotope study. Meteorit. Planet. Sci. 33, 603–622 (1998)
Alexander, C.M.O’D., Cody, G.D., De Gregorio, B.T., Nittler, L.R., Stroud, R.M.: The nature, origin and modification of insoluble organic matter in chondrites, the major source of Earth’s C and N. Chem. Erde 77, 227–256 (2017)
Alexander, C.M.O’D., McKeegan, K.D., Altwegg, K.: Water reservoirs in small planetary bodies: meteorites, asteroids, and comets. Space Sci. Rev. 214, 36 (2018)
Anders, E., Grevesse, N.: Abundances of the elements: meteoritic and solar. Geochim. Cosmochim. Acta 53, 197–214 (1989)
Becker, R.H., Clayton, R.N., Mayeda, T.K.: Characterization of lunar nitrogen components. In: Proceedings of Lunar Science Conference 7th, pp. 441–458 (1976)
Bhandari, N., Murty, S.V.S., Shukla, P.N., Shukla, A.D., Mahajan, R.R., Sarin, M.M., Srinivasan, G., Suthar, K.M., Sisodia, M.S., Jha, S., Bischoff, A.: Itawa Bhopji (L3-5) chondrite regolith breccias: fall, classification, and cosmogenic records. Meteorit. Planet. Sci. 37, 549–563 (2002)
Bhandari, N., Murty, S.V.S., Shukla, P.N., Mahajan, R.R., Shukla, A.D., Suthar, K.M., Parthasarathy, G., Paliwal, B.S.: Bhawad LL6 chondrite: chemistry, petrology, noble gases, nuclear tracks, and cosmogenic radionuclides. Meteorit. Planet. Sci. 40, 1015–1021 (2005)
Bhandari, N., Murty, S.V.S., Shukla, P.N., Mahajan, R.R., Shukla, A.D., Lashkari, G., Sisodia, M.S., Tripathi, R.P., Parthasarathy, G., Verma, H.C., Franchi, I.A.: Ararki (L5) chondrite: the first meteorite find in Thar desert of India. Meteorit. Planet. Sci. 43, 761–770 (2008)
Bhandari, N., Murty, S.V.S., Mahajan, R.R., Parthasarathy, G., Shukla, P.N., Sisodia, M.S., Rai, V.K.: Kaprada L(5/6) chondrite: chemistry, petrography, noble gases and nuclear tracks. Planet. Space Sci. 57, 2048–2052 (2009)
Bland, P.A., Berry, F.J., Smith, T.B., Skinner, S.J., Pillinger, C.T.: The flux of meteorites to the Earth and weathering in hot desert ordinary chondrites finds. Geochim. Cosmochim. Acta 60, 2053–2059 (1996)
Bogard, D.D., Garrison, D.H., Masarik, J.: The Monahans chondrite and halite: Argon-39/argon-40 age, solar gases, cosmic-ray exposure ages, and parent body regolith neutron flux and thickness. Meteorit. Planet. Sci. 36, 107–122 (2001)
Bonal, L., Huss, G.R., Krot, A.N., Nagashima, K., Ishii, H.A., Bradley, J.P.: Highly 15N-enriched chondritic clasts in the CB/CH-like meteorite Isheyevo. Geochim. Cosmochim. Acta 74, 6590–6609 (2010)
Bonino, G., Bhandari, N., Murty, S.V.S., Mahajan, R.R., Suthar, K.M., Shukla, A.D., Shukla, P.N., Cini Castagnoli, G., Taricco, C.: Solar and galactic cosmic-ray records of the Fermo (H) chondritic regolith breccias. Meteorit. Planet. Sci. 36, 831–839 (2001)
Bottke, W.F., Nesvorny, D., Grimm, R.E., Morbidelli, A., O’Brien, D.P.: Iron meteorites as remnants of planetesimals formed in the terrestrial planet region. Nature 439, 821–824 (2006)
Briani, G., Gounelle, M., Marrocchi, Y., Mostefaoui, S., Leroux, H., Quirico, E., Meibom, A.: Pristine extraterrestrial material with unprecedented nitrogen isotopic variation. Proc. Natl. Acad. Sci. 106, 10522–10527 (2009)
Busemann, H., Young, A.F., Alexander, C.M.O’D., Hoppe, P., Mukhopadhyay, S., Nittler, L.R.: Interstellar chemistry recorded in organic matter from primitive meteorites. Science 312, 727–730 (2006)
Clayton, D.D., Dwek, E., Woosley, S.E.: Isotopic anomalies and proton irradiation in the early solar system. Astrophys. J. 214, 300–315 (1977)
Das, J.P., Murty, S.V.S.: Trapped nitrogen in individual chondrules: nature of chondrule precursors and clues to formation mechanisms. J. Geophys. Res. 114, E01008 (2009)
Deligny, C., Füri, E., Deloule, E.: Origin and timing of volatile delivery (N, H) to the angrite parent body: constraints from in situ analyses of melt inclusions. Geochim. Cosmochim. Acta 313, 243–256 (2021)
Des Marais, D.J.: Light element geochemistry and spallogenesis in lunar rocks. Geochim. Cosmochim. Acta 47, 1769–1781 (1983)
Dhingra, D., Bhandari, N., Shukla, P.N., Murty, S.V.S., Mahajan, R.R., Ballabh, G.M., Lashkari, G., Shukla, A.D., Parthasarathy, G.: Spectacular fall of the Kendrapara H5 chondrite. Meteorit. Planet. Sci. 39, A121–A132 (2004)
Fisenko, A.V., Verchovsky, A.B., Semjonova, L.F.: Kinetics of Ar, 21Ne, C and N release during stepped combustion of small chondrules from the Saratov (L4) meteorite. 45th Lunar and Planetary Science Conference #1743.pdf (2014)
Füri, E., Marty, B.: Nitrogen isotope variations in the solar system. Nat. Geosci. 8, 515–522 (2015)
Füri, E., Deloule, E., Dalou, C.: Nitrogen abundance and isotope analysis of silicate glasses by secondary ionization mass spectrometry. Chem. Geol. 493, 327–337 (2018)
Gail, H.-P., Trieloff, M.: Thermal history modelling of the L chondrite parent body. Astron. Astrophys. 628, A77 (2019)
Geiss, J., Bochsler, P.: Nitrogen isotopes in the solar system. Geochim. Cosmochim. Acta 46, 529–548 (1982)
Ghosh, S., Murty, S.V.S., Shukla, P.N., Shukla, A.D., Mahajan, R.R., Bhandari, N., Pant, N.C., Ghosh, J.B., Shome, S.: Fall, classification and cosmogenic records of the Sabrum (LL6) chondrite. Meteorit. Planet. Sci. 37, 439–448 (2002)
Grady, M.M., Wright, I.P.: Elemental and isotopic abundances of carbon and nitrogen in meteorites. Space Sci. Rev. 106, 231–248 (2003)
Grewal, D.S., Dasgupta, R., Marty, B.: A very early origin of isotopically distinct nitrogen in inner solar system protoplanets. Nat. Astron. 5, 356–364 (2021)
Hashizume, K., Nakaoka, Y.T.: Q-nitrogen in CO3 chondrites. 61st Annual Meteoritical Society Meeting. Abstract #5085 (1998)
Hashizume, K., Sugiura, N.: Nitrogen isotopes in bulk ordinary chondrites. Geochim. Cosmochim. Acta 59, 4057–4069 (1995)
Hashizume, K., Marty, B., Wieler, R.: Analysis of nitrogen and argon in single lunar grains: towards a quantification of the asteroidal contribution to planetary surfaces. Earth Planet. Sci. Lett. 202, 201–216 (2002)
Hayes, J.M.: Organic constituents of meteorites – a review. Geochim. Cosmochim. Acta 31, 1395–1440 (1967)
Henke, S., Gail, H.-P., Trieloff, M., Schwarz, W.H., Kleine, T.: Thermal history modelling of the H chondrite parent body. Astron. Astrophys. 545, A135 (2012)
Jehin, E., Manfroid, J., Hutsemekers, D., Arpigny, C., Zucconi, J.M.: Isotopic ratios in comets: status and perspective. Earth Moon Planets 105, 167–180 (2009)
Kerridge, J.F.: Carbon, hydrogen and nitrogen in carbonaceous chondrites: abundances and isotopic compositions in bulk samples. Geochim. Cosmochim. Acta 49, 1707–1714 (1985)
Kohout, T., Haloda, J., Halodova, P., Meier, M.M.M., Maden, C., Busemann, H., Laubenstein, M., Caffee, M.W., Welten, K.C., Hopp, J., Trieloff, M., Mahajan, R.R., Naik, S., Trigo-Rodriguez, J.M., Moyano-Cambero, C.E., Oshtrakh, M.I., Maksimova, A.A., Chukin, A.V., Semionkin, V.A., Karabanalov, M.S., Felner, I., Petrova, E.V., Brusnitsyna, E.V., Grokhovsky, V.I., Yakovlev, G.A., Gritsevich, M., Lyytinen, E., Moilanen, J., Kruglikov, N.A., Ishchenko, A.V.: Annama H chondrite - mineralogy, physical properties, cosmic ray exposure, and parent body history. Meteorit. Planet. Sci. 52, 1525–1541 (2017)
Korochantseva, E.V., Verchovsky, A.B., Buikin, A.I., Lorents, K.A., Korochantsev, A.V.: Isotopic composition of noble gases, nitrogen and carbon in the Ozerki new L chondrite. Geochem. Int. 58, 1239–1256 (2020)
Kothari, B.K., Goel, P.S.: Total nitrogen in meteorites. Geochim. Cosmochim. Acta 38, 1493–1507 (1974)
Kring, D.A., Hill, D.H., Gleason, J.D., Britt, D.T., Consolmagno, G.J., Farmer, M., Wilson, S., Haag, R.: Portales valley: a meteoritic sample of the brecciated and metal-veined floor of an impact crater on an H-chondrite asteroid. Meteorit. Planet. Sci. 34, 663–669 (1999)
Kung, C., Clayton, R.N.: Nitrogen abundance and isotopic composition in stony meteorites. Earth Planet. Sci. Lett. 38, 421–435 (1978)
Lewis, J.S., Prinn, R.G.: Kinetic inhibition of CO and N2 reduction in the solar nebula. Astrophys. J. 238, 357–364 (1980)
Lodders, K.: Solar system abundances and condensation temperatures of the elements. Astrophys. J. 591, 1220–1247 (2003)
Mahajan, R.R.: Noble gases, nitrogen and cosmic ray exposure age of the Sulagiri chondrite. Geosci. Front. 8, 205–210 (2017)
Mahajan, R.R.: Exposure ages, noble gases and nitrogen in the ordinary chondrite Karimati (L5). Earth Moon Planets 124, 3–13 (2020a)
Mahajan, R.R.: Noble gases and nitrogen in metal from the ordinary chondrites Katol (L6), Itawa Bhopji (L3-5) and Portales Valley (H6). Astrophys. Space Sci. 365, 130 (2020b)
Mahajan, R.R.: Laser microprobe noble gases and nitrogen analysis of chondrules from the Dhajala chondrite. Meteorit. Planet. Sci. 55, 2141–2156 (2020c)
Mahajan, R.R.: Ordinary chondrites: nitrogen systematics. The 11th Symposium on Polar Science. National Institute of Polar Research. Abstract#OA_Majajan_00012_01 (2020d)
Mahajan, R.R.: Noble gases, cosmic ray exposure and radiogenic ages in selected ordinary chondrites. Adv. Space Res. 70, 2112–2132 (2022)
Mahajan, R.R.: Investigating noble gases and nitrogen in Zag (H3-6) and ALH 77216 (L3.7-3.9): the ordinary chondrites with solar type neon and argon. Polar Sci. 37, 100966 (2023a)
Mahajan, R.R.: Argon and Nitrogen Signatures in Metal Separates from Portales Valley (H6) Chondrite. The 14th Symposium on Polar Science. National Institute of Polar Research, Tokyo (2023b). Abstract #, OA-O-12.pdf
Mahajan, R.R., Murty, S.V.S.: Laser microprobe for the study of noble gases and nitrogen in single grains: a case study of individual chondrules from the Dhajala meteorite. Proc. Indian Acad. Sci., Earth Planet. Sci. 112, 113–127 (2003)
Mahajan, R.R., Murty, S.V.S.: Sources of excess nitrogen in lunar soils: clues from N and argon in lunar meteorite Y983885. In: 30th Symposium on Antarctica Meteoritics, pp. 50–51. National Institute of Polar Research, Tokyo (2006)
Mahajan, R.R., Varela, M.E., Joron, J.J.L.: Santa Lucia (2008) (L6) chondrite, a resent fall: composition, noble gases, nitrogen and cosmic ray exposure are. Earth Moon Planets 117, 65–76 (2016)
Mahajan, R.R., Laridhi Ouazaa, N., Ray, D., Naik, S.: Noble gases, nitrogen, cosmic ray exposure history and mineralogy of Beni M’hira (L6) chondrite. Planet. Space Sci. 152, 136–141 (2018)
Mahajan, R.R., Ehgamberdiev, S.A., Naik, S.: Noble gases and nitrogen in CV3 chondrite Bukhara. Planet. Space Sci. 207, 105334 (2021)
Marty, B., Chaussidon, M., Weins, R.C., Jurewicz, A.J.G., Burnett, D.S.: A 15N-poor isotopic composition for the solar system as shown by genesis solar wind samples. Science 332, 1533–1536 (2011)
Mathew, K.J., Marti, K.: Lunar nitrogen: indigenous signature and cosmic-ray production rate. Earth Planet. Sci. Lett. 184, 659–689 (2001)
Mathew, K.J., Murty, S.V.S.: Cosmic ray produced nitrogen in extraterrestrial matter. Proc. Indian Acad. Sci., Earth Planet. Sci. 102, 415–437 (1993)
Meibom, A., Krot, A.N., Robert, F., Mostefaoui, S., Russell, S.S., Petaev, M.I., Gounelle, M.: Nitrogen and carbon isotopic composition of the Sun inferred from a high-temperature solar nebular condensate. Astrophys. J. 656, L33–L36 (2007)
Meteoritical Bulletin Database: (2021). http://www.lpi.usra.edu/meteor/metbull.php
Miller, K.E., Glein, C.R., Waite, J.H. Jr.: Contribution from accreted organics to Titan’s atmosphere: new insights from cometary and chondritic data. Astrophys. J. 871, 59 (2019)
Mumma, M.J., Charnley, S.B.: The chemical composition of comets – emerging taxonomies and natal heritage. Annu. Rev. Astron. Astrophys. 49, 471–524 (2011)
Murty, S.V.S.: Nitrogen components in the Dhajala Meteorite. Meteoritics 31, A94 (1996)
Murty, S.V.S., Mahajan, R.R.: Heavy nitrogen and nucleogenic Kr and Xe in Itawa Bhopji chondrite. 64th Annual Meteoritical Society Meeting 5038.pdf (2001)
Murty, S.V.S., Mahajan, R.R.: Nitrogen in individual chondrules of Dhajala. 66th Annual Meteoritical Society Meeting #5025.pdf (2003)
Murty, S.V.S., Mahajan, R.R.: Nitrogen and noble gases in Zag (H3-6) regolith breccias. Lunar and Planetary Science XXXIII #1023.pdf (2002)
Murty, S.V.S., Bhandari, N., Suthar, K.M., Clement, C.J., Bonino, G., Cini Castagnoli, G.: Cosmogenic effects in Mbale, L5/6 chondrite. Meteorit. Planet. Sci. 33, 1311–1316 (1998)
Murty, S.V.S., Mahajan, R.R., Bartoschewitz, R.: Nitrogen in Sayh Al Uhaymir 290. 70th Annual Meteoritical Society Meeting #5012.pdf (2007)
Murty, S.V.S., Mahajan, R.R., Shukla, A.D., Mazumdar, A.C., Shukla, P.N., Durga Prasad, K., Rai, V.K., Panda, D., Ghevaria, Z.G., Goswami, J.N.: Jodiya (L5) and Mahadevpur (H4/5): two recent ordinary chondrite falls in India. Meteorit. Planet. Sci. 44, A150 (2009)
Murty, S.V.S., Mahajan, R.R., Chattopadhyay, B., Shukla, A.D.: Cosmic ray effects in Devri-Khera (L6) and Lohawat (HOW): two meteorites that fell in close proximity, in space and time. Meteorit. Planet. Sci. 45, A144 (2010a)
Murty, S.V.S., Mahajan, R.R., Jenniskens, P., Shaddad, M.H., Eldien, B.: Noble gases and nitrogen in the Almahata Sitta ureilites. Meteorit. Planet. Sci. 45, 1751–1764 (2010b)
Murty, S.V.S., Mahajan, R.R., Shukla, A.D., Ranjith Kumar, P.M.: Cosmogenic nuclides in Katol (L6-7) ordinary chondrite. 77th Annual Meteoritical Society Meeting 5133.pdf (2014)
Nier, A.O.: A redetermination of the relative abundances of the isotopes of carbon, nitrogen oxygen, argon, and potassium. Phys. Rev. 77, 789–793 (1950)
Owen, T., Mahaffy, P.R., Niemann, H.B., Atreya, S., Wong, M.: Protosolar nitrogen. Astrophys. J. 553, L77–L79 (2001)
Paliwal, B.S., Mahajan, R.R., Murty, S.V.S., Shukla, A.D., Shukla, P.N., Bhandari, N., Natarajan, R., Hutchison, R., Russell, S., Franchi, I.A.: Chemical and isotopic characteristics of the Didwana-Rajod (H5) chondrite. Meteorit. Planet. Sci. 36, 1249–1256 (2001)
Ray, D., Mahajan, R.R., Shukla, A.D., Goswami, T.K., Chakraborty, S.: Petrology, classification, oxygen isotopes, noble gases, and cosmogenic records of Kamargaon (L6) meteorite: the latest fall in India. Meteorit. Planet. Sci. 52, 1744–1753 (2017)
Riebe, M.E.I., Huber, L., Metzler, K., Busemann, H., Luginbuehl, S.M., Meier, M.M.M., Maden, C., Wieler, R.: Cosmogenic He and Ne in chondrules from clastic matrix and a lithic clasts of Murchison: no pre-irradiation by the early sun. Geochim. Cosmochim. Acta 213, 618–634 (2017)
Roth, A.S.G., Leya, I.: No cosmic-ray precompaction exposure of chondrules in CR2.7 MIL 090657. Meteorit. Planet. Sci. 53, 2644–2651 (2018)
Rubin, A.E., Ulff-Moller, F., Wasson, J.T., Carlson, W.D.: The portales valley meteorite breccia: evidence for impact-induced melting and metamorphism of an ordinary chondrite. Geochim. Cosmochim. Acta 65, 323–342 (2001)
Russell, S.S., Arden, J.W., Pillinger, C.T.: A carbon and nitrogen study of diamond from primitive chondrites. Meteorit. Planet. Sci. 31, 343–355 (1996)
Sahijpal, S., Gupta, G.: Did the carbonaceous chondrites evolve in the crustal regions of partially differentiated asteroids? J. Geophys. Res. 116, E06004 (2011)
Sahijpal, S., Ivanova, M.A., Kashkarov, L.L., Korotkova, N.N., Migdisova, L.F., Nazarov, M.A., Goswami, J.N.: 26Al as a heat source for early melting of planetesimals: results from isotopic studies of meteorites. Proc. Indian Acad. Sci., Earth Planet. Sci. 104, 555–567 (1995)
Scherf, M., Lammer, H., Erkaev, N.V., Mandt, K.E., Thaller, S.E., Marty, B.: Nitrogen atmosphere of the ice bodies on the solar system. Space Sci. Rev. 216, 123 (2020)
Shuai, K., Hui, H., Zhou, L., Li, W.: Accretion regions of meteorite parent bodies inferred from a two-endmember isotopic mixing model. Mon. Not. R. Astron. Soc. 513, 363–373 (2022)
Sugiura, N., Hashizume, K.: A preliminary report on nitrogen abundances and isotopes in LL chondrites. Meteoritics 24, 329 (1989)
Sugiura, N., Hashizume, K.: Nitrogen isotope anomalies in primitive ordinary chondrites. Earth Planet. Sci. Lett. 111, 441–454 (1992)
Sugiura, N., Kiyota, K., Zashu, S.: Nitrogen isotopic compositions of some solar-gas-rich chondrites. Proc. NIPR Symp. Antarct. Meteor. 9, 189–207 (1996)
Sugiura, N., Kiyota, K., Hashizume, K.: Nitrogen components in primitive ordinary chondrites. Meteorit. Planet. Sci. 33, 463–482 (1998)
Takaoka, N.: Noble gases in Ten, small Yamato chondrites. Mem. Natl. Inst. Polar Res., Spec. Issue 25, 153–161 (1982)
Van Schmus, W.R., Wood, J.A.: A chemical-petrologic classification for the chondritic meteorites. Geochim. Cosmochim. Acta 31, 747–765 (1967)
Verchovsky, A.B.: Origin of isotopically light nitrogen in meteorites. Geochem. Int. 55, 957–970 (2017)
Wulf, A.V., Palme, H., Jochum, K.P.: Fractionation of volatile elements in the early solar system: evidence from heating experiments on primitive meteorites. Planet. Space Sci. 43, 451–468 (1995)
Zanda, B.: Chondrules. Earth Planet. Sci. Lett. 224, 1–17 (2004)
Zolensky, M., Bland, P., Brown, P., Halliday, I.: Flux of extraterrestrial materials. In: Lauretta, D.S., McSween, H.Y. Jr. (eds.) Meteorites and the Early Solar System II, pp. 869–888. The University of Arizona Press, Tucson (2006)
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Mahajan, R.R. Nitrogen isotopic ratio and abundance in selected ordinary chondrites: clues for their formation in proto-planetary disk. Astrophys Space Sci 368, 101 (2023). https://doi.org/10.1007/s10509-023-04260-9
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DOI: https://doi.org/10.1007/s10509-023-04260-9