Abstract
Piezoelectric semiconductors (PSCs) find extensive applications in modern smart electronic devices because of their dual properties of being piezoelectric and semiconductive. With the increasing demand for miniaturization of these devices, the performance of their components needs to be carefully designed and optimized, especially when reduced to nanosize. It has been shown that surface elastic properties play a substantial role in the mechanical performance of nanoscale materials and structures. Building on this understanding, the surface elastic effects, encompassing surface residual stress, surface membrane stiffness, and surface bending stiffness, are comprehensively taken into account to explore the electromechanical responses of a PSC nanobeam. Additionally, the flexoelectric effect on their responses is also systematically studied. The results of this work reveal that surface elastic properties predominantly influence mechanical performance, while the flexoelectric effect plays a more dominant role in electric-related quantities at the nanoscale. Notably, the significance of surface bending rigidity, which was often underestimated in the earlier literature, is demonstrated. Furthermore, owing to the flexoelectric effect, the linear distribution of electric potential and charge carriers along the length transforms into a nonlinear pattern. The distributions of electric potential and charge carriers across the cross section are also evidently impacted. Moreover, the size-dependent responses are evaluated. Our findings may provide valuable insights for optimizing electronic devices based on nanoscale PSCs.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10338-023-00459-z/MediaObjects/10338_2023_459_Fig1_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10338-023-00459-z/MediaObjects/10338_2023_459_Fig2_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10338-023-00459-z/MediaObjects/10338_2023_459_Fig3_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10338-023-00459-z/MediaObjects/10338_2023_459_Fig4_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10338-023-00459-z/MediaObjects/10338_2023_459_Fig5_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10338-023-00459-z/MediaObjects/10338_2023_459_Fig6_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10338-023-00459-z/MediaObjects/10338_2023_459_Fig7_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10338-023-00459-z/MediaObjects/10338_2023_459_Fig8_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10338-023-00459-z/MediaObjects/10338_2023_459_Fig9_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10338-023-00459-z/MediaObjects/10338_2023_459_Fig10_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10338-023-00459-z/MediaObjects/10338_2023_459_Fig11_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10338-023-00459-z/MediaObjects/10338_2023_459_Fig12_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10338-023-00459-z/MediaObjects/10338_2023_459_Fig13_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10338-023-00459-z/MediaObjects/10338_2023_459_Fig14_HTML.png)
Similar content being viewed by others
References
Wang ZL. Progress in piezotronics and piezo-photonics. Adv Mater. 2012;24:4632–46.
Yang JS. Analysis of piezotronics semiconductor structures. Berlin: Springer Nature Switzerland AG; 2020.
Song JH, Zhou J, Wang ZL. Piezoelectric and semiconducting coupled power generating process of a single ZnO belt/wire: a technology for harvesting electricity from the environment. Nano Lett. 2006;6(8):1656–62.
Kumar B, Kim SW. Energy harvesting based on semiconducting piezoelectric ZnO nanostructures. Nano Energy. 2012;1:342–55.
Auld BA. Acoustic fields and waves in solids, vol. 1. New York: Wiley; 1973.
Yang WL, Hu YT, Yang JS. Transient extensional vibration in a ZnO piezoelectric semiconductor nanofiber under a suddenly applied end force. Mater Res Express. 2019;6:025902.
Yang JS, Zhou HG. Amplification of acoustic waves in piezoelectric semiconductor plates. Int J Solids Struct. 2005;42:3171–83.
Wang ZL. Piezotronics and piezo-phototronics. Berlin: Springer; 2012.
Zhou XF, Shen B, Lyubartsev A, Zhai JW, Hedin N. Semiconducting piezoelectric heterostructures for piezo- and piezophotocatalysis. Nano Energy. 2022;96:107141.
Guo YF, Wang ZL. Equilibrium potential of free charge carriers in a bent piezoelectric semiconductive nanowire. Nano Lett. 2009;9:1103–10.
Zhang CL, Wang XY, Chen WQ, Yang JS. An analysis of the extension of a ZnO piezoelectric semiconductor nanofiber under an anial force. Smart Mater Struct. 2017;26:025030.
Fan SQ, Liang YX, **e JM, Hu YT. Exact solutions to the electromechanical quantities inside a statically-bent circular zno nanowire by taking into account both the piezoelectric property and the semiconducting performance: part I– linearized analysis. Nano Energy. 2017;40:82–7.
Cheng RR, Zhang CL, Chen WQ, Yang JS. Piezotronic effects in the extension of a composite fiber of piezoelectric dielectrics and nonpiezoelectric semiconductors. J Appl Phys. 2018;124:064506.
Ma LL, Chen WJ, Zheng Y. Flexoelectric effect at the nanoscale. In: Schmauder S, Chen CS, Chawla K, Chawla N, Chen W, Kagawa Y, editors. Handbook of mechanics of materials. Singapore: Springer; 2018. p. 1–42.
Liu C, Wu HP, Wang J. Giant piezoelectric response in piezoelectric/dielectric superlattices due to flexoelectric effect. Appl Phys Lett. 2016;109:192901.
Majdoub MS, Sharma P, Cagin T. Enhanced size-dependent piezoelectricity and elasticity in nanostructures due to the flexoelectric effect. Phys Rev B. 2008;77:125424.
Zhou ZD, Yang CP, Su YX, Huang R, Lin XL. Electromechanical coupling in piezoelectric nanobeams due to the flexoelectric effect. Smart Mater Struct. 2017;26:095025.
Qu YL, ** F, Yang JS. Effects of mechanical fields on mobile charges in a composite beam of flexoelectric dielectrics and semiconductors. J Appl Phys. 2020;127:194502.
Wang KF, Wang BL. Electrostatic potential in a bent piezoelectric nanowire with consideration of size-dependent piezoelectricity and semiconducting characterization. Nanotechnology. 2018;29: 255405.
Zhao MH, Liu X, Fan CY, Lu CS, Wang BB. Theoretical analysis on the extension of a piezoelectric semi-conductor nanowire: effects of flexoelectricity and strain gradient. J Appl Phys. 2020;127: 085707.
Zhao MH, Niu JN, Lu CS, Wang BB, Fan CY. Effects of flexoelectricity and strain gradient on bending vibration characteristics of piezoelectric semiconductor nanowires. J Appl Phys. 2021;129: 164301.
Sun L, Zhang ZC, Gao CF, Zhang CL. Effect of flexoelectricity on piezotronic responses of a piezoelectric semiconductor bilayer. J Appl Phys. 2021;129:244102.
Qu YL, ** F, Yang JS. Bending of a flexoelectric semiconductor plate. Acta Mech Solida Sin. 2022;35(3):434–45.
Guo JY, Nie GQ, Liu JX, Zhang LL. Free vibration of a piezoelectric semiconductor plate. Eur J Mech/A Solids.2022;95:104647.
Gurtin ME, Murdoch AI. A continuum theory of elastic material surfaces. Arch Ration Mech Anal. 1975;57:291–323.
Gurtin ME, Murdoch AI. Surface stress in solids. Int J Solids Struct. 1978;14:431–40.
Duan HL, Wang J, Karihaloo BL, Huang ZP. Nanoporous materials can be made stiffer than non-porous counterparts by surface modification. Acta Mater. 2006;54(11):2983–90.
Ansari R, Sahmani S. Surface stress effects on the free vibration behavior of nanoplates. Int J Eng Sci. 2011;49(11):1204–15.
Yan Z, Jiang LY. Vibration and buckling analysis of a piezoelectric nanoplate considering surface effects and in-planie constraint. Proc Royal Soc A. 2012;468:3458–75.
Huang DW. Size-dependent response of ultra-thin films with surface effects. Int J Solids Struct. 2008;45:568–79.
Steigmann DJ, Ogden RW. Plane deformations of elastic solids with intrinsic boundary elasticity. Proc Royal Soc London A Math Phys Eng Sci. 1959;453:853–77.
Chhapadia P, Mohammadi P, Sharma P. Curvature-dependent surface energy and implications for nanostructures. J Mech Phys Solids. 2011;59:2103–15.
Mohammadi P, Sharma P. Atomistic elucidation of the effect of surface roughness on curvature-dependent surface energy, surface stress, and elasticity. Appl Phys Lett. 2012;100:133110–4.
Neffati D, Kulkarni Y. Homogenization of surface energy and elasticity for highly rough surfaces. J Appl Mech. 2022;89:041004.
Ban YX, Mi CW. Analytical solutions of a spherical nanoinhomogeneity under far-field unidirectional loading based on Steigmann-Ogden surface model. Math Mech Solids. 2020;25:1904–23.
Li XB, Mi CW. Effects of surface tension and steigmann-ogden surface elasticity on hertzian contact properties. Int J Eng Sci. 2019;145:103165.
Shen SP, Hu SL. A theory of flexoelectricity with surface effect for elastic dielectrics. J Mech Phys Solids. 2010;58:665–77.
Liang X, Hu SL, Shen SP. Effects of surface and flexoelectricity on a piezoelectric nanobeam. Smart Mater Struct. 2014;23:035020.
Xu XJ, Deng ZC, Wang B. Closed solutions for the electromechanical bending and vibration of thick piezoelectric nanobeams with surface effects. J Phys D Appl Phys. 2013;46:405302–11.
Wang KF, Wang BL. Effects of surface and interface energies on the bending behavior of nanoscale multilayered beams. Physica E. 2013;54:197–201.
Zhu CS, Fang XQ, Liu JX, Li HY. Surface energy effect on nonlinear free vibration behavior of orthotropic piezoelectric cylindrical nano-shells. Eur J Mech A/Solids. 2017;66:423–32.
Yan Z, Jiang LY. Size-dependent bending and vibration behavior of piezoelectric nanobeams due to flexoelectricity. J Phys D Appl Phys. 2013;46:355502.
Shingare KB, Kundalwal SI. Flexoelectric and surface effects on the electromechanical behavior of graphene-based nanobeams. Appl Math Model. 2020;81:70–91.
Mizzi CA, Marks LD. The role of surfaces in flexoelectricity. J Appl Phys. 2021;129:224102.
Zhang ZC, Liang C, Wang Y, Xu RQ, Gao CF, Zhang CL. Static bending and vibration analysis of piezoelectric semiconductor beams considering surface effects. J Vibr Eng Technol. 2021;9:1789–800.
Acknowledgements
We wish to acknowledge the support of the National Natural Science Foundation of China [Grant number: 11702076], and the Natural Science Foundation of Anhui Province [Grant numbers: 2208085MA17 and 2208085ME129].
Author information
Authors and Affiliations
Corresponding authors
Ethics declarations
Conflict of interest
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Bao, A., Li, X., Pu, Y. et al. Surface Elastic Effects on Electromechanical Responses of a Piezoelectric Semiconducting Nanobeam. Acta Mech. Solida Sin. (2024). https://doi.org/10.1007/s10338-023-00459-z
Received:
Revised:
Accepted:
Published:
DOI: https://doi.org/10.1007/s10338-023-00459-z