Abstract
Green hydrogen is a buzzword in today's renewable energy applications research domain. This paper analyzes the performance of the photovoltaic (PV) and thermoelectric generator (TEG) systems for the same reason. The prototype system includes PV, TEG, a heat sink, and a Hofmann Voltameter. The output of the PV–TEG is initially connected to a Hofmann Voltmeter to conduct electrolysis of groundwater and seawater. Further, a heat sink is pasted on each TEG using a thermally conductive adhesive. Then again, PV–TEG/heat sink output is connected to the Voltameter for electrolysis on the same water source samples. Finally, the comparative exploration is done to give insights into PV–TEG applications for hydrogen production. The explorative study shows a DC voltage gain of up to 1.77 times concerning TEG alone. Further, at 849 W/m2 of solar irradiance, it is observed that hydrogen production varies from 0.1552 to 0.1639 bar/sec in the case of groundwater and that of seawater goes from 0.1362 to 0.1413 bar/sec when PV–TEG with a heat sink is connected to Voltameter.
Graphic abstract
![](http://media.springernature.com/lw685/springer-static/image/art%3A10.1007%2Fs10098-023-02569-1/MediaObjects/10098_2023_2569_Figa_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10098-023-02569-1/MediaObjects/10098_2023_2569_Fig1_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10098-023-02569-1/MediaObjects/10098_2023_2569_Fig2_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10098-023-02569-1/MediaObjects/10098_2023_2569_Fig3_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10098-023-02569-1/MediaObjects/10098_2023_2569_Fig4_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10098-023-02569-1/MediaObjects/10098_2023_2569_Fig5_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10098-023-02569-1/MediaObjects/10098_2023_2569_Fig6_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10098-023-02569-1/MediaObjects/10098_2023_2569_Fig7_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10098-023-02569-1/MediaObjects/10098_2023_2569_Fig8_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10098-023-02569-1/MediaObjects/10098_2023_2569_Fig9_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10098-023-02569-1/MediaObjects/10098_2023_2569_Fig10_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10098-023-02569-1/MediaObjects/10098_2023_2569_Fig11_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10098-023-02569-1/MediaObjects/10098_2023_2569_Fig12_HTML.png)
Similar content being viewed by others
Data availability
Enquiries about data availability should be directed to the authors.
Abbreviations
- PV:
-
Photovoltaic
- PVT:
-
Photovoltaic thermal
- TEG:
-
Thermoelectric generator
- DC:
-
Direct current
- α :
-
See back coefficient
- T :
-
Operating temperature
- P :
-
Electrical resistivity
- K :
-
Thermal conductivity
- A :
-
Area of TEG
- P eo :
-
Electrical output
- \(\Delta T\) :
-
Temperature variation between the hot side and cold side of TEG
- d :
-
Thickness of TEG
- P o :
-
The extracted electric output power
- Q i :
-
Net heat flowing into TEG
- P si :
-
Solar input
References
Abdo A, Ookawara S, Ahmed M (2019) Performance evaluation of a new design of concentrator photovoltaic and solar thermoelectric generator hybrid system. Energy Convers Manage 195:1382–1401. https://doi.org/10.1016/j.enconman.2019.04.093
Al Kumait AAR, Ibrahim TK, Abdullah MA (2019) Experimental and numerical study of forced convection heat transfer in different internally ribbed tubes configuration using TiO2 nanofluid. Heat Transf-Asian Res 48:1778–1804. https://doi.org/10.1002/htj.21457
Alluri PL, Alli DR (2022) Modelling thermoelectric generators to harvest the low-temperature changes in electronic devices. Int J Eng Trends Technol 70:105–110. https://doi.org/10.14445/22315381/ijett-v70i9p210
Al-Waeli AHA, Sopian K, Kazem HA, Chaichan MT (2017) Photovoltaic/thermal (PV/T) systems: status and future prospects. Renew Sustain Energy Rev 77:109–130. https://doi.org/10.1016/j.rser.2017.03.126
Amatya R, Ram RJ (2010) Solar thermoelectric generator for micropower applications. J Electron Mater 39:1735–1740. https://doi.org/10.1007/s11664-010-1190-8
Ameen ASH, Sinjari AM (2022) Design and implementation of evaporative cooler automation system at Erbil/Perdawd power plant. Tikrit J Eng Sci. https://doi.org/10.25130/tjes.29.3.1
Badea GE, Hora C, Maior I et al (2022) Sustainable hydrogen production from seawater electrolysis: through fundamental electrochemical principles to the most recent development. Energies 15:8560. https://doi.org/10.3390/en15228560
Burnete NV, Mariasiu F, Moldovanu D, Depcik C (2021) Simulink Model of a Thermoelectric Generator for Vehicle Waste Heat Recovery. Appl Sci 11:1340. https://doi.org/10.3390/app11031340
Burton NA, Padilla RV, Rose A, Habibullah H (2021) Increasing the efficiency of hydrogen production from solar powered water electrolysis. Renew Sustain Energy Rev 135:110255. https://doi.org/10.1016/j.rser.2020.110255
Chandrasekar M, Gopal P, Ramesh Kumar C, Edwin Geo V (2022) Effect of solar photovoltaic and various photovoltaic air thermal systems on hydrogen generation by water electrolysis. Int J Hydrogen Energy 47:3211–3223. https://doi.org/10.1016/j.ijhydene.2021.04.205
Clarke RE, Giddey S, Ciacchi FT et al (2009) Direct coupling of an electrolyzer to a solar PV system for generating hydrogen. Int J Hydrogen Energy 34:2531–2542. https://doi.org/10.1016/j.ijhydene.2009.01.053
Cui T, Xuan Y, Li Q (2016) Design of a novel concentrating photovoltaic–thermoelectric system incorporated with phase change materials. Energy Convers Manage 112:49–60. https://doi.org/10.1016/j.enconman.2016.01.008
Du D, Darkwa J, Kokogiannakis G (2013) Thermal management systems for Photovoltaics (PV) installations: A critical review. Sol Energy 97:238–254. https://doi.org/10.1016/j.solener.2013.08.018
Đukić A, Firak M (2011) Hydrogen production using alkaline electrolyzer and photovoltaic (PV) module. Int J Hydrogen Energy 36:7799–7806. https://doi.org/10.1016/j.ijhydene.2011.01.180
El-Emam RS, Özcan H (2019) Comprehensive review on the techno-economics of sustainable large-scale clean hydrogen production. J Clean Prod 220:593–609. https://doi.org/10.1016/j.jclepro.2019.01.309
Elghool A, Basrawi F, Ibrahim TK et al (2020) Multi-objective optimization to enhance the performance of thermo-electric generator combined with heat pipe-heat sink under forced convection. Energy 208:118270. https://doi.org/10.1016/j.energy.2020.118270
Galeev AG (2017) Review of engineering solutions applicable in tests of liquid rocket engines and propulsion systems employing hydrogen as a fuel and relevant safety assurance aspects. Int J Hydrogen Energy 42:25037–25047. https://doi.org/10.1016/j.ijhydene.2017.06.242
Gibson TL, Kelly NA (2010) Predicting efficiency of solar powered hydrogen generation using photovoltaic-electrolysis devices. Int J Hydrogen Energy 35:900–911. https://doi.org/10.1016/j.ijhydene.2009.11.074
Goldsmid H (2014) Bismuth Telluride and Its Alloys as Materials for Thermoelectric Generation. Materials 7:2577–2592. https://doi.org/10.3390/ma7042577
Gopinath M, Marimuthu R (2022) A review on solar energy-based indirect water-splitting methods for hydrogen generation. Int J Hydrogen Energy. https://doi.org/10.1016/j.ijhydene.2022.08.297
Gopinath M, Marimuthu R (2023) PV–TEG output: comparison with heat sink and graphite sheet as heat dissipators. Case Stud Thermal Eng 55:102935. https://doi.org/10.1016/j.csite.2023.102935
Haider SA, Sajid M, Iqbal S (2020) Forecasting hydrogen production potential in Islamabad from solar energy using water electrolysis. Int J Hydrogen Energy. https://doi.org/10.1016/j.ijhydene.2020.10.059
Hai** C, Jiguang H, Heng Z et al (2019) Experimental investigation of a novel low concentrating photovoltaic/thermal–thermoelectric generator hybrid system. Energy 166:83–95. https://doi.org/10.1016/j.energy.2018.10.046
He R, Schierning G, Nielsch K (2017) Thermoelectric devices: a review of devices, architectures, and contact optimization. Adv Mater Technol 3:1700256. https://doi.org/10.1002/admt.201700256
Huang MJ, Eames PC, Norton B (2006) Phase change materials for limiting temperature rise in building integrated photovoltaics. Sol Energy 80:1121–1130. https://doi.org/10.1016/j.solener.2005.10.006
Ibrahim TK, Al-Sammarraie AT, Al-Taha WH et al (2019) Experimental and numerical investigation of heat transfer augmentation in heat sinks using perforation technique. Appl Therm Eng 160:113974. https://doi.org/10.1016/j.applthermaleng.2019.113974
Jamesh M-I, Harb M (2020) Recent advances on hydrogen production through seawater electrolysis. Mater Sci Energy Technol. https://doi.org/10.1016/j.mset.2020.09.005
Khalaf SM, Mohammed AA, Mohammed QJ (2022) An Experimental Investigation on Heat Transfer Enhancement in An Annulus with Rotating Outer Cylinder Using Nano Fluids. Tikrit J Eng Sci 29:51–60. https://doi.org/10.25130/tjes.29.2.7
Mahmoudinezhad S, Qing S, Rezaniakolaei A, Aistrup Rosendahl L (2017) Transient model of hybrid concentrated photovoltaic with thermoelectric generator. Energy Procedia 142:564–569. https://doi.org/10.1016/j.egypro.2017.12.088
Makki A, Omer S, Sabir H (2015) Advancements in hybrid photovoltaic systems for enhanced solar cells performance. Renew Sustain Energy Rev 41:658–684. https://doi.org/10.1016/j.rser.2014.08.069
Mraoui A, Benyoucef B, Hassaine L (2018) Experiment and simulation of electrolytic hydrogen production: Case study of photovoltaic-electrolyzer direct connection. Int J Hydrogen Energy 43:3441–3450. https://doi.org/10.1016/j.ijhydene.2017.11.035
Prajwal KT, Bhat P (2021) Thermal analysis of a Thermoelectric Generator (TEG) using FEM technique. IOP Conference Series: Materials Science and Engineering 1045:012018. https://doi.org/10.1088/1757-899x/1045/1/012018
Ramkumar A, Ramakrishnan M (2022) A comprehensive review on small-scale thermal energy harvesters: Advancements and applications. Materials Today: Proceedings 66:1552–1562. https://doi.org/10.1016/j.matpr.2022.07.309
Senthilraja S, Gangadevi R, Köten H, Marimuthu R (2020a) Performance assessment of a solar powered hydrogen production system and its ANFIS model. Heliyon 6:e05271. https://doi.org/10.1016/j.heliyon.2020.e05271
Senthilraja S, Gangadevi R, Marimuthu R, Baskaran M (2020b) Performance evaluation of water and air based PVT solar collector for hydrogen production application. Int J Hydrogen Energy 45:7498–7507. https://doi.org/10.1016/j.ijhydene.2019.02.223
Senthilraja S, Gangadevi R, Köten H et al (2021) Performance analysis of a novel hydrogen production system incorporated with hybrid solar collector and phase change material. Int J Hydrogen Energy. https://doi.org/10.1016/j.ijhydene.2021.12.046
Sharma NK, Gaur MK, Malvi CS (2021) Application of phase change materials for cooling of solar photovoltaic panels: a review. Mater Today Proceed. https://doi.org/10.1016/j.matpr.2021.05.127
Shen H, Lee H, Han S (2020) Optimization and fabrication of a planar thermoelectric generator for a high-performance solar thermoelectric generator. Curr Appl Phys. https://doi.org/10.1016/j.cap.2020.11.005
Sripadmanabhan Indira S, Vaithilingam CA, Chong K-K et al (2020) A review on various configurations of hybrid concentrator photovoltaic and thermoelectric generator system. Sol Energy 201:122–148. https://doi.org/10.1016/j.solener.2020.02.090
Tabanjat A, Becherif M, Emziane M et al (2015) Fuzzy logic-based water heating control methodology for the efficiency enhancement of hybrid PV–PEM electrolyzer systems. Int J Hydrogen Energy 40:2149–2161. https://doi.org/10.1016/j.ijhydene.2014.11.135
Tebibel H (2017) Off-grid PV system for hydrogen production using PEM methanol electrolysis and an optimal management strategy. Int J Hydrogen Energy 42:19432–19445. https://doi.org/10.1016/j.ijhydene.2017.05.205
Teffah K, Zhang Y (2017) Modeling and experimental research of hybrid PV-thermoelectric system for high concentrated solar energy conversion. Sol Energy 157:10–19. https://doi.org/10.1016/j.solener.2017.08.017
Widera B (2020) Renewable hydrogen implementations for combined energy storage, transportation and stationary applications. Thermal Sci Eng Prog 16:100460. https://doi.org/10.1016/j.tsep.2019.100460
Willars-Rodríguez FJ, Chávez-Urbiola EA, Vorobiev P, Vorobiev YuV (2016) Investigation of solar hybrid system with concentrating Fresnel lens, photovoltaic and thermoelectric generators. Int J Energy Res 41:377–388. https://doi.org/10.1002/er.3614
Yazdanifard F, Ameri M (2018) Exergetic advancement of photovoltaic/thermal systems (PV/T): a review. Renew Sustain Energy Rev 97:529–553. https://doi.org/10.1016/j.rser.2018.08.053
Yemata TA, Ye Q, Zhou H et al (2017) Conducting polymer-based thermoelectric composites. Hybrid Polymer Composite Materials 85:169–195. https://doi.org/10.1016/b978-0-08-100785-3.00006-1
Zaidan MH, Ibrahim TK, Alkumait AAR (2019) Performance enhancement by using wet pad in vapor compression cooling system. J Eng Technol Sci 51:48–63. https://doi.org/10.5614/j.eng.technol.sci.2019.51.1.4
Zhao Y, Li W, Diao H et al (2022) Experimental research of solar thermoelectric generator based on flat heat pipe. Energy Rep 8:245–250. https://doi.org/10.1016/j.egyr.2022.05.193
Acknowledgements
The authors thank VIT for providing 'VIT SEED GRANT (SG20210085)' for carrying out this research work. Furthermore, the authors keenly acknowledge the contribution of Dr Natarajan. M while develo** the experimental setup and Renewable Energy System (RES) laboratory personnel for providing necessary resources.
Funding
The authors have not disclosed any funding.
Author information
Authors and Affiliations
Contributions
We declare that this manuscript is original, has not been published before and is not currently being considered for publication elsewhere. We confirm that the manuscript has been read and approved by all named authors and that there are no other persons who satisfied the criteria for authorship but are not listed. Both authors equally contributed to this work. We further confirm that all have approved the order of authors listed in the manuscript of us. We understand that the Corresponding Author is the sole contact for the Editorial process. He is responsible for communicating with the other authors about progress, submissions of revisions and final approval of proofs.
Corresponding author
Ethics declarations
Competing interests
The authors declare no competing interests.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Gopinath, M., Marimuthu, R. Comparative study of hydrogen production from seawater and groundwater using PV–TEG. Clean Techn Environ Policy 25, 2451–2466 (2023). https://doi.org/10.1007/s10098-023-02569-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10098-023-02569-1