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A zirconia-polyester glycol coating on differently pretreated AISI 316L stainless steel: corrosion behavior in chloride solution

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Abstract

The effect of zirconia and zirconia-polyester glycol hybrid coatings on the corrosion resistance of mechanically polished or anodized AISI 316 stainless steel (316L), was studied by potentiodynamic polarization and electrochemical impedance spectroscopy in 0.1 M NaCl and scanning electron microscope and atomic force microscopy examinations. The deposition of zirconia coatings was achieved by the sol–gel technique by immersing the samples in either the inorganic polymer or the organic–inorganic polymer mixture. From potentiodynamic and impedance measurements, the grade of protection is reduced with the exposure time to the electrolyte, which is mainly associated with lost of film adhesion and, consequently, detachment from the metal substrate. However, the uncoated anodized sample revealed an unexpected corrosion behavior; the anodic film formed during anodizing readily increased the corrosion resistance of the 316L stainless steel in 0.1 M NaCl, revealing a considerable reduction in the corrosion current density and an increase in the pitting potential.

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Acknowledgements

The authors are grateful to Fondecyt (Grant: 1060050), CONICYT-Programa Bicentenario in Science and Technology and to DICYT (USACH) for financial support. H. Torres is grateful to the Alpha program, scholarship (RICICOP-II).

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Authors and Affiliations

  1. Departamento de Química de los Materiales, Facultad de Química y Biología, Universidad de Santiago de Chile, Casilla 40, Correo 33, Santiago, Chile

    C. Martinez, M. Sancy, J. H. Zagal, J. Pavez & M. A. Paez

  2. Departamento de Ciencias del Ambiente, Facultad de Química y Biología, Universidad de Santiago de Chile, Casilla 40, Correo 33, Santiago, Chile

    F. M. Rabagliati

  3. Laboratoire Interfaces et systèmes Electrochimiques, CNRS, Université Pierre et Marie Curie-Paris6, UPR15-LISE.4 place Jussieu, Paris, 75005, France

    B. Tribollet

  4. Facultad de Ingeniería, Departamento de Ingeniería Química, Grupo de Corrosión Y Protección, Sede de Investigaciones Universitarias, Universidad de Antioquia, Calle 62 # 52–59, Torre 2, Medellín, Colombia

    H. Torres

  5. Departamento de Metalurgia, Facultad de Ingeniería, Universidad de Santiago de Chile, Santiago, Chile

    A. Monsalve

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  1. C. Martinez
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  2. M. Sancy
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  9. M. A. Paez
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Correspondence to M. A. Paez.

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Martinez, C., Sancy, M., Zagal, J.H. et al. A zirconia-polyester glycol coating on differently pretreated AISI 316L stainless steel: corrosion behavior in chloride solution. J Solid State Electrochem 13, 1327–1337 (2009). https://doi.org/10.1007/s10008-008-0674-4

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  • DOI: https://doi.org/10.1007/s10008-008-0674-4

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