Abstract
Objective
The aim of this in vitro study was to evaluate the effect of an oxide nanocoating to prevent colour degradation of maxillofacial silicone elastomers following accelerated ageing.
Material and methods
Specimens (N = 40) of specified dimensions were fabricated in Factor II room temperature vulcanizing (RTV) silicone and processed according to the manufacturer’s instructions. Two groups were classified with 20 specimens each. Specimens in the first group were coated with titanium dioxide (TiO2) by atomic layer deposition technology. The colour stability test was conducted with a UV–VIS spectrometer (Schimadzu) for both titanium dioxide nanocoated and uncoated specimen groups after subjecting them to accelerated ageing. It was analysed using the CIE L*a*b method.
Results
The average colour change was highest for uncoated specimens (2.868), and the average colour change for titanium dioxide-coated specimens was significantly low (1.774). The average colour change of uncoated specimens (2.868) was close to the acceptable threshold value (3), and that of coated specimens (1.774) was far below the acceptable threshold (3).
Conclusions
The colour change that occurred in titanium dioxide nanocoated specimens following accelerated ageing was significantly lower than that in the uncoated group, showing that the TiO2 nanocoating was effective in reducing the colour degradation of silicone elastomers.
Clinical relevance
Maxillofacial prostheses fabricated from silicone elastomers go through undesirable colour degradation over time. The development of a scientific technique that retards the colour deterioration of silicone prostheses would be of great clinical significance.
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References
Chen S, Yang J, Jia YG, Lu B, Ren L (2018) A study of 3D-printable reinforced composite resin: PMMA modified with silver nanoparticles loaded cellulose nanocrystal. Materials 11(12):2444
Hanson MD, Shipman B, Blomfield JV, Janus CE (1983) Commercial cosmetics and their role in the colouring of facial prostheses. J Prosthet Dent 50:818–820
Lontz JF (1990) State-of-the-art materials used for maxillofacial prosthetic reconstruction. Dent Clin North Am 34:307–325
Lai JH, Wang LL, Ko CC, DeLong RL, Hodges JS (2002) New organosilicon maxillofacial prosthetic materials. Dent Mater 18:281–286
Haug SP, Andres CJ, Moore BK (1999) Color stability and colorant effect on maxillofacial elastomers. Part III: weathering effect on color. J Prosthet Dent 81(4):431–8
Lemon JC, Chambers MS, Jacobsen ML, Powers JM (1995) Colour stability of facial prostheses. J Prosthet Dent 74:613–618
Bishal AK, Wee AG, Barão VAR, Yuan JCC, Landers R, Sukotjo C et al (2019) Colour stability of maxillofacial prosthetic silicone functionalized with oxide nanocoating. J Prosthet Dent 121:538–543
Mitra A, Choudhary S, Garg H, Jagadeesh HG (2014) Maxillofacial prosthetic materials- an inclination towards silicones. J Clin Diagn Res 8(12):ZE08-13
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Dr. Gopika K. K. formulated the design of the research work and drafting of the manuscript. Dr. Harsha Kumar K. was instrumental in providing guidance to design the concept of the research work and final approval of the version to be published. Dr. R. Ravichandran performed the interpretation of the data. Dr. Prasanth V. helped in the drafting and analysis of the research study. Dr. Kala S. helped in preparing the manuscript. Dr. **esh K. B. did the data acquisition and analysis.
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K. K., G., K., H.K., Ravichandran, R. et al. Effect of titanium dioxide nanocoating on the colour stability of room temperature vulcanizing maxillofacial silicone—an invitro study. Clin Oral Invest 27, 7799–7807 (2023). https://doi.org/10.1007/s00784-023-05369-5
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DOI: https://doi.org/10.1007/s00784-023-05369-5