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Investigation of the effect of poly (sodium styrene sulfonate) on sodium glycodeoxycholate and sodium tetradecyl sulfate mixed micelle

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Abstract

The interactions of polyelectrolyte poly (sodium styrene sulfonate or NaPSS) and anionic surfactants, sodium glycodeoxycholate (SGDC) and sodium tetradecyl sulfate (STS), as well as their combination (SGDC + STS) at different mole fraction ratios, were investigated using surface tension analysis. In the SGDC + STS binary mixture, when the amount of NaPSS (0.005–0.03%) increased from \({\alpha }_{{\text{SGDC}}}\) 0.0 to 1.0, increasing the critical micellization concentration (cmc) of the mixtures. The minimum cmc values were found from 0.833 to 1.480 mmol L−1 in the presence of 0.03% of NaPSS. Clint, Rubingh, Motomura, and Rodenas approaches were used to evaluate the ideal cmc, activity coefficients (fi), interaction parameter (–β), micellar compositions (x), and ideal micellar composition of (xid) of SGDC + STS mixtures. Synergism has been demonstrated by the experimental values of c0m being lower than the ideal values in water. Moreover, by adding NaPSS from 0.005 to 0.03%, the synergism interaction was eliminated and antagonism behavior was developed. The standard Gibb’s free energy of micellization (\({\Delta G}_{m}^{0})\) and surface excess (Γ) and surface area per absorbed molecules (Amin) was decreased or increased depending on NaPSS amount in the SGDC + STS mixture with varying \({a}_{{\text{SGDC}}}\).

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Acknowledgements

The authors are grateful to the Researchers Supporting Project number (RSP2024R360), King Saud University, Riyadh, Saudi Arabia.

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Authors and Affiliations

  1. Research and Development Cell, Swami Vivekanand Subharti University, Meerut, 250005, Uttar Pradesh, India

    Anirudh Srivastava, Mukul Kumar & Doli Devi

  2. Department of Food Science and Nutrition, College of Food and Agricultural Sciences, King Saud University, 11451, Riyadh, Saudi Arabia

    Javed Masood Khan

  3. **dal Global Business School, **dal Global University, O.P, Sonipat, India, 131001

    Sandeep Kumar Singh

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Anirudh Srivastava: conceptualization, data curation, writing—original draft, review and editing. Mukul Kumar: experimental, data curation, review and editing. Doli Devi: experimental, data curation. Javed Masood Khan: data curation, review and editing. Sandeep Kumar Singh: data curation, review and editing;

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Srivastava, A., Kumar, M., Devi, D. et al. Investigation of the effect of poly (sodium styrene sulfonate) on sodium glycodeoxycholate and sodium tetradecyl sulfate mixed micelle. Colloid Polym Sci (2024). https://doi.org/10.1007/s00396-024-05263-w

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