Abstract
Polyimide (PI) films are wildly used in the field of electrical equipment and electronic devices due to their excellent thermal, electrical, and mechanical properties. The various mechanisms of sample thickness on the electrical breakdown of polyimide have been proposed. The purpose of this study is to apply the state of macromolecular aggregation to analyze the breakdown strength of PI film with different thickness. In this paper, the direct current (dc) electrical breakdown properties of PI films as a function of thickness were investigated employing water absorption, mechanical properties, thermal properties, and thermally stimulated depolarization current (TSDC). These experimental results exhibit a good coincidence with the breakdown measurement. On the condition of the structure of the polymeric molecules to the same case, the congregating state of the polymer might be the fundamental reason causing the dc electrical breakdown field of PI film with different thickness.
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Funding
This work is supported by the State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources (Grant No. LAPS21022) and the fund of **nbang Electronic Co. Ltd (Grant No. 20213702030785).
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Ba, Z., Liu, H., Li, C. et al. Study on direct current electrical breakdown properties of polyimide films with different thickness. Colloid Polym Sci 301, 313–318 (2023). https://doi.org/10.1007/s00396-023-05060-x
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DOI: https://doi.org/10.1007/s00396-023-05060-x