Abstract
We report plasmonic enhanced random lasing from dye-doped polymer with dispersed Au nanoparticles (DP@Au NPs). The Au nanoparticles, fabricated by simple and convenient sputtering and thermal annealing processes, are employed as scatterers in a DCJTB-doped PMMA film. Random-arranged and nearly spherical nano-Au particles are fabricated by optimizing the sputtering time and annealing temperature. Multiple scattering coming from particles plays a fundamental role in random lasing emissions. We demonstrate low-threshold random lasing and also the polarization dependence by observing emission as a function of pump beam power and detection polarization in DP@Au NP system. Our findings provide an effective approach for random lasing and could pave a way for the fabrication of efficient random lasing devices.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs00340-018-7097-4/MediaObjects/340_2018_7097_Fig1_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs00340-018-7097-4/MediaObjects/340_2018_7097_Fig2_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs00340-018-7097-4/MediaObjects/340_2018_7097_Fig3_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs00340-018-7097-4/MediaObjects/340_2018_7097_Fig4_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs00340-018-7097-4/MediaObjects/340_2018_7097_Fig5_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs00340-018-7097-4/MediaObjects/340_2018_7097_Fig6_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs00340-018-7097-4/MediaObjects/340_2018_7097_Fig7_HTML.png)
Similar content being viewed by others
References
N.M. Lawandy, R.M. Balachandran, A.S.L. Gomes, E. Sauvain, Laser action in strongly scattering media. Nature 368(6470), 436 (1994)
B. Redding, M.A. Choma, H. Cao, Speckle-free laser imaging using random laser illumination. Nat. Photon. 6(6), 355–359 (2012)
T. Zhai, X. Zhang, Z. Pang, X. Su, H. Liu, S. Feng, L. Wang, Random laser based on wave guided plasmonic gain channels. Nano Lett. 11, 4295 (2011)
X. Shi, Y. Wang, Z. Wang, S. Wei, Y. Sun, D. Liu, J. Zhou, Y. Zhang, J. Shi, Random lasing with a high quality factor over the whole visible range based on cascade energy transfer. Adv. Opt. Mater. 2, 88–93 (2014)
O. Popov, A. Zilbershtein, D. Davidov, Random lasing from dye-gold nanoparticles in polymer films: enhanced gain at the surface-plasmon-resonance wavelength. Appl. Phys. Lett. 89(19), 191116 (2006)
D. He, W. Bao, L. Long, P. Zhang, M. Jiang, D. Zhang, Random lasing from dye-Ag nanoparticles in polymer films: improved lasing performance by localized surface plasmon resonance. Opt. Laser Technol. 91, 193–196 (2017)
Z. Wang, X. Meng, S.H. Choi, K. Sebastian, L.K. Young, C. Hui, M.S. Vladimir, B. Alexandra, Controlling random lasing with three-dimensional plasmonic nanorod metamaterials. Nano Lett. 16(4), 2471–2477 (2016)
Q. Song, S. **ao, Z. Xu, J. Liu, X. Sun, V. Drachev, V. Shalaev, O. Akkus, Y. Kim, Random lasing in bone tissue. Opt. Lett. 35, 1425–1427 (2010)
B. Redding, M.A. Choma, H. Cao, Spatial coherence of random laser emission. Opt. Lett. 36(17), 3404–3406 (2011)
X. Ma, P. Chen, D. Li, Y. Zhang, D. Yang, Electrically pump ZnO film ultraviolet random lasers on silicon substrate. Appl. Phys. Lett. 91(25), 251109 (2007)
X. Meng, K. Fujita, Y. Zong, S. Murai, K. Tanaka, Random lasers with coherent feedback from highly transparent polymer films embedded with silver nanoparticles. Appl. Phys. Lett. 92(20), 201112 (2008)
J. Ziegler, M. Djiango, C. Vidal, C. Hrelescu, T.A. Klar, Gold nanostars for random lasing enhancement. Opt. Express 23(12), 15152–15159 (2015)
S. Xu, Y. Cao, J. Zhou, X. Wang, X. Wang, W. Xu, Plasmonic enhancement of fluorescence on silver nanoparticle films. Nanotechnology 22(21), 275715 (2011)
S. Ning, H. Dong, N. Zhang, J. Zhao, L. Ding, Plasmonic enhancement of random lasing from dye-doped polymer film by bristled Ag/TiO2 composite nanowires. Opt. Mater. Express 6(12), 3725–3732 (2016)
Y. Wan, W. An, L. Deng, Plasmonic enhanced low-threshold random lasing from dye-doped nematic liquid crystals with TiN nanoparticles in capillary tubes. Sci. Rep. 7(1), 1–7 (2017)
H.L. Huang, C.F. Chou, S.H. Shiao, Y.C. Liu, J.J. Huang, S.U. Jen, H.P. Chiang, Surface plasmon-enhanced photoluminescence of DCJTB by using silver nanoparticle arrays. Opt. Express 21(105), A901–A908 (2013)
K. Aslan, Z. Leonenko, J.R. Lakowicz, C.D. Geddes, Fast and slow deposition of silver nanorods on planar surfaces: application to metal-enhanced fluorescence. J. Phys. Chem. B 109(8), 3157–3162 (2005)
S. Anna, S. Petr, K. Irena, M. Petr, M. Anna, V. Švorčík, Gold nanolayer and nanocluster coatings induced by heat treatment and evaporation technique. Nanoscale. Res. Lett. 8(1), 1–3 (2013)
B.M. Reinhard, M. Siu, H. Agarwal, A.P. Alivisatos, J. Liphardt, Calibration of dynamic molecular rulers based on plasmon coupling between gold nanoparticles. Nano Lett. 5(11), 2246–2252 (2005)
T. Zhai, J. Chen, L. Chen, J. Wang, L. Wang, D. Liu, S. Li, H. Liu, X. Zhang, A plasmonic random laser tunable through stretching silver nanowires embedded in a flexible substrate. Nanoscale 7(6), 2235–2240 (2015)
L. Long, D. He, W. Bao, M. Feng, P. Zhang, D. Zhang, S. Chen, Localized surface plasmon resonance improved lasing performance of Ag nanoparticles/organic dye random laser. J. Alloy. Compd. 693, 876–881 (2017)
S. Ning, Z. Wu, H. Dong, F. Yuan, J. **, L. Ma, B. Jiao, X. Hou, Enhanced lasing assisted by the Ag-encapsulated Au plasmonic nanorods. Opt. Lett. 40(6), 990–993 (2015)
C. Rohith, Z. Wang, X. Meng, S.I. Azzam, M.Y. Shalaginov, A. Lagutchev, Y.L. Kim, A. Wei, A.V. Kildishev, A. Boltasseva, V.M. Shalaev, Lasing action with gold nanorod hyperbolic metamaterials. ACS Photon. 4(3), 674–680 (2017)
X. Meng, A.V. Kildishev, K. Fujita, K. Tanaka, V.M. Shalaev, Wavelength-tunable spasing in the visible. Nano Lett. 13(9), 4106–4112 (2013)
D. Saxena, S. Mokkapati, P. Parkinson, N. Jiang, Q. Gao, H.H. Tan, C. Jagadish, Optically pumped room-temperature GaAs nanowire lasers. Nat. Photon. 7(12), 963–968 (2013)
G. Strangi, S. Ferjani, V. Barna, A.D. Luca, C. Versace, N. Scaramuzza, R. Bartolino, Random lasing and weak localization of light in dye-doped nematic liquid crystals. Opt. express 14(17), 7737–7744 (2006)
D.M. Bagnall, Y.F. Chen, Z. Zhu, T. Yao, S. Koyama, M.Y. Shen, T. Goto, Optically pumped lasing of ZnO at room temperature. Appl. Phys. Lett. 70(17), 2230–2232 (1997)
H. Cao, Y.G. Zhao, H.C. Ong, S.T. Ho, J.Y. Dai, J.Y. Wu, R.P.H. Chang, Ultraviolet lasing in resonators formed by scattering in semiconductor polycrystalline films. Appl. Phys. Lett. 73(25), 3656–3658 (1998)
H. Cao, Y.G. Zhao, S.T. Ho, E.W. Seelig, Q.H. Wang, R.P. Chang, Random laser action in semiconductor powder. Phys. Rev. Lett. 82(11), 2278–2281 (1999)
E. Heydari, R. Flehr, J. Stumpe, Influence of spacer layer on enhancement of nanoplasmon-assisted random lasing. Appl. Phys. Lett. 102(13), 133110 (2013)
N. Shuya, W. Zhaoxin, D. Hua, Y. Fang, X. Jun, M. Lin, J. Bo, H. Xun, Enhanced lasing assisted by the Ag-encapsulated Au plasmonic nanorods. Opt. Lett. 40(6), 990–993 (2015)
Acknowledgements
We acknowledge the International Cooperation Program for Excellent Lectures of 2017 by Shandong Province Education Department, the National Natural Science Foundation of China (Grant numbers 11874232, 11504194), the Key research and development plan in Shandong Province (Grant number 2018GGX101008), the Natural Science Foundation of Shandong Province, China (Grant number ZR2014FP012), and the Doctoral Found of QUST (Grant number 010022936).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Lü, H., Lan, Y., Zhao, Q. et al. Plasmonic enhancement of random lasing from dye-doped polymer with dispersed Au nanoparticles. Appl. Phys. B 124, 227 (2018). https://doi.org/10.1007/s00340-018-7097-4
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s00340-018-7097-4