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Systematic nanoarchitectonics of copper- and zinc-metal organic frameworks through ultrasonic assisted reverse micelle route for efficient adsorbents towards arsine gas

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Abstract

In this study, Cu and Zn-metal organic framework nanostructures were synthesized in the shortest possible time and with high efficiency using the ultrasonic assisted reverse micelle (UARM) method. Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy, and nitrogen adsorption techniques were used to characterize the synthesized samples. According to the BET method, the Cu-MOF sample has 410 m2/g of surface area and a volume pore of 0.021 cm3, whereas the corresponding values for Zn-MOF were 1145 m2/g and 0.097 cm3, respectively. The physicochemical properties of the products were thoroughly investigated, and the adsorbent dosage, temperature, and pressure for preparing samples with experimental parameters were 0.05 mg, 25.0 °C and 5.0 bar, respectively with high adsorption efficiency. Fractional factorial design and response surface methodology were used to design and control the best conditions. It could be used as an adsorbent in the adsorption of arsine gas.

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Acknowledgements

The authors would like to acknowledge from the Bam University of Medical Sciences.

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Authors and Affiliations

  1. University Malaysia of Computer Science & Engineering (UNIMY), Cyberjaya, Selangor, Malaysia

    Hossein Abbasi

  2. Department of Chemistry, Lorestan University, Khorramabad, Iran

    Parya Kazemzadeh

  3. Department of Environmental Health Engineering, School of Health, Birjand University of Medical Sciences, Birjand, Iran

    Taher Shahryari

  4. Department of Materials Engineering, Shahid Bahonar University of Kerman, Kerman, 76169-4111, Iran

    Malihe Zeraati

  5. Department of Chemistry, Faculty of Science, Bhupal Nobles’ University, Udaipur, 313002, Rajasthan, India

    Narendra Pal Singh Chauhan

  6. Noncommunicable Diseases Research Center, Bam University of Medical Sciences, Bam, Iran

    Ghasem Sargazi

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  1. Hossein Abbasi
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HA, PK, TS, MZ, NPSC and GS contributed equally including manuscript writing, figures preparation etc. All authors reviewed the manuscript.

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Correspondence to Taher Shahryari, Narendra Pal Singh Chauhan or Ghasem Sargazi.

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Abbasi, H., Kazemzadeh, P., Shahryari, T. et al. Systematic nanoarchitectonics of copper- and zinc-metal organic frameworks through ultrasonic assisted reverse micelle route for efficient adsorbents towards arsine gas. Appl. Phys. A 128, 869 (2022). https://doi.org/10.1007/s00339-022-06019-5

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