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Unusual high-density and saline aqueous inclusions in ultrahigh pressure metamorphic rocks from Sulu terrane in eastern China

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Chinese Science Bulletin

Abstract

Primary high-density fluid inclusions were identified in garnet from ultrahigh pressure eclogite in the southern part of the Sulu terrane. They occur isolatedly or in cluster together with relatively low-density two-phase inclusions. The eutectic temperature of the inclusions is as low as ≤52°C. A bubble was nucleated in a liquid inclusion during the specific stage of cyclic cooling-heating runs, and the liquid-gas homogenization temperature was measured to be ≤12.5°C. The composition of the inclusions modeled by the system CaCl2-NaCl-H2O, yields the fluid density of 1.27 g/cm that corresponds to a pressure of ca. 2.4 GPa at the temperature of peak eclogite-facies metamorphism, close to the ultrahigh pressure metamorphic conditions. During the exhumation of the eclogite the inclusions reacted with the host mineral, forming hydrous silicate minerals that resulted in lowering of the fluid density and its transformation to multi-phase inclusions.

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References

  1. Roedder, E., Fluid inclusions, Reviews in Mineralogy, Washington DC: Mineral. Soc. Amer., 1984, 12.

    Google Scholar 

  2. Fu, B., Touret, J. L. R., Zheng, Y. F., Fluid inclusions in coesite-bearing eclogites and jadeite quartzite at Shuanghe, Dabie Shan (China), J. Metamorphic Geology, 2001, 19: 529–545.

    Google Scholar 

  3. Franz, L., Romer, R. L., Klemd, R. et al., Eclogite-facies quartz veins within metabasites of the Dabie Shan (eastern China): pressure-temperature-time-deformation path, composition of the fluid phase and fluid flow during exhumation of high-pressure rocks, Contnb. Mineral. Petrol., 2001, 141: 322–346.

    Google Scholar 

  4. Klemd, R., Brocker, M., Schramm, J., Characterization of amphibolite-facies fluids of Variscan eclogites from the Orlica-Snieznik dome (Sudetes, SW Poland), Chem. Geol., 1995, 119: 101–113.

    Article  Google Scholar 

  5. Touret, J. L. R., Fluid inclusions in subducted rocks, Proc. Kon. Ned. Akad. v. Wetensch., 1992, 95(3): 385–403.

    Google Scholar 

  6. Philippot, P., Fluid-melt-rock interaction in mafic eclogites and coesite-bearing metasediments: constraints on volatile recycling during subducion, Chem. Geol., 1993, 108: 93–112.

    Article  Google Scholar 

  7. Philippot, P., Chevallier, P., Chopin, C. et al., Fluid composition and evolution in the coesite-bearing rocks of the Dora Maira Massif, Western Alps, Contnb. Mineral. Petrol., 1995, 121: 29–44.

    Article  Google Scholar 

  8. Philippot, P., The Chemistry of high-pressure fluids (1 to 3 GPa): natural observations vs. experimental constraints, Earth Sci. Front. (China Univ. Geosci., Bei**g), 1996, 3: 39–52.

    Google Scholar 

  9. Bakker, A. J., Post-entrapment modification of fluid inclusions due to overpressure: evidence from natural samples, J. Metamor. Geol., 1995, 13: 737–750.

    Article  Google Scholar 

  10. **ao, Y., Hoefs, J., van den Kerkhof, A. M. et al., Fluid history of UHP metamorphism in Dabie Shan, China: a fluid inclusion and oxygen isotope study on the coesite-bearing eclogite from Bixiling, Contnb. Mineral. Petrol., 2000, 139: 1–16.

    Article  Google Scholar 

  11. Svensen, H., Jemtveit, B., Banks, D. A. et al., Halogen contents of eclogite facies fluid inclusions and minerals: Caledonides, western Norway, J. Metamor. Geol., 2001, 19: 165–178.

    Article  Google Scholar 

  12. Liu, F., Xu, Z., Katayama, I. et al., Mineral inclusions in zircons of paraand orthogneiss from pre-pilot drillhole CCSD-PP1, Chinese Continental Scientific Dnlling Project, Lithos, 2001, 59: 199–215.

    Google Scholar 

  13. Lawler, J. P., Crawford, M. L., Stretching of fluid inclusions resulting from a low-temperature microthermometric technique, Econ. Geol., 1983, 78: 527–529.

    Article  Google Scholar 

  14. Oakes, C. S., Bodnar, R. J., Simonson, J. M., The system NaCl-CaCl-H2O: I. The ice liquidus at 1 atm total pressure, Geochim. Cosmochim. Acta, 1990, 54: 603–610.

    Article  Google Scholar 

  15. Willliams-Jones, A. E., Samson, I. M., Theoretical estimation of halite solubility in the system NaCl-CaCl2-H2O: Applications to fluid inclusions, Can. Mineral., 1990, 28: 299–304.

    Google Scholar 

  16. Bakker, R. J., Manish, M. A., Fluid inclusions as metamorphic process indicators in the Southern Aravalli Mountain belt (India), Contnb. Mineral. Petrol., 2000, 139: 163–179.

    Article  Google Scholar 

  17. Zhang, Y. G., Frantz, J. D., Determination of the homogenization temperatures and densities of supercritical fluids in the system NaCl-KCl-CaCl2-H2O using synthetic fluid inclusions, Chem. Geol., 1987, 64: 335–350.

    Article  Google Scholar 

  18. Zhang, R. Y., Hirajima, T., Banno, S. et al., Petrology of ultrahighpressure rocks from the southern Su-Lu region, eastern China, J. Metamorphic Geol., 1995, 13: 659–675.

    Article  Google Scholar 

  19. Zheng, Y., Fu, B., Li, Y. et al., Oxygen and hydrogen isotope geochemistry of ultrahigh pressure eclogites from the Dabie Mountains and the Sulu terrane, Earth Planet. Sci. Lett., 1998, 155: 113–129.

    Article  Google Scholar 

  20. Kiister, M., Stockhert, B., Density changes of fluid inclusions in high-pressure, low-temperature metamorphic rocks from Crete: A thermodynamic approach based on the creep strength of the host minerals, Lithos, 1997, 41: 151–167.

    Article  Google Scholar 

  21. Bohlen, S. R., Boettcher, A. L., The quartz-coesite transformation: a pressure determination and the effects of other composition, J. Geophys. Res., 1982, 87: 7073–7078.

    Article  Google Scholar 

  22. Kennedy, C. A., Kennedy, G. C., The equilibrium boundary between graphite and diamond, J. Geophys. Res., 1976, 81: 2467–3470.

    Article  Google Scholar 

  23. Andersen, T., Burke, E. A. J., Austrheim, H., Nitrogen-bearing, aqueous fluid inclusions in some eclogites from the Western Gneiss Region of the Norwegian Caledonides, Contrib. Mineral. Petrol., 1989, 103: 153–165.

    Article  Google Scholar 

  24. Klemd, R., van der Kerkhof, M., Horn, E. E., High-density CO2-N2 inclusions in eclogite-facies metasediments of the Muncheberg gneiss complex, SE Germany, Contrib. Mineral. Petrol., 1992, 111: 409–419.

    Article  Google Scholar 

  25. Zheng, Y., Fu, B., **ao, Y. et al., Hydrogen and oxygen isotope evidence for fluid-rock interactions in the stages of preand post-UHP metamorphism in the Dabie Mountains, Lithos, 1999, 46: 677–693.

    Article  Google Scholar 

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Correspondence to Zeming Zhang.

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Shen, K., Zhang, Z., van den Kerkhof, A.M. et al. Unusual high-density and saline aqueous inclusions in ultrahigh pressure metamorphic rocks from Sulu terrane in eastern China. Chin. Sci. Bull. 48, 2018–2023 (2003). https://doi.org/10.1007/BF03183997

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  • DOI: https://doi.org/10.1007/BF03183997

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