SpringerLink
Log in

Kinetic studies of detergency. I. Analysis of cleaning curves

  • Technical
  • Published:
Journal of the American Oil Chemists’ Society

Abstract

The kinetics of removal of thin films of pure radioactive tristearin from a stainless-steel surface by .03M NaOH was studied in a circulation system. The data obtained are consistent with the presence of two species of tristearin, each species being removed simultaneously by a first-order process and behaving independently of the other. The principal evidence for the existence of the two species is the excellent agreement of the experimental data with the mathematical techniques of kinetics over a wide range of experimental conditions. Rate constants for the removal of each species and the relative proportions of the two species are given for different experimental conditions. It is shown that the difference between the two species must be based on some physical factor, and possible explanations are discussed. The presence of two species gives a satisfactory explanation for hitherto unexplained results of other workers.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price includes VAT (France)

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Ackley, R. R., Ann. N.Y. Acad. Sci.,46, 511–530 (1946).

    Article  CAS  Google Scholar 

  2. Anderson, R. M., J. J. Satanek, and J. C. Harris, JAOCS,36, 286 (1959).

    Article  CAS  Google Scholar 

  3. Anderson, R. M., J. J. Satanek, and J. C. HarrisIbid., 37, 119 (1960).

    Article  CAS  Google Scholar 

  4. Bacon, O. C., and J. E. Smith, Ind. Eng. Chem.,40, 2361–2370 (1948).

    Article  CAS  Google Scholar 

  5. Bourne, M. C., and W. G. Jennings, Food Technol.,15, 495–499 (1961).

    CAS  Google Scholar 

  6. Ferguson, R. H., and E. S. Lutton, Chem. Revs.,29, 353 (1941).

    Article  Google Scholar 

  7. Fineman, M. N., and Phyllis J. Kline, J. Colloid Sci.,8, 288–299 (1958).

    Article  Google Scholar 

  8. Guadagni, D. G., S. H. Kelly, and L. L. Ingraham, Food Res.,25, 464 (1960).

    CAS  Google Scholar 

  9. Harris, J. C., Textile Res. J.,29, 99 (1959).

    CAS  Google Scholar 

  10. Harris, J. C., R. M. Anderson, and J. Satanek, JAOCS,38, 123 (1961).

    Article  CAS  Google Scholar 

  11. Harris, J. C., and J. Satanek,Ibid., 38, 244 (1961).

    Article  CAS  Google Scholar 

  12. Harris, J. C., and J. Satanek,Ibid., 38, 169 (1961).

    Article  CAS  Google Scholar 

  13. Hensley, J. W., Iron Age (Nov. 13), 151 (1952).

    Google Scholar 

  14. Hensley, J. W., H. A. Skinner, and H. R. Suter, Metal Finishing (Aug.) 77 (1952).

  15. Hucker, G. J., A. J. Emergy, and Elizabeth Winkel, J. Milk and Food Tech.,14, 95 (1951).

    Google Scholar 

  16. Jennings, W. G., J. Dairy Sci.,42, 1763 (1959).

    Article  CAS  Google Scholar 

  17. Jones, T. G., Surface Activity and Detergency, ed. by J. Durham, Macmillan and Co., London, 1961, p. 90.

    Google Scholar 

  18. Jones, T. G.,Ibid. p. 104.

    Google Scholar 

  19. Lachampt, F., C. Zviak, and H. Rossignol, Surface Chemistry, Butterworths, London, 1949, pp. 165–170.

    Google Scholar 

  20. Laidler, K. J., Catalysis, Vol. 1, ed. by P. H. Emmett, Reinhold Publishing Co., N. Y., 1954, p. 132.

    Google Scholar 

  21. Lawrence, A. S. C., Nature,183, 1237 (1959).

    Google Scholar 

  22. Mankowich, A. M., JAOCS,38, 589 (1961).

    CAS  Google Scholar 

  23. Masurovsky, E. B., and W. K. Jordan, J. Dairy Sci.,43, 1545 (1960).

    Article  Google Scholar 

  24. Matantsev, A. I., Zhurnal Prikladnoi Khimii,33, 674 (1960). (Journal of Applied Chemistry of U.S.S.R. English Translation 679)

    CAS  Google Scholar 

  25. Norris, F. I., and C. C. Ruchhoft, Public Health Reports,63, 97 (1948).

    CAS  Google Scholar 

  26. O’Connor, T. L., and H. H. Uhlig, J. Phys. Chem.,61, 402 (1957).

    Article  CAS  Google Scholar 

  27. Patrick, R. L., and G. O. Payne, Jr., J. Colloid Sci.,16, 93 (1961).

    Article  CAS  Google Scholar 

  28. Pedersen, L., Ingenioren,67, 681 (1958).

    Google Scholar 

  29. Pflug, I. J., T. I. Hedrick, O. W. Kaufmann, R. A. Keppeler, and C. C. Pheil, J. Milk and Food Technol.,24, 390 (1961).

    Google Scholar 

  30. Powe, W. C., Textile Res. J.,29, 879 (1959).

    CAS  Google Scholar 

  31. Rhodes, F. H., and S. W. Brainard, Ind. Eng. Chem.,21, 60 (1929).

    Article  CAS  Google Scholar 

  32. Romero, E. L., and H. A. Stern, Inst. of Radio Engineers, International Convention Record, 1960, part 6 pp. 225–231.

  33. Shuttleworth, T. H., and T. G. Jones, Proc. 2d. Int. Cong. Surface Activity, Vol. 4, Butterworths, London, 1957, p. 52.

    Google Scholar 

  34. Utermohlen, W. P., Jr., and Mary Ryan, Ind. Eng. Chem.,41, 2881 (1949).

    Article  CAS  Google Scholar 

  35. Utermohlen, W. P., Jr., and E. L. Wallace, Textile Res. J.,17, 670 (1947).

    Article  CAS  Google Scholar 

  36. Vaeck, S. V., A. V. Nuffel, and G. Wouters-VanLook, Teintex,21, 605 (1956).

    Google Scholar 

  37. Vaughn, T. H., A. Vittone, Jr., and L. R. Bacon, Ind. Eng. Chem.,33, 1011 (1941).

    Article  CAS  Google Scholar 

  38. Wagg, R. E., and C. J. Britt, Nature,180, 49 (1957).

    Article  Google Scholar 

Download references

Author information

Author notes

  1. M. C. Bourne

    Present address: Dept. of Food Science and Technology, New York State Agricultural Experiment Station, Cornell University, Geneva, N.Y.

Authors and Affiliations

  1. Department of Food Science and Technology, University of California, Davis, California

    M. C. Bourne & W. G. Jennings

Authors
  1. M. C. Bourne
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. W. G. Jennings
    View author publications

    You can also search for this author in PubMed Google Scholar

About this article

Cite this article

Bourne, M.C., Jennings, W.G. Kinetic studies of detergency. I. Analysis of cleaning curves. J Amer Oil Chem Soc 40, 517–523 (1963). https://doi.org/10.1007/BF02822456

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02822456

Keywords

Search

Navigation