Abstract
In terms of the donor-acceptor interaction concept /1/ the relative reactivity (RR) of organic and inorganic compounds and its correlation with catalyst properties in deep oxidation reactions are treated. RR and relative activity of the catalysts are shown to change depending on the predominant character (acceptor or donor) of reactant-catalyst interaction.
Abstract
На основе концепции донорно-акцепторных взаимодейстний /1/ дана трактовка относительной реакционной способности (OPC) органических и неорганических соединений и её связи со свойствами катализаторов в реакциях глубокого окисления. Показано, что OPC и относительная активность катализаторов меняются в зависимости от преимущественно акцепторного или донорного характера взаимодействий реагента с катализатором.
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Sokolovskii, V.D. Reactivity of oxidized substances and its correlation with catalyst properties in deep oxidation reactions. React Kinet Catal Lett 18, 257–260 (1981). https://doi.org/10.1007/BF02065603
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DOI: https://doi.org/10.1007/BF02065603