Summary
Gold(I) forms linear [AuL2]X complexes (X = Cl, Br, I or CIO4) with thioacetamide and thiobenzamide, AuLX compounds with thiobenzamide (X = CI or Br),N, N-dimethylthioformamide (X = Cl, Br or 1) andN-dimethylthioacetamide (X = CI, Br or 1). Thev(AuS) vibrations are assigned in the 320-260 cm−1 range. The i.r. spectra further suggest hydrogen bonding between the ligands and the anions. The conductivity measurements indicate dissociation of the [AuL2]X complexes (X = halide) and coordination of X in solution.
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Presented in part at the XIX ICCC, Prague, 1978.
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Aarts, A.J., Desseyn, H.O. & Herman, M.A. Gold(I) complexes of thioamides. Transition Met Chem 5, 10–14 (1980). https://doi.org/10.1007/BF01396857
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DOI: https://doi.org/10.1007/BF01396857