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Palladium catalysts on carbon supports

1. General features of adsorption of H2PdCl4 on carbon supports

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of H2PdCl4 with carbon supports results in the formation of chloride complexes of Pd(II) with adsorption sites located on the unoxidized sections of the surface.

  2. 2.

    At least three types of H2PdCl4 adsorption sites which differ in the strength of the complexes with Pd(II) formed and the reactivity to the effect of oxidants were found. It was hypothesized that the elements of the π system of the carbon support are the adsorption sites of Pd(II).

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Authors and Affiliations

  1. Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk

    P. A. Simonov, V. A. Semikolenov, V. A. Likholobov, A. I. Boronin & Yu. I. Ermakov

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  1. P. A. Simonov
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  2. V. A. Semikolenov
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  3. V. A. Likholobov
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  4. A. I. Boronin
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  5. Yu. I. Ermakov
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Additional information

Deceased.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2719–2724, December, 1988.

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Simonov, P.A., Semikolenov, V.A., Likholobov, V.A. et al. Palladium catalysts on carbon supports. Russ Chem Bull 37, 2447–2451 (1988). https://doi.org/10.1007/BF00952615

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  • DOI: https://doi.org/10.1007/BF00952615

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