Abstract
The adsorption of poly(acrylonitrile), poly(methyl acrylate), poly(ethyl acrylate) and poly(butyl acrylate) was studied at different temperatures fromN,N′-dimethyl formamide solution on various solid surfaces, i.e. silica gel, alumina and calcium carbonate. The thermodynamic quantities for adsorption processes were computed by using a) infinite dilution and b) surface coverage approaches. Both procedures tend to give similar conclusions. These reveal the importance of polymer-adsorbent interactions besides many other properties including solvent power.
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References
Napper DH (1983) Polymeric Stabilization of Colloidal Dispersons, Academic Press, New York
Sate T, Ruch R (1980) Stabilization of Colloidal Dispersions by Polymer Adsorption, Marcell Dekker, New York
Freeman WJ (1985) In: Salvatore A (ed), Encyclopedia of Polymer Science and Engineering, Vol. 3. John Wiley, New York
Joseph R, Devi S, Rakshit AK (1991) Polym Inter 26:89
Vangani V, Joseph R, Devi S, Rakshit AK (1991) Colloid Polym Sci 269:242
Daniel SG (1951) Trans Faraday Soc 47:1345
Parfitt GD, Rochester CH (1983) In: Parfitt GD, Rochester CH (eds), Adsorption from Solution at the Solid/Liquid Interface. Academic Press, London
Mitra SP, Chattoraj DK (1978) Ind J Biochem Biophysics 15:149
Greenwood FG, Parfitt GD, Picton NH, Wharton DG (1968) Adv Chem Ser 79:135, ACS, Washington DC
Zettlemoyer AC (1968) J Coll Interface Sci 28:343
Johnson HE, Granick S (1991) Macromolecules 24:3023
Silberberg A (1972) J Coll Interface Sci 38:217
Priel Z, Silberberg A (1978) J Polym Sci Polym Phys Ed 16:1917
Polonski TM (1966) Vysokomol Soed 8:1901; taken from Chem Abst
Dijt JC, Cohen Stuart MA, Hofman JE, Fleer GJ (1990) Coll Surf 51:41.
Vander Beek GP, Cohen Stuart MA, Fleer GJ (1991) Macromolecules 24:3553
Nedeltscheva I, Bencheva S, Valcheva E, Valchev V (1987) Colloid Polym Sci 265:312
Patat F, Schliebener C (1961) Macromol Chem 44:643
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Joseph, R., Vangani, V., Devi, S.G. et al. Studies of adsorption of polyacrylonitrile and polyacrylates at solid-liquid interface. Colloid Polym Sci 272, 130–140 (1994). https://doi.org/10.1007/BF00658839
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DOI: https://doi.org/10.1007/BF00658839