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Synthesis and characterization of the narrow polydispersity fullerene-end-capped polystyrene

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Summary

A living free radical polymerization process was adopted to synthesize a narrow polydispersity fullerene-end-capped polystyrene(NPFECPS). The UV-Vis, DSC, GPC demonstrated that fullerene(C60) was chemically bonded to polystyrene successfully, and C60 was almost monosubstituted. The NPFECPS can be dissolved in a variety of solvents, such as THF, toluene, trichloromethane, and so on. The good photoconductivity is also found for NPFECPS.

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Authors and Affiliations

  1. Department of Macromolecular Science, Fudan University, 200433, Shanghai, People's Republic of China

    Changchun Wang, Junpo He & Shoukuan Fu

  2. Institute of Polymer Science and Materials, Zhejiang University, 310027, Hangzhou, People's Republic of China

    Kejian Jiang, Hongzheng Cheng & Mang Wang

Authors
  1. Changchun Wang
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  2. Junpo He
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  3. Shoukuan Fu
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  4. Kejian Jiang
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  5. Hongzheng Cheng
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  6. Mang Wang
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Wang, C., He, J., Fu, S. et al. Synthesis and characterization of the narrow polydispersity fullerene-end-capped polystyrene. Polymer Bulletin 37, 305–311 (1996). https://doi.org/10.1007/BF00318062

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  • DOI: https://doi.org/10.1007/BF00318062

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