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Orientation in uniaxially stretched plasticized atactic polystyrene

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Summary

Fourier transform infrared spectroscopy and birefringence measurements have been used to study the changes in molecular orientation which occur on drawing of plasticized as compared to pure polystyrene (PS) at a temperature T=Tg+Cte. No influence of plasticizers on orientation can be detected whatever the interactions between small molecules and PS chains are. Comparison with previous results obtained on PS-poly(vinylmethyl ether) compatible blends confirms the importance of the macromolecular nature of the second component to enhance the friction coefficient leading to higher level of chain orientation.

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Authors and Affiliations

  1. Laboratoire de Physicochimie Structurale et Macromoléculaire, Ecole Supérieure de Physique et de Chimie de la Ville de Paris, 10, rue Vauquelin, F-75231, Paris Cedex 05, France

    Y. Zhao, B. Jasse & L. Monnerie

Authors
  1. Y. Zhao
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  2. B. Jasse
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  3. L. Monnerie
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Zhao, Y., Jasse, B. & Monnerie, L. Orientation in uniaxially stretched plasticized atactic polystyrene. Polymer Bulletin 13, 259–262 (1985). https://doi.org/10.1007/BF00254660

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  • DOI: https://doi.org/10.1007/BF00254660

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