Abstract
The influence of non macroporous and macroporous supports on a test reaction is studied. t-BuOH reacts with tetra O-acetyl bromoglucose in presence of silver nitrate and a supported crown ether. Two reaction products are formed. Yield and selectivity are affected by the morphology of the support. The selectivity depends on the crosslinking degree. This dependence is explained by the rigidity of the matrix and by the variation of steric hindrance.
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Capillon, J., Ricard, A., Audebert, R. et al. Importance of the texture of the resin in crown ether supported catalysis. Polymer Bulletin 13, 185–192 (1985). https://doi.org/10.1007/BF00254229
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DOI: https://doi.org/10.1007/BF00254229