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Synthesis, structure and electrochemical behaviour of cobalt(II) complexes with 2,6-bis(benzimidazol-2′-yl) pyridine

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The complexes Co(BBP)Cl2, Co(BBP)2SO4·H2O, Co(BBP)2(NO3)2·H2O, Co(BBP)2(ClO4)2 and Co(BBP−H)2· 2H2O, where BBP is 2,6-bis(benzimidazol-2′-yl) pyridine, were prepared and characterized by elemental analysis, electrical conductance, i.r. and electronic spectra. The electrochemical behaviour of the complexes was recorded and the X-ray crystal structure of Co(BBP)Cl2(MeOH)2 was determined. The geometry about cobalt is a distorted octahedron.

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Wang, S., Yu, S., Luo, Q. et al. Synthesis, structure and electrochemical behaviour of cobalt(II) complexes with 2,6-bis(benzimidazol-2′-yl) pyridine. Transition Met Chem 19, 205–208 (1994). https://doi.org/10.1007/BF00161890

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