SpringerLink
Log in

N-heterocyclic carbene-based polymer coating of gold nanoparticles and luminescent quantum dots

  • Original Paper
  • Published:
MRS Advances Aims and scope Submit manuscript

Abstract

We test the capacity of two N-heterocyclic carbene (NHC)-based metal-coordinating compounds that present polyethylene glycol solubilizing blocks, a polymer and monomer, as ligands for the surface passivation of colloidal gold nanoparticles, luminescent quantum dots, and iron oxide nanoparticles (IONPs) alike in water. The long-term colloidal stability of the NHC-stabilized nanocolloids has been tested following phase transfer to aqueous media, which presents a highly challenging environment for such groups, due to the moisture-sensitive nature of NHC molecules. We find that nanocrystals coated with these NHC-containing ligands exhibit long-term colloidal stability in buffer media with no sign of degradation or aggregation build-up, while preserving their photo-physical properties, for extended periods of time.

Graphical abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. P.K. Jain, X. Huang, I.H. El-Sayed, M.A. El-Sayed, Plasmonics (2007). https://doi.org/10.1007/s11468-007-9031-1

    Article  Google Scholar 

  2. M.-C. Daniel, D. Astruc, Chem. Rev. (2004). https://doi.org/10.1021/cr030698

    Article  Google Scholar 

  3. I.L. Medintz, H.T. Uyeda, E.R. Goldman, H. Mattoussi, Nat. Mater. (2005). https://doi.org/10.1038/nmat1390

    Article  Google Scholar 

  4. Y. Shirasaki, G.J. Supran, M.G. Bawendi, V. Bulović, Nat. Photon. (2013). https://doi.org/10.1038/nphoton.2012.328

    Article  Google Scholar 

  5. W. Wang, H. Mattoussi, Acc. Chem. Res. (2020). https://doi.org/10.1021/acs.accounts.9b00641

    Article  Google Scholar 

  6. C.-H.M. Chuang, P.R. Brown, V. Bulović, M.G. Bawendi, Nat. Mater. (2014). https://doi.org/10.1038/nmat3984

    Article  Google Scholar 

  7. R. Sardar, A.M. Funston, P. Mulvaney, R.W. Murray, Langmuir (2009). https://doi.org/10.1021/la9019475

    Article  Google Scholar 

  8. P. Pyykkö, N. Runeberg, Chem. Asian J. (2006). https://doi.org/10.1002/asia.200600181

    Article  Google Scholar 

  9. M. Rodríguez-Castillo, G. Lugo-Preciado, D. Laurencin, F. Tielens, S. Clément, Y. Guari, J.M. López-De-Luzuriaga, M. Monge, F. Remacle, S. Richeter, Chem. Eur. J. (2016). https://doi.org/10.1002/chem.201601253

    Article  Google Scholar 

  10. A.V. Zhukhovitskiy, M.G. Mavros, T. Van Voorhis, J.A. Johnson, J. Am. Chem. Soc. (2013). https://doi.org/10.1021/ja401965d

    Article  Google Scholar 

  11. N.A. Nosratabad, Z. **, L. Du, M. Thakur, H. Mattoussi, Chem. Mater. (2021). https://doi.org/10.1021/acs.chemmater.0c03918

    Article  Google Scholar 

  12. L. Du, N.A. Nosratabad, Z. **, C. Zhang, S. Wang, B. Chen, H. Mattoussi, J. Am. Chem. Soc. (2021). https://doi.org/10.1021/jacs.0c10592

    Article  Google Scholar 

  13. N. Arabzadeh Nosratabad, Z. **, L. Du, H. Mattoussi, SPIE BiOS (2022). https://doi.org/10.1117/12.2610485

    Article  Google Scholar 

  14. J.-F. Soule, H. Miyamura, S. Kobayashi, J. Am. Chem. Soc. (2013). https://doi.org/10.1021/ja404006w

    Article  Google Scholar 

  15. A. Rühling, K. Schaepe, L. Rakers, B. Vonhören, P. Tegeder, B.J. Ravoo, F. Glorius, Angew. Chem. Int. Ed. (2016). https://doi.org/10.1002/anie.201508933

    Article  Google Scholar 

  16. W. Wang, A. Kapur, X. Ji, M. Safi, G. Palui, V. Palomo, P.E. Dawson, H. Mattoussi, J. Am. Chem. Soc. (2015). https://doi.org/10.1021/jacs.5b00671

    Article  Google Scholar 

  17. S. Liu, G. Chen, P.N. Prasad, M.T. Swihart, Chem. Mater. (2011). https://doi.org/10.1021/cm201343k

    Article  Google Scholar 

  18. C. Murray, D.J. Norris, M.G. Bawendi, J. Am. Chem. Soc. (1993). https://doi.org/10.1021/ja00072a025

    Article  Google Scholar 

  19. Z.A. Peng, X. Peng, J. Am. Chem. Soc. (2001). https://doi.org/10.1021/ja003633m

    Article  Google Scholar 

  20. J. Park, K. An, J.-G.P.Y. Hwang, H.-J. Noh, J.-Y. Kim, J.-H. Park, N.-M. Hwang, T. Hyeon, Nat. Mater. (2004). https://doi.org/10.1038/nmat1251

    Article  Google Scholar 

  21. M.N. Hopkinson, C. Richter, M. Schedler, F. Glorius, Nature (2014). https://doi.org/10.1038/nature13384

    Article  Google Scholar 

  22. L. Du, S. Helsper, N.A. Nosratabad, W. Wang, D.A. Fadool, C. Amiens, S. Grant, H. Mattoussi, Bioconjug. Chem. (2022). https://doi.org/10.1021/acs.bioconjchem.2c00116

    Article  Google Scholar 

  23. B. Zeng, G. Palui, C. Zhang, N. Zhan, W. Wang, X. Ji, B. Chen, H. Mattoussi, Chem. Mater. (2018). https://doi.org/10.1021/acs.chemmater.7b04204

    Article  Google Scholar 

Download references

Acknowledgments

The authors thank FSU and the National Science Foundation (NSF-CHE #2005079) and Kasei-Asahi for financial support.

Author information

Authors and Affiliations

  1. Department of Chemistry and Biochemistry, Florida State University, 95 Chieftan Way, Tallahassee, FL, 32306, USA

    Neda Arabzadeh Nosratabad, Zhicheng **, Liang Du & Hedi Mattoussi

Authors
  1. Neda Arabzadeh Nosratabad
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Zhicheng **
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Liang Du
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Hedi Mattoussi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Hedi Mattoussi.

Ethics declarations

Conflict of interest

The authors declare no competing financial interest.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Arabzadeh Nosratabad, N., **, Z., Du, L. et al. N-heterocyclic carbene-based polymer coating of gold nanoparticles and luminescent quantum dots. MRS Advances 8, 336–342 (2023). https://doi.org/10.1557/s43580-023-00555-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/s43580-023-00555-9

Search

Navigation