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Influence of the Type of Carbon Material on the Formation of a Heat-Conductive Frame in Granules of Cobalt Catalyst for Fischer–Tropsch Synthesis

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Abstract

A series of granulated composite materials based on alumina and zeolite are prepared. The effect of carbon materials (thermally expanded graphite (TEG), element graphite, colloidal graphite, channel black, carbon nanotubes) on the physical-chemical and catalytic properties of prepared cobalt-containing systems is investigated. It is shown that the obtained heat-conductive frame is of critical importance for catalyst granule stability at high reagent velocities.

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REFERENCES

  1. P. M. Maitlis and A. de Klerk, Greener Fissher–Tropssh Processes (Wiley-VCH, Weinheim, 2013).

    Google Scholar 

  2. D. Merino, O. Sanz, and M. Montes, Fuel 210, 49 (2017). https://doi.org/10.1016/j.fuel.2017.08.040

    Article  CAS  Google Scholar 

  3. C. G. Visconti, E. Tronconi, G. Groppi, et al., Chem. Eng. J. 171, 1294 (2011). https://doi.org/10.1016/j.cej.2011.05.014

    Article  CAS  Google Scholar 

  4. L. Fratalocchi, C. G. Visconti, G. Groppi, et al., Chem. Eng. J. 349, 829 (2018). https://doi.org/10.1016/j.cej.2018.05.108

    Article  CAS  Google Scholar 

  5. J. C. Park, N. S. Roh, D. H. Chun, et al., Fuel Proc. Tech. 119, 60 (2014). https://doi.org/10.1016/j.fuproc.2013.10.008

    Article  CAS  Google Scholar 

  6. T. Fu and Z. Li, Chem. Eng. Sci. 135, 3 (2015). https://doi.org/10.1016/j.ces.2015.03.007

    Article  CAS  Google Scholar 

  7. E. Asalieva, K. Gryaznov, E. Kulchakovskaya, et al., Appl. Catal. A 505, 260 (2015). https://doi.org/10.1016/j.apcata.2015.08.006

    Article  CAS  Google Scholar 

  8. D. Wang, C. Chen, J. Wang, et al., Appl. Catal. A 527, 60 (2016). https://doi.org/10.1016/j.apcata.2016.08.027

    Article  CAS  Google Scholar 

  9. GOST (State Standard) 17219-71: The coals are active. Method for determining the total pore volume in water.

  10. V. Z. Mordkovich, L. V. Sineva, E. V. Kul’chakovskaya, et al., “Catalyst for Fischer-Tropsch synthesis and process for producing this catalyst,” RF Patent No. 2685437 (2017).

  11. A. P. Karnaukhov, Adsorption. Texture of Dispersed and Porous Materials (Nauka, Novosibirsk, 1999) [in Russian].

    Google Scholar 

  12. T. Morishita, M. Matsushita, Y. Katagiri, et al., J. Mater. Chem. 21, 5610 (2011). https://doi.org/10.1039/c0jm04007j

    Article  CAS  Google Scholar 

  13. D. G. Larrude, P. Ayala, M. E. H. M. da Costa, et al., J. Nanomaterials 2012, 1 (2012). https://doi.org/10.1155/2012/695453

    Article  CAS  Google Scholar 

  14. M. Rahmati, B. Huang, M. K. Mortensen, et al., J. Catal. 359, 92 (2018). https://doi.org/10.1016/j.jcat.2017.12.022

    Article  CAS  Google Scholar 

  15. V. Ermolaev, K. Gryaznov, E. Mitberg, et al., Chem. Eng. Sci. 138, 1 (2015). https://doi.org/10.1016/j.ces.2015.07.036

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

We are grateful to I.A. Perezhogin for research in the field of transmission electron microscopy and S.I. Zholudev for measurements in the X-ray diffraction and processing of the results.

The work was carried out using equipment of the Center for Collective Use of the Federal State Budgetary Institution Technological Institute For Superhard and Novel Carbon Materials “Studies of Nanostructural, Carbon, and Superhard Materials.”

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Authors and Affiliations

  1. Technological Institute for Superhard and Novel Carbon Materials, 108840, Troitsk, Moscow, Russia

    K. O. Gryaznov, L. V. Sineva, D. A. Ovsyannikov, E. O. Nalivaiko & V. Z. Mordkovich

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  1. K. O. Gryaznov
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  2. L. V. Sineva
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  3. D. A. Ovsyannikov
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  4. E. O. Nalivaiko
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  5. V. Z. Mordkovich
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Correspondence to K. O. Gryaznov.

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Translated by Sh. Galyaltdinov

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Gryaznov, K.O., Sineva, L.V., Ovsyannikov, D.A. et al. Influence of the Type of Carbon Material on the Formation of a Heat-Conductive Frame in Granules of Cobalt Catalyst for Fischer–Tropsch Synthesis. Nanotechnol Russia 17, 550–558 (2022). https://doi.org/10.1134/S2635167622040103

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  • DOI: https://doi.org/10.1134/S2635167622040103

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