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Preparation and Properties of Polypropylene Compositions with Binary Carbon Nanofillers

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Abstract

Composites based on polypropylene and binary carbon nanofillers (graphene particles and single-walled carbon nanotubes) have been synthesized by in situ polymerization using the homogeneous isospecific metallocene catalyst rac-Me2Si(2-Me-4-PhInd)2ZrCl2 activated by methylaluminoxane. The use of binary carbon nanofillers increases thermal stability and resistance to thermo-oxidative degradation and affects the reflectance and other electrical characteristics of synthesized materials. It has been shown that the binary nanofillers can have a synergistic effect on the thermal oxidation of polypropylene. The introduction of even a small amount of single-walled carbon nanotubes into graphene nanoplatelets significantly reduces the reflection coefficient of the resulting composite materials.

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Funding

The work was carried out within the framework of the State Assignment for the Basic Research Program of the Russian Academy of Sciences (no. FFZE-2022-0009).

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Authors and Affiliations

  1. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, 119991, Moscow, Russia

    O. M. Palaznik, P. M. Nedorezova, V. G. Krasheninnikov, A. N. Klyamkina & A. A. Gulin

  2. Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences, 117393, Moscow, Russia

    V. G. Shevchenko

  3. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 117997, Moscow, Russia

    T. V. Monakhova

  4. Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia

    A. A. Arbuzov

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  1. O. M. Palaznik
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  3. V. G. Shevchenko
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  4. V. G. Krasheninnikov
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Correspondence to P. M. Nedorezova.

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Translated by S. Zatonsky

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Palaznik, O.M., Nedorezova, P.M., Shevchenko, V.G. et al. Preparation and Properties of Polypropylene Compositions with Binary Carbon Nanofillers. Polym. Sci. Ser. B 65, 935–945 (2023). https://doi.org/10.1134/S1560090423600316

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  • DOI: https://doi.org/10.1134/S1560090423600316

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