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Hybrid Photopolymer Material Based on (8-Acryloyl-1,4-dithia-8-azaspiro[4.5]decan-2-yl)methyl Acrylate and Thiol-Siloxane Component for Recording Microstructures: Synthesis and Optical and Thermomechanical Properties

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Abstract

A transparent hybrid photopolymer material is synthesized on the basis of (8-acryloyl-1,4-dithia-8-azaspiro[4.5]decan-2-yl)methyl acrylate and 3-[3-(3-mercaptopropyl)-1,1,3,5-tetramethoxy-5,5-diphenyltrisiloxane]propane-1-thiol. Using NMR spectroscopy and MALDI TOF mass spectrometry, the ability of the thiol-siloxane compound to undergo spontaneous hydrolytic condensation during storage is studied. The hybrid photopolymer films were obtained at different ratio of the components (from 16 : 1 to 1 : 2), and their thermomechanical and optical properties are investigated. The values of the storage modulus (0.9–2.3 GPa), the glass transition temperature (73–111°C), and the refractive index (1.56–1.59) are determined. On the basis of the 4 : 1 hybrid composition, a replica of relief microstructures with characteristic sizes of square elements of 5 × 0.8 μm is presented.

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  1. Color images are available in the electronic version of the journal.

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ACKNOWLEDGMENTS

We are grateful to the Multi-Access Chemical Research Center, Siberian Branch, Russian Academy of Sciences, for performing spectral and analytical measurements. The profilometry of the samples was carried out on the equipment of the Shared Research Center High-Resolution Spectroscopy of Gases and Condensed Matter at the Institute of Automation and Electrometry, Siberian Branch, Russian Academy of Sciences.

Funding

This work was supported by the Russian Science Foundation (project no. 18-73-00226); mass spectrometric analysis was supported by the Russian state budget project for the Institute of Chemical Biology and Fundamental Medicine, Siberian Branch, Russian Academy of Sciences (AAAA-A17-117020210025-5).

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Authors and Affiliations

  1. Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    D. I. Derevyanko, V. S. Basistyi, V. V. Shelkovnikov, I. K. Shundrina, A. D. Bukhtoyarova, G. E. Sal’nikov & V. N. Berezhnaya

  2. Institute of Chemical Biology and Fundamental Medicine, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    A. A. Chernonosov

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  1. D. I. Derevyanko
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Correspondence to D. I. Derevyanko.

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Derevyanko, D.I., Basistyi, V.S., Shelkovnikov, V.V. et al. Hybrid Photopolymer Material Based on (8-Acryloyl-1,4-dithia-8-azaspiro[4.5]decan-2-yl)methyl Acrylate and Thiol-Siloxane Component for Recording Microstructures: Synthesis and Optical and Thermomechanical Properties. Polym. Sci. Ser. B 62, 509–521 (2020). https://doi.org/10.1134/S1560090420050048

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