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Nanocomposite hydrogels composed of cloisite 30B-graft-poly(acrylic acid)/poly(acrylic acid): Synthesis and characterization

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Abstract

The hydrophilicity of Cloisite 30B is enhanced by surface grafting of polyacrylic acid (PAA). The radical polymerization of acrylic acid with the vinylsilylated Cloisite 30B leads to chemical grafting of PAA onto the organoclay surface. Chemical grafting of the PAA onto the surface of Cloisite 30B is shown by FTIR spectroscopy. Hydrogel nanocomposites are successfully prepared by using acrylic acid, vinylsilylated Cloisite 30B, and N,N-methylene bisacrylamide as a cross-linker. Thermogravimetric analysis (TGA) and differential thermal mechanical analysis (DMTA) revealed that prepared hydrogel nanocomposites show enhanced thermal and mechanical properties than those of pure hydrogel (hydrogel without nanoparticles). Swelling degree and equilibrium swelling capacity of hydrogel nanocomposites 1–7 wt % (loaded with 1–7 wt % of vinylsilylated Cloisite 30B, with respect to monomer) are also increased regarding to pure hydrogel. The interlayer and surface changes of the clay in the prepared nanocomposite materials and the grafted nano-particles are studied by X-ray diffraction and scanning electron microscopy.

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References

  1. K. Haraguchi, Curr. Opin. Solid State Mater. Sci. 11, 47 (2007).

    Article  CAS  Google Scholar 

  2. Y. Mansoori, S. V. Atghia, M. R. Zamanloo, G. Imanzadeh, and M. Sirousazar, Eur. Polym. J. 46, 1844 (2010).

    Article  CAS  Google Scholar 

  3. S.-F. Wang, M.-L. Lin, Y.-N. Shieh, Y.-R. Wang, and S.-J. Wang, Ceram. Int. 33, 681 (2007).

    Article  CAS  Google Scholar 

  4. G. Tartaglione, D. Tabuani, and G. Camino, Microporous Mesoporous Mater. 107, 161 (2008).

    Article  CAS  Google Scholar 

  5. I. Brnardi, M. Huski, M. igon, and M. Ivankovi, J. Non-Cryst. Solids 354, 1986 (2008).

    Article  Google Scholar 

  6. S. Tunç and O. Duman, Appl. Clay Sci. 48, 414 (2010).

    Article  Google Scholar 

  7. S. Tunç and O. Duman, LWT-Food Sci. Technol. 44, 465 (2011).

    Article  Google Scholar 

  8. S. Tunç, O. Duman, and B. Kanc, Colloids Surf., A 398, 37 (2012).

    Article  Google Scholar 

  9. H. ShamsiJazeyi, C. A. Miller, M. S. Wong, J. M. Tour, and R. Verduzco, J. Appl. Polym. Sci. 131, 40576 (2014).

    Article  Google Scholar 

  10. K. Deligkaris, T. S. Tadele, W. Olthuis, and A. van den Berg, Sens. Actuators, B 147, 765 (2010).

    Article  CAS  Google Scholar 

  11. W. E. Hennink and C. F. van Nostrum, Adv. Drug Delivery Rev. 54, 13 (2002).

    Article  CAS  Google Scholar 

  12. K. Burugapalli, D. Bhatia, V. Koul, and V. Choudhary, J. Appl. Polym. Sci. 82, 217 (2001).

    Article  CAS  Google Scholar 

  13. Y. **ang, Z. Peng, and D. Chen, Eur. Polym. J. 42, 2125 (2006).

    Article  CAS  Google Scholar 

  14. D. olpan,_S. Duran, and M. Torun, Radiat. Phys. Chem. 77, 447 (2008).

    Article  Google Scholar 

  15. J. E. Elliott, M. Macdonald, J. Nie, and C. N. Bowman, Polymer 45, 1503 (2004).

    Article  CAS  Google Scholar 

  16. V. Mittal, J. Colloid Interface Sci. 314, 141 (2007).

    Article  CAS  Google Scholar 

  17. X. Fan, C. **a, T. Fulghum, M.-K. Park, J. Locklin, and R. C. Advincula, Langmuir 19, 916 (2002).

    Article  Google Scholar 

  18. X. Fan, C. **a, and R. C. Advincula, Langmuir 19, 4381 (2003).

    Article  CAS  Google Scholar 

  19. C.-Y. Chen, C.-C. Chen, and S.-S. Hou, J. Appl. Polym. Sci. 115, 416 (2010).

    Article  CAS  Google Scholar 

  20. W. Tao, W. Mozhen, Z. Zhicheng, G. Xuewu, and F. Yue’e, Mater. Lett. 61, 3723 (2007).

    Article  Google Scholar 

  21. J. C. Chen, W. Q. Luo, H. D. Wang, J. M. **ang, H. F. **, F. Chen, and Z. W. Cai, Appl. Surf. Sci. 256, 2490 (2010).

    Article  CAS  Google Scholar 

  22. Negrete, J.-M. Letoffe, J.-L. Putaux, L. David, and E. Bourgeat-Lami, Langmuir 20, 1564 (2004).

    Article  Google Scholar 

  23. M. Nemat-Gorgani, K. Karimian, and F. Mohanazadeh, J. Am. Chem. Soc. 107, 4756 (1985).

    Article  CAS  Google Scholar 

  24. N. A. Agudelo, L. D. Perez, and B. L. Lopez, Appl. Surf. Sci. 257, 8581 (2011).

    Article  CAS  Google Scholar 

  25. T. G. Waddell, D. E. Leyden, and M. T. DeBello, J. Am. Chem. Soc. 103, 5303 (1981).

    Article  CAS  Google Scholar 

  26. Y. Mansoori, S. V. Atghia, S. S. Sanaei, M. R. Zamanloo, and G. Imanzadeh, Macromol. Res. 18, 1174 (2010).

    Article  CAS  Google Scholar 

  27. Y. Mansoori, A. Akhtarparast, M. Reza Zamanloo, G. Imanzadeh, and T. M. Masooleh, Polym. Compos. 32, 1225 (2011).

    Article  CAS  Google Scholar 

  28. M. Kaplan and H. Kasgoz, Polym. Bull. 67, 1153 (2011).

    Article  CAS  Google Scholar 

  29. J. Zhang, R. K. Gupta, and C. A. Wilkie, Polymer 47, 4537 (2006).

    Article  CAS  Google Scholar 

  30. B. B. Wheals, J. Chromatogr. 107, 402 (1975).

    Article  CAS  Google Scholar 

  31. Y. Fukushima, Clays Clay Miner. 32, 320 (1984).

    Article  CAS  Google Scholar 

  32. P. Liu and J. Guo, Colloids Surf., A 282-283, 498 (2006).

    Article  Google Scholar 

  33. Y. Mansoori, S. V. Atghia, M. R. Zamanloo, G. Imanzadeh, and M. Sirousazar, Eur. Polym. J. 46, 1844 (2010).

    Article  CAS  Google Scholar 

  34. F. Santiago, A. E. Mucientes, M. Osorio, and C. Rivera, Eur. Polym. J. 43, 1 (2007).

    Article  CAS  Google Scholar 

  35. H. Kaşgöz, A. Durmu, and A. Kaşgöz, Polym. Adv. Technol. 19, 213 (2008).

    Article  Google Scholar 

  36. W.-F. Lee and R.-J. Chiu, J. Polym. Res. 9, 141 (2002).

    Article  CAS  Google Scholar 

  37. Y. Bao, J. Ma, and N. Li, Carbohydr. Polym. 84, 76 (2011).

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Applied Chemistry, College of Science, University of Mohaghegh Ardabili, Ardabil, 56199-11367, Iran

    Yagoub Mansoori & Hadi Salemi

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  1. Yagoub Mansoori
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  2. Hadi Salemi
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Correspondence to Yagoub Mansoori.

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Mansoori, Y., Salemi, H. Nanocomposite hydrogels composed of cloisite 30B-graft-poly(acrylic acid)/poly(acrylic acid): Synthesis and characterization. Polym. Sci. Ser. B 57, 167–179 (2015). https://doi.org/10.1134/S1560090415020086

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  • DOI: https://doi.org/10.1134/S1560090415020086

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