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Magnetic Nanoparticle-Supported Basic Ionic Liquid: A Reusable Phase-Transfer Catalyst for Knoevenagel Condensation in Aqueous Medium

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Abstract

This study addressed the preparation and characterization of polyethylene glycol-substituted 1-methyl­imidazolium hydroxide supported on magnetic nanoparticles (MNP@PEG-ImOH) by FESEM, FT-IR, EDAX, TEM, TGA, VSM, and XRD techniques. The catalytic activity of MNP@PEG-ImOH has been examined in Knoevenagel condensation between active methylene compounds and aromatic aldehydes in aqueous medium at room temperature. Numerous benefits of the catalytic system, such as higher yields of the products, shorter reaction time, reusability and recyclability of the catalyst, simplified work-up, and more acceptable reaction conditions, have been demonstrated. It is possible to easily isolate the catalyst from the reaction mixture by an external magnet and reapply it in the consequent reactions with no remarkable loss of activity.

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Authors and Affiliations

  1. Department of Chemistry, Payame Noor University, 19395-4697, Tehran, Iran

    M. Fallah-Mehrjardi & R. Behjatmanesh-Ardakani

  2. Department of Basic Sciences and General Courses, Faculty of Economics and Management, Khorramshahr University of Marine Science and Technology, 64199-34619, Khorramshahr, Iran

    S. Saidian

Authors
  1. M. Fallah-Mehrjardi
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  3. S. Saidian
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Correspondence to M. Fallah-Mehrjardi.

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Fallah-Mehrjardi, M., Behjatmanesh-Ardakani, R. & Saidian, S. Magnetic Nanoparticle-Supported Basic Ionic Liquid: A Reusable Phase-Transfer Catalyst for Knoevenagel Condensation in Aqueous Medium. Russ J Org Chem 58, 144–151 (2022). https://doi.org/10.1134/S1070428022010201

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