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Experimental and Theoretical Studies of Two New Trinuclear Ni(II) Asymmetric Salamo-Based Complexes

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Abstract

Two new trinuclear Ni(II) complexes, [{Ni(L)(DMF)(μ-OAc)}2Ni] (1) and [{Ni(L)(EtOH)(μ-OAc)}2Ni]·2CH2Cl2 (2), have been successfully synthesized from a new asymmetric salamo-based hexa-dentate chelating ligand (H2L) and Ni(OAc)2·4H2O, and characterized by elemental analysis, IR and UV-Vis spectra, and X-ray crystallography. The binding ratio of H2L and Ni(II) ion has been confirmed by UV-Vis titration. All Ni(II) atoms are hexa-coordinated, and the complexes have octahedral configuration, though with difference in the solvent molecules (DMF/EtOH) involved in the coordination, composition of the hydrogen bond and chemical stability. This conclusion is confirmed by Hirshfeld surfaces analyses and Density Functional Theory (DFT).

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Funding

This work was supported by the National Natural Science Foundation of China (21761018), which are gratefully acknowledged. Computations were done using National Supercomputing Center in Shenzhen, China.

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Lanzhou Jiaotong University, Lanzhou, 730070, Gansu, China

    Y.-F. Ding, Y.-T. La, W.-D. Li, G.-X. Yao, L. Wang & W.-K. Dong

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  1. Y.-F. Ding
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  2. Y.-T. La
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  3. W.-D. Li
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  4. G.-X. Yao
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Correspondence to W.-K. Dong.

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Ding, YF., La, YT., Li, WD. et al. Experimental and Theoretical Studies of Two New Trinuclear Ni(II) Asymmetric Salamo-Based Complexes. Russ J Gen Chem 91 (Suppl 1), S89–S97 (2021). https://doi.org/10.1134/S1070363222020220

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