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New Organosilicon Bis-Derivatives of 2-Thiobenzimidazole

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Abstract

The earlier unknown organosilicon polyiodides of 2-thiobenzimidazolium have been synthesized basing on the three-component reaction of 2-thiobenzimidazole, bis(iodomethyl) derivatives of siloxanes or silanes, and molecular iodine; the products have been identified by means of NMR, IR, and UV spectroscopy.

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Funding

The authors thank L.I. Larina (Irkutsk Institute of Chemistry, Siberian Branch of Russian Academy of Sciences) for recording the 15N NMR spectra. This study was performed using of equipment of the Baikal Center for Collective Usage, Siberian Branch of Russian Academy of Sciences.

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Correspondence to L. V. Zhilitskaya.

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No conflict of interest was declared by the authors.

Russian Text © The Author(s), 2019, published in Zhurnal Obshchei Khimii, 2019, Vol. 89, No. 8, pp. 1239–1244.

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Zhilitskaya, L.V., Yarosh, N.O., Shagun, L.G. et al. New Organosilicon Bis-Derivatives of 2-Thiobenzimidazole. Russ J Gen Chem 89, 1625–1629 (2019). https://doi.org/10.1134/S1070363219080127

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  • DOI: https://doi.org/10.1134/S1070363219080127

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